Elucidation of Physical Structural Stability of Nickel Nanoparticles Additive-Based Magnetorheological Grease

Open Access

Year : 2026 | Volume : 14 | Issue : 01 | Page : 191 215
    By

    Norzilawati Mohamad,

  • Ubaidillah,

  • Siti Aishah Abdul Aziz,

  • Saiful Amri Mazlan,

  • Siti Maisarah Tarmizi,

  • Irfan Bahiuddin,

  1. Lecturer, Faculty of Engineering, Universiti Malaysia Sabah, Jalan UMS, 88400 Kota Kinabalu, Sabah, , Malaysia
  2. Professor, Mechanical Engineering Department, Universitas Sebelas Maret, Jl. Ir. Sutami 36A, Kentingan 57126 Surakarta, , Indonesia
  3. Lecturer, Faculty of Applied Sciences, Universiti Teknologi MARA (UiTM) Cawangan Pahang, Kampus Jengka 26400 Bandar Tun Abdul Razak Jengka, Pahang, , Malaysia
  4. Professor, Engineering Materials and Structures (eMAST) iKohza, Malaysia-Japan International Institute of Technology (MJIIT), Universiti Teknologi Malaysia, 54100 Kuala Lumpur, , Malaysia
  5. Professor, Engineering Materials and Structures (eMAST) iKohza, Malaysia-Japan International Institute of Technology (MJIIT), Universiti Teknologi Malaysia, 54100 Kuala Lumpur, , Malaysia
  6. Lecturer, Department of Mechanical Engineering, Vocational College, Universitas Gadjah Mada, Yogyakarta, , India

Abstract

This study investigates the influence of nickel nanoparticles on the physical properties and structural stability of magnetorheological grease (NMRG) as a smart composite. The incorporation of nickel nanoparticles aims to mitigate issues commonly observed in conventional magnetorheological grease (MRG), including particle aggregation within the fibrous matrix, limited material performance, and deformation instability. NMRG samples containing 1–5 wt% nickel nanoparticles were prepared using a mechanical stirring method. The tests focused on physical properties, subjected to rheological analysis, chemical compound identification, and wettability characterizations. The results revealed that the NMRG exhibited enhanced hydrophobicity, increasing by approximately 8.4% with higher nanoparticle content, while no detectable changes occurred in the chemical composition of the compound. This indicates that the inherent chemical bonds in the grease dominate over the physical adsorption process. The inclusion of nickel nanoparticles also led to notable improvements in magnetic and rheological performance, characterized by higher viscosity, greater energy storage capability, an extended linear viscoelastic (LVE) range, and reduced damping behavior. These outcomes confirm that the incorporation of nickel nanoparticles enhances the physical properties and structural stability of NMRG, particularly in terms of elasticity and deformation resilience. The findings provide insight into how nanoparticle-induced surface modifications can significantly influence the performance of magnetorheological materials for advanced engineering applications.

Keywords: Magnetorheological grease, nickel nanoparticles, physical properties, smart composite, structural stability

[This article belongs to Journal of Polymer & Composites ]

How to cite this article:
Norzilawati Mohamad, Ubaidillah, Siti Aishah Abdul Aziz, Saiful Amri Mazlan, Siti Maisarah Tarmizi, Irfan Bahiuddin. Elucidation of Physical Structural Stability of Nickel Nanoparticles Additive-Based Magnetorheological Grease. Journal of Polymer & Composites. 2026; 14(01):191-215.
How to cite this URL:
Norzilawati Mohamad, Ubaidillah, Siti Aishah Abdul Aziz, Saiful Amri Mazlan, Siti Maisarah Tarmizi, Irfan Bahiuddin. Elucidation of Physical Structural Stability of Nickel Nanoparticles Additive-Based Magnetorheological Grease. Journal of Polymer & Composites. 2026; 14(01):191-215. Available from: https://journals.stmjournals.com/jopc/article=2026/view=236571


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References

  1. Fardan MF, Lenggana BW, Ubaidillah U, Choi SB, Susilo DD, Khan SZ. Revolutionizing Prosthetic Design with Auxetic Metamaterials and Structures: A Review of Mechanical Properties and Limitations. Micromachines (Basel). 2023 May 31;14(6):1165. DOI: 10.3390/mi14061165
  2. Rankin PJ, Horvath AT, Klingenberg DJ. Magnetorheology in viscoplastic media. Rheol Acta. 1999;38(5):471–7. DOI: https://doi.org/10.1007/s003970050
  3. Kim J, Ko J, Liu Y, Kim I, Choi H. Effect of medium oil on magnetorheology of soft magnetic carbonyl iron particles. 2012;170(2004):5246. IEEE Transactions on Magnetics. Volume: 48(11). DOI: 10.1109/TMAG.2012.2195160
  4. Wang K, Dong X, Li J, Shi K, Li K. Effects of silicone oil viscosity and carbonyl iron particleweight fraction and size on yield stress for magnetorheological grease based on a new preparation technique. Materials. 2019;12(11):7–9. DOI: 10.3390/ma12111778
  5. Pang Z Bin, Mazlan SA, Ubaidillah U, Nordin NA, Mohamad N, Johari MAF, et al. Microstructural analysis on the compatibility of various dilution oils on magnetorheological grease performance. Engineering Research Express. 2024 Sep 1;6(3). DOI: 10.1088/2631-8695/ad78aa
  6. Park JH, Kwon MH, Park OO. Rheological properties and stability of magnetorheological fluids using viscoelastic medium and nanoadditives. Korean Journal of Chemical Engineering. 2001;18(5):580–5. DOI: https://doi.org/10.1007/BF02706371
  7. Mohamad N, Ubaidillah, Mazlan SA, Choi SB, Halim NA. Improvement of magnetorheological greases with superparamagnetic nanoparticles. Setiadji BH, Han AL, Widodo A, Setiawan JD, Kurdi O, Hatmoko JUD, editors. MATEC Web of Conferences [Internet]. 2018 Apr 6;159:02066. Available from: https://www.matec-conferences.org/10.1051/matecconf/201815902066
  8. Mohd Nasir NA, Nazmi N, Mohamad N, Ubaidillah U, Nordin NA, Mazlan SA, et al. Rheological performance of magnetorheological grease with embedded graphite additives. Materials. 2021;14(17):1–15. DOI: 10.3390/ma14175091
  9. Tarmizi SMA, Nordin NA, Mazlan SA, Mohamad N, Rahman HA, Aziz SAA, et al. Incorporation of cobalt ferrite on the field dependent performances of magnetorheological grease. Journal of Materials Research and Technology [Internet]. 2020;9(6):15566–74. Available from: https://doi.org/10.1016/j.jmrt.2020.11.028
  10. Tarmizi SMA, Nordin NA, Mazlan SA, Ubaidillah U, Aziz SAA, Mohamad N, et al. Improvement of rheological and transient response of magnetorheological grease with amalgamation of cobalt ferrite. Journal of Materials Research and Technology. 2023 Mar 1;23:1285–95.DOI: 10.1016/j.jmrt.2022.12.154
  11. Tarmizi SMA, Nordin NA, Mazlan SA, Savukkath Ali SAH, Aziz SAA, Mohamad N, et al. Thermal stability enhancement of magnetorheological grease with cobalt-ferrite particles as additive. In 2024. p. 080005. Available from: https://pubs.aip.org/aip/acp/article-lookup/doi/10.1063/5.0227794
  12. Ghasemi SS, Golshan Ebrahimi N, Hajalilou A. Simultaneous effect of magnetic nanoparticles additive and noble metal coating on carbonyl iron-based magnetorheological fluid. J Alloys Compd. 2023 Oct 25;961.
  13. Mohamad N, Mazlan SA, Ubaidillah, Choi SB, Nordin MFM. The Field-Dependent Rheological Properties of Magnetorheological Grease Based on Carbonyl-Iron-Particles. Smart Mater Struct [Internet]. 2016 Sep 1;25(9):095043. Available from: https://iopscience.iop.org/article/10.1088/0964-1726/25/9/095043
  14. Yari B, Norouzi M, Hashemian SM, Ghatee M, Izadifard MH. Synthesis and characterization of a novel magnetorheological fluid based on surfactants with dual hydrophilic/hydrophobic property. Colloids Surf A Physicochem Eng Asp. 2025 Mar 5;708. [Page number missing] [DOI missing]
  15. Ayrilmis N, Kanat G, Yildiz Avsar E, Palanisamy S, Ashori A. Utilizing waste manhole covers and fibreboard as reinforcing fillers for thermoplastic composites. Journal of Reinforced Plastics and Composites. 2025 Sep 1;44(17–18):1108–18.
  16. Xu H, Clarke A, Rothstein JP, Poole RJ. Viscoelastic drops moving on hydrophilic and superhydrophobic surfaces. J Colloid Interface Sci. 2018 Mar 1;513:53–61.
  17. Patro BDK, Suvin PS, Kreivaitis R, Gumbytė M. Investigating the Wettability, Rheological, and Tribological Properties of Ammonium-Based Protic Ionic Liquids as Neat Lubricants for Steel–Steel and Steel–Aluminium Contacts. Lubricants. 2023 Nov 1;11(11).
  18. Padmanabhan RG, Rajesh S, Karthikeyan S, Palanisamy S, Ilyas RA, Ayrilmis N, et al. Evaluation of mechanical properties and Fick’s diffusion behaviour of aluminum-DMEM reinforced with hemp/bamboo/basalt woven fiber metal laminates (WFML) under different stacking sequences. Ain Shams Engineering Journal. 2024 Jul 1;15(7).
  19. Karuppiah G, Kuttalam KC, Palaniappan M, Santulli C, Palanisamy S. Multiobjective optimization of fabrication parameters of jute fiber/polyester composites with egg shell powder and nanoclay filler. Molecules. 2020 Dec 1;25(23).
  20. Lee S, Yim C, Kim W, Jeon S. Magnetorheological Elastomer Films with Tunable Wetting and Adhesion Properties. ACS Appl Mater Interfaces. 2015 Sep 9;7(35):19853–6.
  21. Wang K, Dong X, Li J, Shi K. Yield dimensionless magnetic effect and shear thinning for magnetorheological grease. Results Phys. 2020 Sep 1;18.
  22. Huang W, Liao S, Wang X. Wettability and friction coefficient of micro-magnet arrayed surface. Appl Surf Sci. 2012 Jan 15;258(7):3062–7.

Regular Issue Open Access Original Research
Volume 14
Issue 01
Received 21/11/2025
Accepted 01/12/2025
Published 14/01/2026
Publication Time 54 Days


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