Determination of Compatibility of Polymer Systems and Study of Chemical Properties of their Mixtures

Year : 2026 | Volume : 04 | Issue : 01 | Page : 17 29
    By

    Shixaliyev Kerem Sefi*,

  1. Professor, Department of Organic Substances and Technology of Macromolecular Compounds, Azerbaijan State Oil and Industry University,, Baku, AZ1010, Azerbaijan

Abstract

We have obtained mechanical strength of materials as a result not by synthesizing new polymers, but by using industrial polymers. We have developed a technology for obtaining new composite materials based on industrial multi-tonnage polymers of high-strength polyethylene (HSPE), polyvinyl chloride (PVC), polyurethane thermoplastic elastomer (DUTEP), butyl rubber (BR), chlorocarboxylate polyethylene (CCPE), ethylene propylene rubber (EPR). To obtain a composition from these polymers, their mixture compatibility was first determined using the most modern methods. Thermodynamic compatibility of the butyl rubber-polyethylene (BR-LDPE), polyvinyl chloride, HSPE, polyurethane thermoplastic elastomer, PVC-chlorocarboxylate polyethylene (CPE), (CREP-VC) systems was studied using inverse gas chromatography methods, and structural features of these systems were revealed using IR spectroscopy and polarization microscopy. The study demonstrated that the incorporation of polyfunctional groups such as chlorine, hydroxyl, and carboxyl markedly influences the compatibility mechanism and provides a consistent set of enhanced properties, including improved adhesive performance, greater tensile and tear strength, and increased resistance to thermal and chemical degradation. These improvements arise from intermolecular polar interactions between macromolecular chains. The solubility parameters of four polymers with varying degrees of polarity were evaluated using turbidimetric titration (TDT) and inverse gas chromatography techniques. Based on the temperature dependence of the solubility parameter derived from sorbent retention times, the parameter value normalized to 25 °C was calculated and compared with that obtained through the TDG method at the same temperature. The results indicated that the discrepancy between the solubility parameters determined by the two methods increased with higher polymer polarity. This phenomenon is attributed to the fundamentally different states of the examined polymer–solvent systems.

Keywords: Polymer, macromolecules, compatibility, high-strength polyethylene (HSPE), polyvinyl chloride (PVC), polyurethane thermoplastic elastomer (PUTE), butyl rubber (BR), chlorocarboxylate polyethylene (CCPE), ethylene propylene rubber (EPR). solubility parameter, sorbent, stability, polyfunctional groups

[This article belongs to International Journal of Cheminformatics ]

How to cite this article:
Shixaliyev Kerem Sefi*. Determination of Compatibility of Polymer Systems and Study of Chemical Properties of their Mixtures. International Journal of Cheminformatics. 2026; 04(01):17-29.
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Shixaliyev Kerem Sefi*. Determination of Compatibility of Polymer Systems and Study of Chemical Properties of their Mixtures. International Journal of Cheminformatics. 2026; 04(01):17-29. Available from: https://journals.stmjournals.com/ijci/article=2026/view=242784


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Regular Issue Subscription Original Research
Volume 04
Issue 01
Received 02/02/2026
Accepted 20/02/2026
Published 28/02/2026
Publication Time 26 Days
33

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