Study of Binary Systems Based on Butadiene-Terephthalate Rubber and Astragals and Its Rheological Properties

Year : 2025 | Volume : 13 | Issue : 05 | Page : 153 169
    By

    Shixaliyev Kerem,

  1. Professor, Department of Organic Substances and Technology of Macromolecular Compounds Azerbaijan State Oil and Industry University, Baku, Azerbaijan

Abstract

Study of binary systems based on butadiene-terephthalate rubber and Astragals and it In this work, Nano sized astragals was used for the first time to modify butadiene terephthalate rubber. For this purpose, compositions were prepared to study the properties of butadiene terephthalate rubber with different astragals contents of 1, 3 and 5 mass parts. Their results were compared with the control composition without nanoparticles. The presence of astragals and its distribution in the matrix of butadiene terephthalate rubber was confirmed by determining the melt flow indices of the binary system and IR analysis. The effect of Nano sized astragals modification on the main rheological properties of polybutylene terephthalate was studied. The effect of Nano sized astragals on the kinetics of vulcanization was studied To select the vulcanization mode of the rubber compound, the optimum and plateau of the vulcanization process were determined, and it was established that the onset of vulcanization begins at 127 °C and ends at 155–157 °C. The vulcanization process was carried out at a temperature of 1750C and The main indicators of the obtained vulcanizate were determined by the physical and mechanical properties of the vulcanizates by known methods. The obtained data were compared with reference rubbers. In terms of strength, the proposed rubber exceeds the standard by 1.2 times. The ultimate strength of the vulcanizate sample is achieved up to 26 MPa.

Keywords: Astragals, butadiene terephthalate rubber, modification, vulcanization, rheology

[This article belongs to Journal of Polymer and Composites ]

How to cite this article:
Shixaliyev Kerem. Study of Binary Systems Based on Butadiene-Terephthalate Rubber and Astragals and Its Rheological Properties. Journal of Polymer and Composites. 2025; 13(05):153-169.
How to cite this URL:
Shixaliyev Kerem. Study of Binary Systems Based on Butadiene-Terephthalate Rubber and Astragals and Its Rheological Properties. Journal of Polymer and Composites. 2025; 13(05):153-169. Available from: https://journals.stmjournals.com/jopc/article=2025/view=223054


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References

  1. Zaikin A.E., Bobrov G.B.: Visokomolekulyarniye soyedineniya, Seriya A, 2012, 54, 1275.
  2. Zaikin A.E., Bobrov G.B. / Compatibilization of mixtures of incompatible polymers by filling // High-molecular compounds. -2012.-№8.-p.1275-1282
  3. Klezmer V.N., Surikov P.V.//Phase equilibria in three-component mixtures of polymers/High-molecular compounds. -2012.-No.11.-p.1602-1609
  4. Belov N.A., Safronov A.P., Yu.P. Yampolsky//Inverted gas chromatography and thermodynamics of sorption in polymers. /High-molecular compounds. – 2012.-No.11.-p.1631-1647
  5. Bunjali B., Yudistira I., JAriah B, Sukria L.//Study on properties of Polymer Blends from Polypropylene with Polycaprolactone and their Biodegradability/Polymer Journal, -2007 – Vol.39, No.12.-pp. 1337-1344
  6. Kuleznev V.N. Polymer mixtures and alloys. – St. Petersburg: NOT Publishing House, 2013, 214 p.
  7. Kablov, V.F. Polymer materials with functionally active components. Research and technology (part 1): monograph / V.F. Kablov, N.A. Keibal; VPI (branch) of VolGTU. – Volgograd, 2017. – 406 p.
  8. Vlasov S. V., Kandyrin L. B., Kuleznev V. N. et al. Fundamentals of Plastics Processing Technology. — Moscow: Chemistry, 2004. — Chapter 9 “Mixing Polymers, Blends and Polymer Alloys”.
  9. Polymer Blends. Edited by D. Paul, K. Bucknell; trans. from English edited by V. N. Kuleznev. — St. Petersburg: Scientific Foundations and Technologies, 2009. Callister W. D., Retwitch D. J. Materials Science: From Technology to Application (Metals, Ceramics, Polymers). — St. Petersburg: Scientific Foundations and Technologies, 2011.
  10. Semakov A. V., Kulichikhin V. G. Self-organization and Elastic Instability in Polymer Flow // High-Molecular. 51. – No. 11. – 2054-2070 (2009).
  11. Kuleznev V.N., Kandyrin L.B. Oligomer mixtures: rheology, structure, properties. // Vysokomolsk. soed. A50. – No. 7. – 757-766 (2008).
  12. Vlasov S.V., Kandyrin L.B., Kuleznev V.N., Markov A.V., Simonov-Emelyanov I.D., Surikov P.V., Ushakova O.B. Fundamentals of plastics processing technology. – Moscow: Chemistry, 2004. – 596 p.
  13. Kablov, V.F. System technology of oligomer rubber compositions “Oligomers 2009” Coll. articles of the X international conference on physical chemistry of oligmers, VolGTU. – Volgograd, 2009, – P. 162-191.
  14. Kablov, V.F., Keibal, N.A., Novopoltseva, O.M. Fire-protective polymeric materials with functionally active components: monograph // VPI (branch) 15. VolGTU. – Volgograd: IUNL VolGTU, 2016. – 203 p.
  15. Gambaro D.S. Botanical-geographical analysis of Astaxanthin and sedum species of Nakhichevan MR // Institute of Genetic Resources of ANAS, 2012, p. 210-215
  16. Gambaro D.S. Bio ecological features of the rare species of Astaxanthin species common in the territory of Nakhichevan Autonomous Republic // Nakhichevan State University, No. 1, Nakhichevan 2012 p. 49-52
  17. Gambaro D.S. The history of the study of species belonging to the genus Astragals L. distributed in Nakhichevan MR // Scientific works of the Botany Institute of ANAS, volume XXXII, Baku, 2012 p. 50-53
  18. Gambaro D.S. Morphological characteristics and life forms of Astaxanthin and Astragals species distributed in Nakhichevan MR flora // Azerbaijan National Academy of Sciences. Works of the Central Botanical Garden vol. XI. Baku-2013. pp. 327-333
  19. Gambaro D.S. Astragals in the low mountain belt in Nakhichevan Autonomous Republic Distribution of L. species //Nakhichevan State University Nakhichevan 2013, No. 1, p. 56-60
  20. Gambaro D.S. On the high mountain belt in Nakhichevan Autonomous Republic Distribution of Astragals L. species // Nakhichevan State University Nakhichevan 2013, No. 1, etc. 56-59
  21. Gambaro D.S. Distribution of Astaxanthin potlach species in the Nakhichevan Autonomous Republic by altitude zones // News of the Nakhichevan branch of ANAS. Nakhichevan Tosi 2013, No. 2, p. 154-159
  22. Gambaro D.S. Distribution of Astaxanthin and Astragals species in semi-desert vegetation in the territory of Nakhichevan Autonomous Republic // Nakhichevan State University Nakhichevan 2014, No. 8, pp. 24-27
  23. Gambaro D.S. Astragals in the middle mountainous belt in Nakhchivan Autonomous Republic distribution of species // Nakhichevan State University Nakhichevan, 2014 #4, p. 57-61
  24. Gambaro D.S. Floristic analysis of Astaxanthin and Astragals species distributed in the flora of Nakhichevan Autonomous Republic // Azerbaijan National Academy of Sciences, Ganja branch, 2015, p. 35-45
  25. Gambaro D.S. Distribution of Astaxanthin and Astragals species in the flora of the Nakhchivan Autonomous Republic by altitude zones, phytocoenological characteristics and importance // Nakhichevan State University, Keyret-2015 No. 4, pp. 44-53
  26. Gambaro D.S. Dye properties of some species belonging to the genera Astaxanthin and Astragals distributed in the territory of the Nakhichevan Autonomous Republic // Actual problems of modern biology and chemistry. Ganja State University, 2015, p. 32-36
  27. S. Gambaro, M.Z. Piriyev. Shrubs and shrubs of the genus Astaxanthin distributed in the territory of Nakhichevan MR // Nakhichevan State University, 2016, pp. 50-56
  28. Qanbarov D.Ş., Distribution of the species included in the genera Astaxanthin and Astragals in forest-shrub vegetation // Actual problems of modern biology and chemistry. Ganja State University, 2016, p. 99-101
  29. Gambaro D.Sh., Ibrahimov A., Nabiyeva F. Geographical area of ​​Astragals species in Nakhichevan Autonomous Republic // Kafka’s Universities Fen Baillie Dergisi, Institute of Natural and Applied Science journal, 2011. p. 58-64
  30. Gambaro D.Sh., Spreading of Astaxanthin and Astragals species in the mountainous-xerophyte plant zones of the Nakhichevan Autonomous Republic // e-Library Science Research Journal Impact Factor 0,109: 2014. p.1-3
  31. Shixaliyev Kerem. Paint and Varnish Materials Based on Epoxy Novolac Oligomers2020, Jour of Adv Research in Dynamical & Control Systems, 12, Special Issue-02,  .рр351-358: https://www.scopus.com/authid/detail.uri?authorId=57215836118
  32. Shixaliyev Kerem Application of Heavy Metal Ions Separation from Contaminated Water in Industry,2020, Jour of Adv Research in Dynamical & Control Systems, Vol. 12, Special Issue-02, рр351-358https://www.scopus.com/authid/detail.uri?authorId=57215836118
  33. Şıxəliyev Kerem Application of Heavy Metal Ions Separation from Contaminated Water in Industry,2021, International Journal of Innovative Technology and Exploring Engineering (IJITEE) ISSN: 2278-3075, Volume-9 Issue-6, April 2021.рр132-134, https://www.scopus.com/authid/detail.uri?origin=resultslist&authorId=57215860756
  34. .Kerem Shixaliyev Paint and varnish materials based on epoxy novolac oligomers Journal of Advanced Research in Dynamical and Control Systems, 2020, 12(Special Issue 2), страницы 351–35 DOI: 35940/ijitee.G5721.079920
  35. Kerem Shixaliyev Development and implementation in industry technology of obtaining composite materials and products based on polyvinyl chloride visibilityEveryonearrow_drop_downJournal of Advanced Research in Dynamical and ControlSystems2020 | Journal article DOI: 5373/JARDCS/V12SP2/SP20201081
  36. Shixaliyev kerem Seyfi Modification of the used up polymeric materials and investigation thof e properties of the materials obtained.Journal of Medical Pharmaceutical and Allied Sciences, 2022, 11(2), pages 4697–4702 DOI: 35940/ijitee.G5721.079920
Regular Issue Subscription Original Research
Volume 13
Issue 05
Received 30/04/2025
Accepted 16/07/2025
Published 11/08/2025
Publication Time 103 Days
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