Ki-Ho Rim,
Mi Yong Kim,
Mi Hyang Jong,
So Yon Kim,
Chol Ho Kim,
Byong So Ri,
- Professor, Department of Dental Caries and Oral Medicine Research, Pyongyang University of Medical Sciences, Pyongyang, Korea
- Professor, Department of Dental Caries and Oral Medicine Research, Pyongyang University of Medical Sciences, Pyongyang, Korea
- Researcher, Department of Dental Caries and Oral Medicine Research, Pyongyang University of Medical Sciences, Pyongyang, Korea
- (DMD) Dr. of Medical Dentist, Department of Dentistry, General Dental Hospital of Ministry of Public Health, Pyongyang, Korea
- Professor and PhD Chief, Department of Dental Caries and Oral Medicine Research, Pyongyang, Korea
- Professor and PhD Chief, Department of Analytic Chemistry Research, Pyongyang University of Medical Sciences, Pyongyang, Korea
Abstract
The effect of solutions of sodium fluoride in hydrofluoric acid on the fluoride-dental minerals reaction system was investigated. The fluoride concentration in each fluoride solution was kept at 1.23% as the fluoride concentration in the acidulated phosphate fluoride solution at pH 3. The acidic sodium fluoride-hydrofluoric acid solutions with different contents of sodium fluoride and hydrofluoric acid were prepared. These solutions were added to synthetic powder hydroxyapatite and calcium hydrogen phosphate crystal, respectively, and then precipitated for 10 min at room temperature. Acidulated phosphate fluoride solution (pH 3.0) was used as a control fluoride solution. The results of the analysis showed that the CaF2 content in the samples treated with acidic NaF-HF solution with relatively low hydrofluoric acid content was almost like that of the samples treated with acidulated phosphate fluoride. However, the CaF2 content in the samples treated with acidic NaF-HF solution with high hydrofluoric acid content was higher than that of the samples treated with acidulated phosphate fluoride. It was found that the chemical reactivity of hydroxyapatite with fluoride solution was related to the content of hydrofluoric acid and the ionic atmosphere, that is, the higher the content of hydrofluoric acid and lower the ionic concentration, the higher the reactivity.
Keywords: Acidic sodium fluoride-hydrofluoric acid solution (ANHS), CaF2, hydroxyapatite, fluorapatite, calcium hydrogen phosphate (burshite), chemical reactivity
[This article belongs to Research & Reviews: A Journal of Dentistry ]
Ki-Ho Rim, Mi Yong Kim, Mi Hyang Jong, So Yon Kim, Chol Ho Kim, Byong So Ri. Influence of Acidic Naf-Hf Solution on Dental Minerals. Research & Reviews: A Journal of Dentistry. 2024; 15(03):27-37.
Ki-Ho Rim, Mi Yong Kim, Mi Hyang Jong, So Yon Kim, Chol Ho Kim, Byong So Ri. Influence of Acidic Naf-Hf Solution on Dental Minerals. Research & Reviews: A Journal of Dentistry. 2024; 15(03):27-37. Available from: https://journals.stmjournals.com/rrjod/article=2024/view=184888
References
- Shalin GS, Vijay B, Sunita C, Karthik V, Prashant C, Mahadeban G, Krishna T. Efficacy of silver diamine fluoride as a topical fluoride agent compared to fluoride varnish and acidulated phosphate fluoride gel: an in vivo study. J Pediat Dentist. 2014;2:5–12.
- Taniya T, Pratik KL, Madhumanti K, Bhumi S, Piyali D, Rajib S. Comparison of the fluoride release of silver diamine fluoride, fluoride varnish, acidulated phosphate fluoride gel on extracted teeth over various time intervals in artificial saliva. 2021;33:55–63.
- Maria I, Dantas De M, Hugo LC, Rogerio LS, Frederico B. TiF4 varnish protects the retention of brackets to enamel after in vitro mild erosive challenge. J Appl Oral Sci. 2018;26:1–9.
- Lader D, Chadwick B, Chestnutt I, Harker R, Morris J, Nuttall N. Children’s dental health in the United Kingdom, 2003: Summary Report: Office for National Statistics, 2005.
- Van Rijkom HM, Truin GJ, Van’thof MA. Caries-inhibiting effect of professional fluoride gel application in low-caries children initially aged 4.5–6.5 years. Caries Res. 2004;38:115–23.
- Cobb HB, Rozier RG, Bawden JW. A clinical study of the caries preventive effects of an APF solution and APF thixotropic gel. Pediatr Dent. 1980;2:263–6.
- Samira HJ, Savio JCB, Alessandra BB, Ana CA, Tais S. Effect of sodium fluoride and stannous chloride associated with Nd:YAG laser irradiation on the progression of enamel erosion. Lasers Med Sci. 2015;30:2227–32.
- Jiang H, Bian Z, Tai BJ, Du MQ, Peng B. The effect of a bi-annual professional application of APF foam on dental caries increment in primary teeth: 24-month clinical trial. J Dent Res. 2005;84:265–8.
- Gee Ho L, Chang Nam G. Effectiveness of topical application of ammonium fluoride – ammonium molybdate(3%F-) in school children: a 3-year followup study. Int J Dent Health Sci. 2015;2:1071–9.
- Beulah MB, Moonnamkoottu SS, Liza G, Josey M, Raveendran PVV, Aleesha J. Comparative evaluation of casein phosphopeptide -amorphous calcium phosphate–fluoride paste and sodium fluoride mouthwash in the prevention of dental erosion: an in vitro study. J Contemp Dent Pract. 2020; 21:266–9.
- Rickles NH, Becks H. Effects of an acid and a neutral solution of sodium fluoride on the incidence of dental caries in young adults. J Dent Res. 1951;30:757–65.
- Brudevold F, Savory A, Gardner DE, Spinelli M, Speirs R. A study of acidulated fluoride solutions-I. In vitro effects on enamel. Arch Oral Biol. 1963;8:167–77.
- Wellock WD, Brudevold F. A study of acidulated fluoride solutions-II. The caries inhibiting effect of single annual topical applications of an acidic fluoride and phosphate solution. Arch Oral Biol. 1963;8:179–82.
- Pameijea JHN, Brudevold F, Hunt EE. A study of acidulated fluoride solutions-Ⅲ the cariostatic effect of repeated topical sodium fluoride applications with and without phosphate: a pilot study. Arch Oral Biol. 1963;8:183–5.
- Bibby BG, Brudevold F. The external action of fluoride and other agents on the teeth in the prevention of dental decay. In: Fluoridation as a Public Health Measure, 143, 1954.
- Fischer RB, Muhler JJC, Wust CJ. Effects of several fluoride reagents on the surface structure of powdered dental enamel. J Dent Res. 1954;33:538–41.
- Marcela MA, Marina AT, Gabriela MB, Hilton TC, Cecy MS, Jesuina L, et al. Effect of fluoride gels on the surface roughness of different composite resins. Op Dent J. 2020;14:474–81.
- Aysun A, Nuray T. Effect of different topical fluoride applications on the surface roughness of a colored compomer. J Appl Oral Sci. 2010;18:171–7.
- Vanessa Zulema S. Surface degradation of glass ceramics after exposure to acidulated phosphate fluoride. J Appl Oral Sci. 2010;18:155–65.
- Peter A, de Paula J. Physical Chemistry for the Life Sciences, ed. 2, Italy: L.E.G.O. S.p.A.; 2011.
- Ki Ho R, Myong Chol J. Preventive effect of 1% subacidic NaF-HF gel on dental caries in 6~7-year-old primary school children: a randomized controlled trial. Quint Int. 2021;52:318–26.
- Qu H, Wei M. Synthesis and characterization of fluorine containing hydroxyapatite by a pH-cyclic method. Mater Sci Mater Med. 2005;16:129–33.
- Rowles SL. The inorganic composition of arrested carious dentine. Caries Res. 1973;7:360–7.
- Frondel C. Whidlockite: new calcium phosphate, Ca (PO4)2. Amer Miner. 1941;26:145–52.
- Roufosse AH. Identification of burshite in newly deposited bone mineral embryonic chicks. J Ultrast Res. 1979;68:235–55.
Research and Reviews: A Journal of Dentistry
Volume | 15 |
Issue | 03 |
Received | 03/10/2024 |
Accepted | 07/10/2024 |
Published | 29/10/2024 |