Moulya H V,
Vishvachetan S G,
Hitha Chowdary,
Geetha L,
- Assistant Professor, Department of Civil Engineering, Nitte Meenakshi Institute of Technology (NMIT), Nitte Deemed to be University, Bengaluru, Karnataka, India
- Research Scholar, Department of Civil Engineering, Nitte Meenakshi Institute of Technology (NMIT), Nitte Deemed to be University, Bengaluru, Karnataka, India
- Research Scholar, Department of Civil Engineering, Nitte Meenakshi Institute of Technology (NMIT), Nitte Deemed to be University, Bengaluru, Karnataka, India
- Assistant Professor, Department of Civil Engineering, Dayananda Sagar College of Engineering, Bengaluru, Karnataka, India
Abstract
The present investigation examines the development of a hybrid composite using Black Cotton (BC) soil, Bagasse Ash (BA), and Sodium Benzophenone (SBP) as performance-enhancing elements. Different ratios of BA, a silica-rich agro-industrial by-product, were added to improve pozzolanic reactivity and particle size distribution (0%, 6%, and 12%). SBP was added in the range of 0–0.6% as a compatibilizer in order to enhance interfacial adhesion, particle cohesivity and moisture-assisted deterioration resistance. Composite specimens were prepared by applying controlled compaction and tested for their engineering behavior using Standard Proctor test, Unconfined Compressive Strength (UCS) tests and microstructural examination by adopting Scanning Electron Microscopy (SEM). The best packing was observed at 10% BA and 0.2% SBP, which gave the highest dry density and optimum moisture content. A more pronounced strength increase was observed according to the results of the UCS test, where the maximum value at 10%BA and 0.4%SBP after 30 days curing, exceeded over 60 per cent improvement in strength compared with untreated BC soil. SEM images showed a dense paste with fewer pores and stronger particle contact, caused by BA’s pozzolanic reaction and SBP’s chemical modification. These results show that blending agro-waste with chemical processing produces strong and economical composite material. This material displays excellent compaction properties, gradual strength improvement, and intact microstructure, suggesting significant promise for eco-friendly engineering and structural uses requiring increased longevity and weight-bearing capability.
Keywords: Composite materials, soil stabilization, bagasse ash, sodium benzophenone, expansive soil, pozzolanic reaction, compaction behavior, unconfined compressive strength.
[This article belongs to Special Issue under section in Journal of Polymer & Composites (jopc)]
Moulya H V, Vishvachetan S G, Hitha Chowdary, Geetha L. Composite Behavior of Bagasse Ash Stabilized Expansive Soil with Sodium Benzophenone Under Curing Conditions. Journal of Polymer & Composites. 2025; 13(06):1134-1146.
Moulya H V, Vishvachetan S G, Hitha Chowdary, Geetha L. Composite Behavior of Bagasse Ash Stabilized Expansive Soil with Sodium Benzophenone Under Curing Conditions. Journal of Polymer & Composites. 2025; 13(06):1134-1146. Available from: https://journals.stmjournals.com/jopc/article=2025/view=234443
References
- Kumar and A. Walia, “Stabilization of soil using bagasse ash,” International Journal of Research in Engineering and Technology, vol. 3, no. 4, pp. 263–267, 2014.
- D. Singh and R. Singh, “Effect of bagasse ash on strength characteristics of expansive soil,” International Journal of Innovative Research in Science, Engineering and Technology, vol. 4, no. 5, pp. 261–265, 2015.
- Bhardwaj A, Sharma RK. Effect of industrial wastes and lime on strength characteristics of clayey soil. J Eng Des Technol. 2020; ahead-of-print. doi:10.1108/jedt-12-2019-0350.
- Akobo IZS, Iroaganachi PN, Charles K. Comparative strength evaluation of cementitious stabilizing agents blended with pulverized bagasse fibre for stabilization of expansive lateritic soils. Glob Sci J. 2018;6(12):239-55.
- Charles K, Nwikina BB, Wokoma TTT. Potential of cement, lime and Costaceae lacerus bagasse fibre in lateritic soils swell–shrink control and strength variance determinations. Glob Sci J. 2018;6(12):273-90.
- Nwikina BB, Charles K, Amakiri-Whyte B. Modification of expansive lateritic soils of highway subgrade with blended composite materials and performance characteristics. Glob Sci J. 2018;6(12):256-72.
- Ngekpe BE, Charles K, Ode T. Evaluation of cement, lime and bagasse fibre ash waste admixture on swell–shrink control of road embankment materials. Glob Sci J. 2018;6(12):220-38.
- Essien U, Charles K. Comparative stabilization and model prediction of geotechnical parameters of Ebekpo residual soils, Akwa Ibom State, Nigeria. J Sci Eng Res. 2016;3(1):129-37.
- Okonkwo UN, Agunwamba JC, Iro UI. Geometric models for lateritic soil stabilized with cement and bagasse ash. Niger J Technol. 2016;35(4):769-77.
- Kale RY, Wawage R, Kale G. Effect of foundry waste on expansive soil (black cotton soil). Int J Sci Res Dev. 2019;7(2):1800-4.
- Jain T, Yadav G, Chandra B, Solanki CH. Comparative study of effect of waste material on black cotton soils in Surat region – a review. Indian Geotech Conf. 2015; Pune:12.
- Amu OO. Geotechnical properties of lateritic soil stabilized with sugarcane straw ash. Am J Sci Ind Res. 2011;12(11):35-47.
- Chittaranjan M, Ramesh HN, Mamatha R, Bindu RL. Agricultural wastes as soil stabilizers. Int J Earth Sci Eng. 2011;4(6):50-1.
- Laxmikant Y, Rao S, Kumar S, Sharma RK. Comparison of fly ash and rice husk ash stabilized black cotton soil. Int J Earth Sci Eng. 2011;4(6):42-5.
- Mu’azu MA. Evaluation of plasticity and particle size distribution characteristics of bagasse ash on cement treated lateritic soil. Leonardo J Sci. 2007;17:137-52.
- Omotosho O, Eze-Uzomaka OJ. Optimal stabilization of deltaic laterite. J South Afr Inst Civ Eng. 2008;50(2):10-7.
- Osinubi KJ, Thomas SA. Influence of compactive effort on bagasse ash treated soils. Niger J Soil Environ Res. 2007;7:92-101.
- Osinubi KJ, Eberemu AO, Aliyu J. Bagasse ash stabilization of lateritic soil. In: Muchie M, Baskaran A, editors. Appropriate technologies for environmental protection in the developing world. Dordrecht: Springer; 2009. p. 281-90.
- L. Shrivastava and P. K. Sharma, “Effect of incinerated bagasse ash on engineering properties of clayey soil,” Journal of Materials in Civil Engineering, vol. 27, no. 9, pp. 04014248, 2015.
- Davies and G. R. Higgo, “Ketyl radicals of benzophenone: Formation and reactivity,” Journal of Physical Chemistry, vol. 92, pp. 1376–1381, 1988.
- Moulya H.V, Vikram Kedambadi Vasu, Praveena B A., Study on acoustic properties of polyester– Fly ash CenosphereNanographene composites, Materials Today: Proceedings, https://doi.org/10.1016/j.matpr.2021.11.052
- B. Nagarnaik and S. M. Bajad, “Effect of bagasse ash on properties of cement concrete,” International Journal of Civil and Structural Engineering, vol. 3, no. 2, pp. 138–145, 2012.
- R. Karim, M. F. M. Zain, and M. Jamil, “Strength of mortar and concrete as influenced by bagasse ash: A review,” Construction and Building Materials, vol. 36, pp. 719–726, 2012.
- Pandey and R. K. Jain, “Utilization of industrial waste in construction materials,” International Journal of Environmental Sciences, vol. 3, no. 1, pp. 195–204, 2012.
- N. Ramesh, R. L. Bindu, and R. J. Mamatha, “Effect of sodium and calcium chloride on index properties of black cotton soils,” International Journal of Earth Sciences and Engineering, vol. 4, no. 6, pp. 11–14, 2011.
- Tadesse and A. Wubshet, “Effect of lime and bagasse ash on the engineering properties of expansive soil,” International Journal of Engineering Research and Applications, vol. 6, no. 6, pp. 53–58, 2016.
- Venkatesh and K. Reddy, “Soil stabilization using waste sawdust ash,” International Journal of Civil Engineering and Technology, vol. 8, no. 6, pp. 829–836, 2017.
- Batari, P. Kulshreshtha, and S. R. Choudhary, “Stabilization of black cotton soil with bagasse ash,” International Journal of Emerging Technology and Advanced Engineering, vol. 3, no. 11, pp. 225–232, 2013.
- Guttikonda and T. Abhilash, “Chemical stabilization of expansive soil using sodium chloride,” International Journal of Civil Engineering and Technology, vol. 8, no. 2, pp. 468–475, 2017.
- Zumrawi and A. E. Elsharief, “Stabilization of expansive subgrade soils using chloride salts,” International Journal of Engineering and Innovative Technology, vol. 4, no. 6, pp. 140–144, 2014.
- Zali and M. Rahman, “Stabilization of soft clay using GGBS and lime,” International Journal of Civil and Environmental Engineering, vol. 6, no. 9, pp. 688–692, 2012.
- Nath and P. Sarker, “Effect of GGBS on durability of fly ash geopolymer concrete,” Cement and Concrete Composites, vol. 55, pp. 205–214, 2015.
- Yarbasi, E. Kalkan, and S. Akbulut, “Modification of clayey soils using natural pozzolan,” Applied Clay Science, vol. 38, no. 1–2, pp. 194–202, 2007.
- Horpibulsuk, R. Rachan, and C. Suddeepong, “Strength development in cement stabilized silty clay: Laboratory and field study,” Soils and Foundations, vol. 50, no. 1, pp. 11–21, 2010.
- Brillet, M. Delamar, and A. Lesimple, “Radical polymerization initiated by benzophenone in organic systems,” Polymer, vol. 32, no. 6, pp. 985–990, 1991.
- A. Muntohar and J. Hantoro, “Influence of lime and bagasse ash on engineering properties of clay soils,” International Journal of Civil and Structural Engineering, vol. 2, no. 2, pp. 494 499, 2011.
- Ghazavi and M. Roustaie, “Stabilization of clay soils using lime and microsilica,” Geotechnical and Geological Engineering, vol. 28, no. 2, pp. 139–145, 2010.
- Kaniraj and V. Havanagi, “Behavior of cement-stabilized fiber-reinforced fly ash soil mixtures,” Journal of Geotechnical and Geoenvironmental Engineering, vol. 127, no. 7, pp. 574–584, 2001.
- Moulya HV, Chandrashekhar A. Experimental investigation of effect of recycled coarse aggregate properties on the mechanical and durability characteristics of geopolymer concrete. Mater Today Proc 2022;59:1700–7. https://doi.org/ 10.1016/j.matpr.2022.03.403.
- Bhuvaneshwari, R. G. Robinson, and S. R. Gandhi, “Stabilization of expansive soils using fly ash,” Fly Ash India 2005 Conference, New Delhi, 2005.
- Sabat, “Effect of phosphogypsum on the engineering properties of lime stabilized expansive soil,” Indian Highways, vol. 37, no. 5, pp. 21–27, 2009.
- Mahapatra, R. Patra, and S. Ray, “Stabilization of subgrade soil using rice husk ash and lime,” International Journal of Engineering Trends and Technology, vol. 5, no. 2, pp. 79–85, 2013.
- Kelly and C. Zweben, Comprehensive Composite Materials, vol. 1–5, Elsevier Science, 2000.
- Al-Rawas and H. Goosen, “Expansive Soils: Recent Advances in Characterization and Treatment,” Taylor & Francis, 2006.
- Arabi, A. Bouziani, and M. A. Hamad, “Pozzolanic behavior of bagasse ash in blended cement paste and mortar,” Journal of Adhesion Science and Technology, vol. 33, no. 18, pp. 1992–2008, 2019.
- Umesha, S. Ramachandra Murthy, and K. Ramesh, “Effect of pozzolanic bagasse ash on geotechnical behavior of soft soils,” Geotechnical Research, vol. 5, no. 4, pp. 168–177, 2018.
- Zhang and C. Wang, “Effect of benzophenone and derivatives on radical surface reactions in dry conditions,” Journal of Molecular Structure, vol. 993, pp. 114–119, 2011.
- Bureau of Indian Standards, IS 2720 (Part 7 & 10): Methods of Test for Soils Compaction and UCS, New Delhi, 1980.
- V. Ramana and S. N. Rao, “Use of industrial waste in geotechnical applications,” Indian Geotechnical Journal, vol. 32, no. 2, pp. 105–119, 2002.
- S. J. Thomas and J. R. Jones, “Role of chemical modifiers in hybrid polymer ceramic composites,” Journal of Materials Chemistry, vol. 21, no. 14, pp. 5152–5160, 2011.

Journal of Polymer & Composites
| Volume | 13 |
| Special Issue | 06 |
| Received | 08/08/2025 |
| Accepted | 03/09/2025 |
| Published | 16/12/2025 |
| Publication Time | 130 Days |
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