Synthesis and Applications of Copper- Doped Pyridine Precipitate

Year : 2025 | Volume : 15 | Issue : 01 | Page : 51 60
    By

    P. Girija,

  1. Assistant Professor, Department of Chemistry, Annamalai University, Chidambaram, Tamil Nadu, India
  2. Professor, Department of Chemistry, Arignar Anna Government Arts College (AAGAC), Villupuram, Tamil Nadu, India

Abstract

A metal organic nonlinear optical single crystal, copper doped pyridine material, was created at room temperature using the slow evaporation solution growth technique (SEST). The developed material’s crystalline nature was revealed by a powder X-ray diffraction (XRD) analysis. Single crystal XRD study shows that the material synthesized possesses monoclinic system of cell parameters, a = 11.44 Å, b = 7.92 Å, C = 11.74 Å and alpha and gamma is equal to 90°, beta 110.40° differing from other two angles which shows that the synthesized material is new and not reported by any researchers before. Thermal studies of the sample material were also studied and confirmed that the synthesized material is temperature resistant revealing its application in laser technology. UV-visible-NIR spectroscopy confirms that the absorbance is in higher cutoff wavelength. The morphology and the presence of the metal copper is discussed in the scanning electron microscopy–energy dispersive X-ray spectroscopy ((SEM-EDS) specimen. Fourier transform infrared (FTIR) spectral studies confirm the synthesized material as copper-doped pyridine material. A novel copper-doped pyridine material was synthesized at room temperature using the slow evaporation solution growth technique (SEST). Powder and single-crystal XRD confirmed the monoclinic structure and uniqueness of the material. Thermal, UV-visible-NIR, SEM-EDS, and FTIR studies revealed its thermal resistance, optical properties, and chemical composition, making it suitable for laser technology applications. This green-colored material is reported for the first time.

Keywords: Pyridine, slow evaporation solution growth technique (SEST), copper sulfate, reflectance and energy dispersive spectroscopy

[This article belongs to Journal of Materials & Metallurgical Engineering ]

How to cite this article:
P. Girija. Synthesis and Applications of Copper- Doped Pyridine Precipitate. Journal of Materials & Metallurgical Engineering. 2025; 15(01):51-60.
How to cite this URL:
P. Girija. Synthesis and Applications of Copper- Doped Pyridine Precipitate. Journal of Materials & Metallurgical Engineering. 2025; 15(01):51-60. Available from: https://journals.stmjournals.com/jomme/article=2025/view=197757


References

  1. Saravanan N, Ravisankar V, Chithambaram V. Growth and characterization of novel semi organic nonlinear optical urea lead acetate single crystal by solution growth technique. J Mater Sci Mater Electron. 2018; 29: 5009–50
  2. Shah SH, Bristowe PD. First-principles density functional study of polarization–strain coupling in bismuth titanate. J Phys Condens 2010; 22 (38): 385902.
  3. Oliver SA, Yoon SD, Kozulin I, Chen ML, Vittoria C. Growth and characterization of thick oriented barium hexaferrite films on MgO (111) substrates. Appl Phys Lett. 2000; 76 (24): 3612–361
  4. Prasad LG, Krishnakumar V, Nagalakshmi R. Growth and characterization of semi-organic nonlinear optical crystal: sodium 2,4-dinitrophenolate monohydrate. Spectrochim Acta Part A Mol Biomol Spectrosc. 2013; 110: 377–3
  5. Hanumantharao R, Kalainathan S. Growth, spectroscopic, dielectric and nonlinear optical studies of semi organic nonlinear optical crystal–l-alanine lithium chloride. Spectrochim Acta Part A Mol Biomol Spectrosc. 2012; 86: 80–8
  6. Rani N, Vijayan N, Maurya KK, Haranath D, Saini P, Rathi B, Wahab MA, Bhagavanarayana G. Studies on the effect of polymer coating on solution grown hygroscopic non-linear optical single crystal of L-lysine monohydrochloride. Spectrochim Acta Part A Mol Biomol Spectrosc. 2012; 97: 871–87
  7. Bouchouit K, Bendeif EE, Ouazzani HE, Dahaoui S, Lecomte C, Benali-Cherif N, Sahraoui B. Correlation between structural studies and third order NLO properties of selected new quinolinium semi-organic compounds. Chem Phys. 2010; 375 (1): 1–
  8. Akselrod MS, Bruni FJ. Modern trends in crystal growth and new applications of sapphire. J Cryst 2012; 360: 134–145.
  9. Bouchouit K, Essaidi Z, Abed S, Migalska-Zalas A, Derkowska B, Benali-Cherif N, Mihaly M, Meghea A, Sahraoui B. Experimental and theoretical studies of NLO properties of organic–inorganic materials base on p-nitroaniline. Chem Phys Lett. 2008; 455 (4–6): 270–27
  10. Vivek P, Suvitha A, Murugakoothan P. Growth, spectral, anisotropic, second and third order nonlinear optical studies on potential nonlinear optical crystal anilinium perchlorate (AP) for NLO device fabrications. Spectrochim Acta Part A Mol Biomol Spectrosc. 2015; 134: 517–5
  11. Akdas-Kilig H, Malval JP, Morlet-Savary F, Singh A, Toupet L, Ledoux-Rak I, Zyss J, Le Bozec H. The synthesis of tetrahedral bipyridyl metallo-octupoles with large second-and third-order nonlinear optical properties. Dyes 2012; 92 (1): 681–688.
  12. Srineevasan R, Rajasekaran R. Growth and optical studies of 2-aminopyridine bis thiourea zinc sulphate (2-APTZS) single crystals for NLO applications. J Mol Struct. 2013; 1048: 238–2
  13. Gowri S, Devi TU, Sajan D, Bheeter SR, Lawrence N. Spectral, thermal and optical properties of adenosinium picrate: a nonlinear optical single crystal. Spectrochim Acta Part A Mol Biomol Spectrosc. 2012; 89: 119–1
  14. Kumar P, Gupta R. The wonderful world of pyridine-2,6-dicarboxamide based scaffolds. Dalton Trans. 2016; 45 (47): 18769–187
  15. M ü ller S, Sanders DA, Di Antonio M, Matsis S, Riou JF, Rodriguez R, Balasubramanian S . Pyridostatin analogues promote telomere dysfunction and long-term growth inhibition in human cancer cells. Org Biomol Chem. 2012; 10 (32): 6537–6546.
  16. Li J, Tilbury CJ, Kim SH, Doherty MF. A design aid for crystal growth engineering. Prog Mater Sci. 2016; 82: 1–
  17. Wood JS, Keijzers CP, De Boer E. The ESR spectra of the pure and zinc doped hexakis pyridine-N-oxide cuprate ion. Chem Phys Lett. 1977; 51: 489–492.
  18. Usman MU, Faruque MO. Applications of synchrophasor technologies in power systems. Journal of Modern Power Systems and Clean Energy. 2019; 7(2): 211–26.
Regular Issue Subscription Original Research
Volume 15
Issue 01
Received 30/12/2024
Accepted 19/01/2025
Published 29/01/2025
178

Login


My IP

PlumX Metrics