An Ultraviolet-Curable Nano Cerium Oxide Coating and Its Anti Ultraviolet /Blue Light Properties

Year : 2025 | Volume : 13 | Issue : 06 | Page : 306 324
    By

    Guoyao Li,

  • Yihua Sun,

  • Rong Zhong,

  1. Student, Department of Materials and Chemistry, School of Environmental & Chemical Engineering, Nanchang Hangkong University, Nanchang, China
  2. Student, Department of Materials and Chemistry, School of Environmental & Chemical Engineering, Nanchang Hangkong University, Nanchang, China
  3. Associate Professor, Department of Materials and Chemistry, School of Environmental & Chemical Engineering, Nanchang Hangkong University, Nanchang, China

Abstract

An ultraviolet (UV)-curable nano cerium oxide (CeO2) coating with enhanced blue light and UV shielding properties, prepared using an ultrasonic blending method, is presented. This study systematically investigated the optimal synthesis conditions for nano CeO2, as well as the effects of UV intensity and CeO2 concentration on the curing kinetics and blue/UV light shielding performance of the UV-curable nanocomposite. The results indicate that the synthesized nano CeO2 exhibited improved mechanical properties and reduced agglomeration compared to commercially available CeO2. Furthermore, the UV-cured PUA/CeO2 composite demonstrated superior reflection and scattering capabilities for both blue and UV light compared with composites containing commercial CeO2 at equivalent additive concentrations. These findings highlight the potential of the proposed nanocoating for applications requiring robust UV and blue light shielding performance. When the nano CeO2 content is 4%, the shielding rates of the coating for UV and blue light are approximately 40% and 34%, respectively. The cured composites have excellent mechanical properties. Its pencil hardness can reach 4H, adhesion, 4B, flexibility, 5 and has good abrasion resistance. This indicates its potential for industrial applications. The UV cured nano-coating is expected to be used in the field of electronic products, such as display screen protective layers for mobile phones, ipad, tablets, etc., to reduce the damage to human vision caused by long-term use of these products.

Keywords: UV-curable coating; nano CeO2; UV, blue light and shielding

[This article belongs to Journal of Polymer and Composites ]

aWQ6MjMzODIzfGZpbGVuYW1lOmU1Mzg0Zjg4LWZpLmF2aWZ8c2l6ZTp0aHVtYm5haWw=
How to cite this article:
Guoyao Li, Yihua Sun, Rong Zhong. An Ultraviolet-Curable Nano Cerium Oxide Coating and Its Anti Ultraviolet /Blue Light Properties. Journal of Polymer and Composites. 2025; 13(06):306-324.
How to cite this URL:
Guoyao Li, Yihua Sun, Rong Zhong. An Ultraviolet-Curable Nano Cerium Oxide Coating and Its Anti Ultraviolet /Blue Light Properties. Journal of Polymer and Composites. 2025; 13(06):306-324. Available from: https://journals.stmjournals.com/jopc/article=2025/view=233826


Browse Figures

References

  1. Bretterbauer, K.; Holzmann, C.; Rubatscher, E.; Schwarzinger, C.; Roessler, A.; Paulik, C., UV-curable coatings of highly crosslinked trimethylmelamine based acrylates and methacrylates. European Polymer Journal 2013, 49 (12), 4141-4148.
  2. Liu, F.; Liu, A.; Tao, W.; Yang, Y., Preparation of UV curable organic/inorganic hybrid coatings-a review. Progress in Organic Coatings 2020, 145, 105685.
  3. Yang, Z.; Wicks, D. A.; Hoyle, C. E.; Pu, H.; Yuan, J.; Wan, D.; Liu, Y., Newly UV-curable polyurethane coatings prepared by multifunctional thiol- and ene-terminated polyurethane aqueous dispersions mixtures: Preparation and characterization. Polymer 2009, 50 (7), 1717-1722.
  4. Yang, Z.; Wicks, D. A.; Yuan, J.; Pu, H.; Liu, Y., Newly UV-curable polyurethane coatings prepared by multifunctional thiol- and ene-terminated polyurethane aqueous dispersions: Photopolymerization properties. Polymer 2010, 51 (7), 1572-1577.
  5. Park, M.; Moon, H.; Jung, H. W.; Paik, H.-j.; Noh, S. M., Characteristics of Colorless Fluorinated Imide-Based Oligomers for UV-Curing Coatings. ACS Applied Polymer Materials 2024, 6 (17), 11039-11049.
  6. Liu, F.; Wang, Y.; Xue, X.; Yang, H., UV curable EA-Si hybrid coatings prepared by combination of radical and cationic photopolymerization. Progress in Organic Coatings 2015, 85, 46-51.
  7. Xu, T.; Zvonkina, I. J.; Soucek, M. D., UV-curable polyurethane inorganic–organic hybrid coatings. Journal of Coatings Technology and Research 2021, 18 (6), 1461-1479.
  8. Xiao, T.; Geng, L.; Dai, Y.; Zhao, J.; Liu, C., UV-cured polymer aided phase change thermal energy storage: Preparation, mechanism and prospects. Journal of Energy Storage 2023, 64, 107066.
  9. Akarsu, E.; Uslu, R., Light-activated hybrid organic/inorganic antimicrobial coatings. Journal of Sol-Gel Science and Technology 2018, 87 (1), 183-194.
  10. Mano, I.; Taniguchi, J., Fabrication of an antireflection structure on an aspherical lens using a UV-curable inorganic–organic hybrid polymer. Japanese Journal of Applied Physics 2019, 58 (SD), SDDJ03.
  11. Ma, Y.; Chen, L.; Ye, Y.; Wan, H.; Zhou, H.; Chen, J., Preparation and tribological behaviors of a novel organic-inorganic hybrid resin bonded solid lubricating coating cured by ultraviolet radiation. Progress in Organic Coatings 2019, 127, 348-358.
  12. Manchanda, H.; Mannari, V., Super photo-base initiated organic-inorganic hybrid coatings by plural-cure mechanisms. Progress in Organic Coatings 2019, 127, 222-230.
  13. Ma, H.; Zhou, L.; Han, C.; Zhang, C.; Zhang, L., The fabrication of novel optical diffusers based on UV-cured polymer dispersed liquid crystals. Liquid Crystals 2019, 46 (1), 138-144.
  14. Quan, J.; Dong, T.; Shi, Z.; Xv, B.; Hu, H.; Hao, S.; Fan, H.; Huang, X.; Fan, M.; Cheng, Q.; Hang, Z., Development and characteristics of UV-photocurable anticorrosive MXene coatings. AIP Advances 2024, 14 (3) , 665.
  15. Yamagishi, R.; Miura, S.; Yabu, K.; Ando, M.; Hachikubo, Y.; Yokoyama, Y.; Yasuda, K.; Takei, S., Fabrication Technology of Self-Dissolving Sodium Hyaluronate Gels Ultrafine Microneedles for Medical Applications with UV-Curing Gas-Permeable Mold. Gels 2024, 10 (1), 65.
  16. Barman, B. K.; Sele Handegård, Ø.; Hashimoto, A.; Nagao, T., Carbon Dot/Cellulose-Based Transparent Films for Efficient UV and High-Energy Blue Light Screening. ACS Sustainable Chemistry & Engineering 2021, 9 (29), 9879-9890.
  17. Li, Y.; Bian, X.; Wu, W.; Dong, H., Synthesis, characterization, and double shielding performance for ultraviolet and short-wave blue light of ceria-based materials. Ceramics International 2024, 50 (22, Part C), 48592-48599.
  18. Hsu, C.-H.; Liu, T.-X.; Hsieh, I.-C.; Han, P.; Lien, S.-Y., Blue-light shielding, hard and hydrophobic inorganic and organic silicon stack-films prepared on flexible substrates. Thin Solid Films 2016, 618, 146-150.
  19. Wittawat, R.; Rittipun, R.; Jarasfah, M.; Nattaporn, B., Synthesis of ZnO/TiO2 spherical particles for blue light screening by ultrasonic spray pyrolysis. Materials Today Communications 2020, 24, 101126.
  20. Yang, Y.; Ju, Y.; Li, Y.; Yin, L.; Chen, L.; Gu, P.; Zhang, J., Transparent Nanostructured BiVO4 Double Films with Blue Light Shielding Capabilities to Prevent Damage to ARPE-19 Cells. ACS Applied Materials & Interfaces 2020, 12 (18), 20797-20805.
  21. Su, K.; Tao, Y.; Zhang, J., Highly transparent plasticized PVC composite film with ideal ultraviolet/high-energy short-wavelength blue light shielding. Journal of Materials Science 2021, 56 (30), 17353-17367.
  22. Liu, X.; Zhou, Q.; Lin, H.; Wu, J.; Wu, Z.; Qu, S.; Bi, Y., The Protective Effects of Blue Light-Blocking Films With Different Shielding Rates: A Rat Model Study. Translational Vision Science & Technology 2019, 8 (3), 19-19.
  23. Han, C.; Wang, F.; Gao, C.; Liu, P.; Ding, Y.; Zhang, S.; Yang, M., Transparent epoxy–ZnO/CdS nanocomposites with tunable UV and blue light-shielding capabilities. Journal of Materials Chemistry C 2015, 3 (19), 5065-5072.
  24. Li, H.; Wang, J.; Yang, J.; Zhang, J.; Ding, H., Large CeO2 nanoflakes modified by graphene as barriers in waterborne acrylic coatings and the improved anticorrosion performance. Progress in Organic Coatings 2020, 143, 105607.
  25. Rajendran, P.; Muthuraj, A.; Rajagounder, N. E., Review on CeO2-Based Corrosion Coatings. Transactions of the Indian Ceramic Society 2022, 81 (4), 158-174.
  26. Liu, K.-Q.; Kuang, C.-X.; Zhong, M.-Q.; Shi, Y.-Q.; Chen, F., Synthesis, characterization and UV-shielding property of polystyrene-embedded CeO2 nanoparticles. Optical Materials 2013, 35 (12), 2710-2715.
  27. Zhao, Y.; Shi, L.; Tang, A.; Song, N.; Tang, S.; Ding, P., Enhanced blue light shielding property of light-diffusion polycarbonate composites by CeO2-coated silicate microspheres. Functional Materials Letters 2015, 08 (06), 1550074.
  28. Paier, J.; Kropp, T.; Penschke, C.; Sauer, J., Stability and migration barriers of small vanadium oxide clusters on the CeO2(111) surface studied by density functional theory. Faraday Discussions 2013, 162 (0), 233-245.
  29. Chang, S.; Bao, H.; Huang, W., Size-Dependent Redispersion or Agglomeration of Ag Clusters on CeO2. The Journal of Physical Chemistry C 2022, 126 (28), 11537-11543.
  30. Kravtsov, A. A.; Chikulina, I. S.; Tarala, V. A.; Evtushenko, E. A.; Shama, M. S.; Tarala, L. V.; Malyavin, F. F.; Vakalov, D. S.; Lapin, V. A.; Kuleshov, D. S., Novel synthesis of low-agglomerated YAG:Yb ceramic nanopowders by two-stage precipitation with the use of hexamine. Ceramics International 2019, 45 (1), 1273-1282.
  31. Waseem, S.; Zeeshan, T.; Tariq, H.; Majid, F.; Ali, M. D.; Kayani, Z. N.; Amami, M., The influence of transition metals (Fe, Co) on the structural, magnetic and optical properties of TiO2 nanoparticles synthesized by the hydrothermal method. Applied Physics A 2022, 128 (8), 690.
  32. Predoana, L.; Stanciu, I.; Anastasescu, M.; Calderon-Moreno, J. M.; Stoica, M.; Preda, S.; Gartner, M.; Zaharescu, M., Structure and properties of the V-doped TiO2 thin films obtained by sol–gel and microwave-assisted sol–gel method. Journal of Sol-Gel Science and Technology 2016, 78 (3), 589-599.
  33. Guha, A., Mathur, H., Malik, H., Enhancing grid resilience with hybrid STATCOM and optimal power flow control for renewable integration, Ain Shams Engineering Journal, 2024, 15(9): 102759. / doi.org/10.1016/j.asej.2024.102759.
  34. Naveenkumar R., Shaik S., Suresh, S., Khan, M., Alruban, A., Otaibi, S., Performance enhancement of a solar still desalination system using activated carbon derived from sugarcane biomass, Ain Shams Engineering Journal, 2024, 15(8): 102759. / doi.org/10.1016/j.asej.2024.102759.
  35. Lopes, Ana., Silva, J., Machado, J., Ramalho A., Soares, F., Mechanical and Microstructural Characterization of Carbon Fiber Reinforced Polymers Produced by Additive Manufacturing, Fibers 2022, 10 (4): 32. / doi.org/10.3390/fib10040032.
  36. Li, Y., Wang, Y., Li, C., He, Y., Jiang, H., Zhang, Y., Song, Y., Zheng Q., A self-healing hydrogel based on polyacrylamide and sodium alginate with mechanical and swelling properties tuned via cross-linking density. Journal of Polymer Research, 2024, 71, doi.org/10.1007/s10965-024-03946-0.
  37. Rahman, M., Khusairy M., Bakri, B., Hamdan, S., Rahman M., Mechanical and Dynamic Properties of Bamboo Fiber-Reinforced Polypropylene Composites, Journal of Composites Science 2023, 7(4): 136. /10.3390/jcs7040136
  38. Shyu, J.-J.; Huang, Y.-H., Development of blue-light absorbing silicate glasses through codoping with TiO2, CeO2, Fe2O3, and Bi2O3. Optical Materials 2024, 155, 115899.
  39. Wang, W.; Zhang, B.; Jiang, S.; Bai, H.; Zhang, S. Use of CeO2Nanoparticles to Enhance UV-Shielding of Transparent Regenerated Cellulose Films Polymers, 2019, org/10.3390/polym11030458.
  40. Li, P.; Zou, G.; Chang, L.; Guo, W.; Tian, K.; Li, X.; Wang, H., UV-stimulated self-healing SiO2/CeO2microcapsule with excellent UV-blocking capability in epoxy coating. Bulletin of Materials Science 2023, 46 (3), 159.
  41. Rahman, M. M.; Suleiman, R.; Zahir, M. H.; Helal, A.; Kumar, A. M.; Haq, M. B. Multi Self-Healable UV Shielding Polyurethane/CeO2 Protective Coating: The Effect of Low-Molecular-Weight Polyols Polymers, 2020,org/10.3390/polym12091947.

Regular Issue Subscription Original Research
Volume 13
Issue 06
Received 25/08/2025
Accepted 20/09/2025
Published 18/10/2025
Publication Time 54 Days


Login


My IP

PlumX Metrics