Carbon-Coated Te-Doped Bi₂Se₃ as a Topological Quantum Anode Material for Sodium-Ion Batteries

Year : 2026 | Volume : 16 | Issue : 02 | Page : 55 61
By

Anunad Mishra*,

Urvesh Vala,

  1. Engineer, Department of Material Engineering Technology, L&T Energy Hydrocarbon Engineering Limited, Vadodara, Gujrat, India
  2. Head, Department of Material Engineering Technology, L&T Energy Hydrocarbon Engineering Limited, Vadodara, Gujrat, India

Abstract

Sodium-ion batteries (SIBs) are increasingly investigated as cost-effective alternatives to lithium-ion systems for large-scale energy storage; however, the development of stable and conductive anode materials remains a major challenge. In this work, tellurium-doped bismuth selenide (Te-doped Bi₂Se₃) was synthesized and further modified with Super P conductive carbon to improve its sodium-storage behavior. The phase formation and structural retention of the active material were examined using X-ray diffraction, while elemental mapping and energy-dispersive X-ray spectroscopy verified the incorporation of Te and the presence of carbon in the modified sample. Thermogravimetric analysis showed that the material remained thermally stable up to approximately 500°C. Electrochemical testing in sodium half-cells revealed that the uncoated Te-doped Bi₂Se₃ electrode delivered stable capacities of about 150 mAh g⁻¹ at 20 mA g⁻¹ and 110 mAh g⁻¹ at 40 mA g⁻¹. After carbon modification, the corresponding capacities increased to approximately 250 mAh g⁻¹ and 175 mAh g⁻¹, respectively. Cyclic voltammetry further indicated improved redox reversibility and more stable peak currents for the carbon-modified electrode. These results suggest that carbon-coated/composite Te-doped Bi₂Se₃ is a promising anode candidate for SIBs, with carbon modification providing improved conductivity, enhanced reaction reversibility, and better rate performance.

Keywords: Sodium-ion battery, Te-doped Bi₂Se₃, carbon coating, Super P., anode, topological quantum material

[This article belongs to Journal of Materials & Metallurgical Engineering ]

How to cite this article: Anunad Mishra*, Urvesh Vala. Carbon-Coated Te-Doped Bi₂Se₃ as a Topological Quantum Anode Material for Sodium-Ion Batteries. Journal of Materials & Metallurgical Engineering. 2026; 16(02):55-61.
How to cite this URL: Anunad Mishra*, Urvesh Vala. Carbon-Coated Te-Doped Bi₂Se₃ as a Topological Quantum Anode Material for Sodium-Ion Batteries. Journal of Materials & Metallurgical Engineering. 2026; 16(02):55-61. Available from: https://journals.stmjournals.com/jomme/article=2026/view=252048

References

  1. Hwang JY, Myung ST, Sun YK. Sodium-ion batteries: present and future. Chemical Society Reviews. 2017;46(12):3529-614. 
  2. More VS, Yadav MD. Progress and prospects in cathode materials for sodium-ion batteries: synthesis, characterization, and engineering aspects. Energy & Fuels. 2024 Oct 23;38(21):20285-313. 
  3. Xie M, Wu F, Huang Y. Sodium-ion batteries: Advanced technology and applications. Walter de Gruyter GmbH & Co KG; 2022 Aug 1. 
  4. Jang H, Youn B, Han Y, Lee D. Bridging the gap from basic principles to advanced applications in sodium-ion batteries. Journal of Energy Storage. 2026 Jan 10;142:119547. 
  5. Palomares V, Serras P, Villaluenga I, Hueso KB, Carretero-González J, Rojo T. Na-ion batteries, recent advances and present challenges to become low cost energy storage systems. Energy & Environmental Science. 2012;5(3):5884-901. 
  6. Pahari D, Verma P, Puravankara S. Are Na-ion batteries nearing the energy storage tipping point?–Current status of non-aqueous, aqueous, and solid-sate Na-ion battery technologies for sustainable energy storage. Journal of Energy Storage. 2022 Dec 1;56:105961. 
  7. Luo W, Shen F, Bommier C, Zhu H, Ji X, Hu L. Na-ion battery anodes: materials and electrochemistry. Accounts of chemical research. 2016 Feb 16;49(2):231-40. 
  8. Cui J, Yao S, Kim JK. Recent progress in rational design of anode materials for high-performance Na-ion batteries. Energy Storage Materials. 2017 Apr 1;7:64-114. 
  9. Xie L, Yang Z, Sun J, Zhou H, Chi X, Chen H, Li AX, Yao Y, Chen S. Bi2Se3/C nanocomposite as a new sodium-ion battery anode material. Nano-micro letters. 2018 Jul;10(3):50. 
  10. Li D, Zhou J, Chen X, Song H. Graphene-loaded Bi2Se3: a conversion–alloying-type anode material for ultrafast gravimetric and volumetric Na storage. ACS applied materials & interfaces. 2018 Aug 16;10(36):30379-87. 

Regular Issue Subscription Original Research
Volume 16
Issue 02
Received 23/05/2026
Accepted 29/05/2026
Published 22/06/2026
Publication Time 30 Days


Login

My IP

PlumX Metrics