Ananda M N,
Sudheer Reddy J,
Vikram Kedambadi Vasu,
Madhusudhan,
- Assistant Professor, Department of Mechanical Engineering, Centre for Additive Manufacturing, Nitte (Deemed to be University), Nitte Meenakshi Institute of Technology, Bengaluru, Karnataka, India
 - Professor, Department of Mechanical Engineering, Centre for Additive Manufacturing, Nitte (Deemed to be University), Nitte Meenakshi Institute of Technology, Bengaluru, Karnataka, India
 - Assistant Professor, Department of Mechanical Engineering, Centre for Additive Manufacturing, Nitte (Deemed to be University), Nitte Meenakshi Institute of Technology, Bengaluru, Karnataka, India
 - Assistant Professor and Deputy Controller of Examinations, Department of Mechanical Engineering, Presidency School of Engineering, Bengaluru, Karnataka, India
 
Abstract
This study investigates the thermal and mechanical properties of Polyetheretherketone (PEEK) polymer and Glass Fiber (GF) reinforced PEEK polymer fabricated using the Fused Filament Fabrication (FFF) process. Specimens were printed in three building orientations—X, Y, and 45°—to evaluate the influence of layer deposition on polymer material performance. Tensile and flexural tests revealed that GF-PEEK polymer exhibited significantly higher Ultimate Tensile Strength (110 MPa in X-orientation), Young’s Modulus (4.5 GPa), and Flexural Strength (180 MPa) compared to PEEK polymer, attributed to the reinforcing effect of Glass Fibers. However, a reduction in Elongation at Break indicated increased brittleness. The X-orientation showed superior mechanical properties due to layer alignment with the loading direction, while the 45° orientation demonstrated lower values due to increased interlayer shear. Thermal analysis using TGA and DSC demonstrated enhanced thermal stability and degree of crystallinity for GF-PEEK polymer, with an initial decomposition temperature of 590 °C and a 38% crystallinity, owing to the nucleating effect of Glass Fibers. Comparative analysis with existing literature confirmed the positive impact of Glass Fiber reinforcement on both mechanical and thermal performance. This study establishes the potential of GF-PEEK polymer for high-performance applications requiring enhanced stiffness, strength, and thermal resistance. The novelty of this research lies in the comprehensive evaluation of build orientations and their impact on mechanical and thermal properties, providing new insights for optimizing FFF-printed polymer composite materials. The findings also highlight the significant role of build orientation in optimizing mechanical behavior, paving the way for future advancements in 3D-printed polymer composite materials.
Keywords: PEEK, glass fiber, fused filament fabrication, mechanical properties, thermal analysis.
[This article belongs to Special Issue under section in Journal of Polymer and Composites (jopc)]
Ananda M N, Sudheer Reddy J, Vikram Kedambadi Vasu, Madhusudhan. Investigation of Mechanical and Thermal Behavior of Glass Fiber–Enhanced PEEK Parts Produced via Fused Filament Fabrication. Journal of Polymer and Composites. 2025; 13(06):65-78.
Ananda M N, Sudheer Reddy J, Vikram Kedambadi Vasu, Madhusudhan. Investigation of Mechanical and Thermal Behavior of Glass Fiber–Enhanced PEEK Parts Produced via Fused Filament Fabrication. Journal of Polymer and Composites. 2025; 13(06):65-78. Available from: https://journals.stmjournals.com/jopc/article=2025/view=230495
References
- Rubino F, Nisticò A, Tucci F, Carlone P. Marine application of fiber reinforced composites: a review. Journal of Marine Science and Engineering. 2020 Jan 6;8(1):26.
 - Karataş MA, Gökkaya H. A review on machinability of carbon fiber reinforced polymer (CFRP) and glass fiber reinforced polymer (GFRP) composite materials. Defence Technology. 2018 Aug 1;14(4):318-26.
 - Thomas D. Enhancing the electrical and mechanical properties of graphene nanoplatelet composites for 3D printed microsatellite structures. Additive Manufacturing. 2021 Nov 1;47:102215.
 - Xu X, Wei K, Mei M, Li M, Yang X. An ultrasound-assisted resin transfer molding to improve the impregnation and dual-scale flow for carbon fiber reinforced resin composites. Composites Science and Technology. 2024 Aug 18;255:110710.
 - Kabir SMF, Mathur K, Seyam AM. A critical review on 3D printed continuous fiber-reinforced composites: history, mechanism, materials and properties. Compos Struct. 2020;232:111476.
 - He Y, Mei M, Wei K, et al. Interlaminar shear behaviour and meso damage suppression mechanism of stitched composite under short beam shear using X-ray CT. Compos Sci Technol. 2022;218:109189.
 - Safari F, Kami A, Abedini V. 3D printing of continuous fiber reinforced composites: a review of the processing, pre- and post-processing effects on mechanical properties. Polym Polym Compos. 2022;30.
 - Hou Z, Tian X, Zhang J, et al. Optimization design and 3D printing of curvilinear fiber reinforced variable stiffness composites. Compos Sci Technol. 2021;201:108502.
 - An Y, Myung JH, Yoon J, et al. Three-dimensional printing of continuous carbon fiber-reinforced polymer composites via in-situ pin-assisted melt impregnation. Addit Manuf. 2022;55:102860.
 - Hu B, Duan X, Xing Z, et al. Improved design of fused deposition modeling equipment for 3D printing of high-performance PEEK parts. Mech Mater. 2019;137:103139.
 - Zhang M, Tian X, Cao H, et al. 3D printing of fully recyclable continuous fiber self-reinforced composites utilizing supercooled polymer melts. Compos Part A Appl Sci Manuf. 2023;169:107513.
 - Liu G, Xiong Y, Zhou L. Additive manufacturing of continuous fiber reinforced polymer composites: design opportunities and novel applications. Compos Commun. 2021;27:100907.
 - Tian X, Liu T, Yang C, et al. Interface and performance of 3D printed continuous carbon fiber reinforced PLA composites. Compos Part A Appl Sci Manuf. 2016;88:198–205.
 - Tian X, Liu T, Wang Q, et al. Recycling and remanufacturing of 3D printed continuous carbon fiber reinforced PLA composites. J Clean Prod. 2017;142:1609–18.
 - Li N, Li Y, Liu S. Rapid prototyping of continuous carbon fiber reinforced polylactic acid composites by 3D printing. J Mater Process Technol. 2016;238:218–25.
 - Pertuz AD, Díaz-Cardona S, González-Estrada OA. Static and fatigue behaviour of continuous fibre reinforced thermoplastic composites manufactured by fused deposition modelling technique. Int J Fatig. 2020;130:105275.
 - Liu T, Tian X, Zhang Y, et al. High-pressure interfacial impregnation by microscrew in-situ extrusion for 3D printed continuous carbon fiber reinforced nylon composites. Compos Part A Appl Sci Manuf. 2020;130:105770.
 - Zhang J, Zhou Z, Zhang F, et al. Performance of 3D-printed continuous-carbon-fiber-reinforced plastics with pressure. Mater. 2020;13.
 - Zhang R, Yu L, Chen K, et al. Amelioration of interfacial properties for CGF/PA6 composites fabricated by ultrasound-assisted FDM 3D printing. Compos Commun. 2023;39:101551.
 - Chen K, Yu L, Cui Y, et al. Optimization of printing parameters of 3D-printed continuous glass fiber reinforced polylactic acid composites. Thin-Walled Struct. 2021;164:107717.
 - Barış Vatandaş B, Usun A, Yıldız N, et al. Additive manufacturing of PEEK-based continuous fiber reinforced thermoplastic composites with high mechanical properties. Compos Part A Appl Sci Manuf. 2023;167:107434.
 - Luo M, Tian X, Shang J, et al. Impregnation and interlayer bonding behaviours of 3D-printed continuous carbon-fiber-reinforced poly-ether-ether-ketone composites. Compos Part A Appl Sci Manuf. 2019;121:130–8.
 - Liu X, Shan Z, Liu J, et al. Mechanical and electrical properties of additive manufactured high-performance continuous glass fiber reinforced PEEK composites. Compos Part B. 2022;247:110292.
 - Chu XX, Wu ZX, Huang RJ, et al. Mechanical and thermal expansion properties of glass fibers reinforced PEEK composites at cryogenic temperatures. Cryogenics. 2010;50:84–8.
 - Sathishkumar TP, Satheeshkumar S, Naveen J. Glass fiber-reinforced polymer composites – a review. J Reinf Plast Compos. 2014;33.
 - Akhoundi B, Nabipour M, Kordi O, et al. Calculating printing speed in order to correctly print PLA/continuous glass fiber composites via fused filament fabrication 3D printer. J Thermoplast Compos Mater. 2023;36.
 - Caminero MA, Chacón JM, García-Moreno I, et al. Impact damage resistance of 3D printed continuous fibre reinforced thermoplastic composites using fused deposition modelling. Compos Part B. 2018;148:93–103.
 - Vasu VK, Praveena BA, Santhosh N, Amanullah MI. Mechanical and fracture property optimization of graphene-SiO₂-reinforced epoxy-PLA nanocomposites for biomedical applications. Results Chem. 2025;13. ISSN: 2211-7156.
 - Chacón JM, Caminero MA, Núñez PJ, et al. Additive manufacturing of continuous fibre reinforced thermoplastic composites using fused deposition modelling: effect of process parameters on mechanical properties. Compos Sci Technol. 2019;181:107688.
 - Kousiatza C, Tzetzis D, Karalekas D. In-situ characterization of 3D printed continuous fiber reinforced composites: a methodological study using fiber Bragg grating sensors. Compos Sci Technol. 2019;174:134–41.
 - Morales U, Esnaola A, Iragi M, et al. Quasi-static and dynamic crush behaviour of 3D printed thin-walled profiles reinforced with continuous carbon and glass fibres. Compos Part B. 2021;217:108865.
 - Chabaud G, Castro M, Denoual C, et al. Hygromechanical properties of 3D printed continuous carbon and glass fibre reinforced polyamide composite for outdoor structural applications. Addit Manuf. 2019;26:94–105.
 - Ananda MN, Sudheer Reddy J, Vijay Kumar S, Vikram KV, Mahesh Kumar. Evaluation of mechanical properties of carbon reinforced composite for different process parameters using FDM. J Polym Compos. 2022;11(13):218–28. ISSN: 2321-2810. doi:10.37591/JoPC.
 - Praveena BA, Buradi A, Santhosh N, Vasu VK, Hatgundi J, Huliya D. Study on characterization of mechanical, thermal properties, machinability and biodegradability of natural fiber reinforced polymer composites and its applications, recent developments, and future potentials: A comprehensive review. Mater Today Proc. 2022;52(3):1255–59. doi:10.1016/j.matpr.2021.11.049.
 - Vaneker THJ. Material extrusion of continuous fiber reinforced plastics using commingled yarn. Procedia CIRP. 2017;66:317–22.
 - Amanat N, Chaminade C, Grace J, et al. Transmission laser welding of amorphous and semi-crystalline poly-ether–ether–ketone for applications in the medical device industry. Mater Des. 2010;31:4823–30.
 - Deuk JK, Chi HP, Sang YN. Molecular dynamics simulations of modified PEEK polymeric membrane for fuel cell application. Int J Hydrogen Energy. 2016;41.
 - Luo M, Tian X, Shang J, et al. Bi-scale interfacial bond behaviors of CCF/PEEK composites by plasma-laser cooperatively assisted 3D printing process. Compos Part A Appl Sci Manuf. 2020;131:105812.
 - Chen Y, Shan Z, Yang X, et al. Preparation of CCF/PEEK filaments together with property evaluation for additive manufacturing. Compos Struct. 2022;281:114975.
 - Qin Y, Ge G, Yun J, et al. Enhanced impregnation behavior and interfacial bonding in CF/PEEK prepreg filaments for 3D printing application. J Mater Res Technol. 2022;20:4608–23.
 - Chen Y, Shan Z, Yang X, et al. Influence of preheating temperature and printing speed on interlaminar shear performance of laser-assisted additive manufacturing for CCF/PEEK composites. Polym Compos. 2022;43:3412–25.
 - Yadav SPS, Shankar VK, Avinash L, Buradi A, Praveena BA, Vasu VK, Vinayaka N, Kumar KD. Development of 3D Printed Electromyography Controlled Bionic Arm. In: Srinivasa Pai P, Krishnaraj V, editors. Sustainable Machining Strategies for Better Performance. Lecture Notes in Mechanical Engineering. Singapore: Springer; 2022. https://doi.org/10.1007/978-981-16-2278-6_2.
 - Yu X, Song W, Zheng J, et al. Effects of low-pressure annealing on the performance of 3D printed CF/PEEK composites. Chin J Mech Eng Addit Manuf Front. 2023;2:100076.
 - Lokesh N, Praveena B, Sudheer Reddy J, Vikram Kedambadi V, Vijaykumar S. Evaluation on effect of printing process parameter through Taguchi approach on mechanical properties of 3D printed PLA specimens using FDM at constant printing temperature. Mater Today Proc. 2021.
 - Mayer C, Wang X, Neitzel M. Macro- and micro-impregnation phenomena in continuous manufacturing of fabric reinforced thermoplastic composites. Compos Part A Appl Sci Manuf. 1998;29:783–93.
 

Journal of Polymer and Composites
| Volume | 13 | 
| Special Issue | 06 | 
| Received | 27/03/2025 | 
| Accepted | 22/07/2025 | 
| Published | 01/09/2025 | 
| Publication Time | 158 Days | 
PlumX Metrics
