Development of Self-Healing Circuit Boards Using Shape Memory Polymer Composites

Year : 2025 | Volume : 13 | Special Issue 06 | Page : 746 770
    By

    Mohit Tiwari,

  • K. Senthil Kumar,

  • Sajith Erat,

  • Tanima Bhowmik,

  • P. Neopolean,

  • Savita Verma,

  • K.P. Yuvaraj,

  • Ram Subbiah,

  1. Assistant professor, Department of Computer Science and Engineering, Bharati Vidyapeeth’s College of Engineering, A-4, Rohtak Road, Paschim Vihar, Delhi, India
  2. Professor, Department of Agricultural Engineering, Nehru Institute of Technology, Kaliapuram, Coimbatore, Tamil Nadu, India
  3. Lecturer, University of Technology and Applied Science, Nizwa, Oman
  4. Associate Professor, Department of Computer Science Engineering (AIML), Institute of Engineering & Management, School of University of Engineering & Management, Kolkata, West Bengal, India
  5. Associate Professor, Department of Mechanical Engineering, SCAD College of Engineering and Technology, Cheranmahadevi, Tamil Nadu, India
  6. Associate Professor, Department of Chemistry, School of Engineering, Presidency University, Bengaluru, Karnataka, India
  7. Associate Professor, Department of Mechanical Engineering, Sri Krishna College of Engineering and Technology, Coimbatore, Tamil Nadu, India
  8. Professor, Department of Mechanical Engineering, Gokaraju Rangaraju Institute of Engineering and Technology, Nizampet, Hyderabad, Telangana, India

Abstract

This study investigates the influence of temperature, humidity, and nanofiller type on the electrical and structural performance of advanced polymer nanocomposites for self-healing circuit applications. Particular attention was given to conductivity retention and the morphological behavior of carbon nanotubes (CNTs), graphene, and silver nanoparticles (AgNPs). Results show that conductivity decreased under elevated thermal–humidity conditions, reflecting the role of environmental stress in material degradation. Among the tested systems, AgNP-based composites achieved the highest recovery efficiency (>95%) and demonstrated stable operation under cyclic stress. Electrical measurements revealed a temperature-dependent resistance decline, consistent with thermally activated percolative conduction. Scanning Electron Microscopy (SEM) confirmed distinct filler morphologies: fibrous CNT networks and uniformly dispersed AgNPs, both contributing to enhanced charge transport pathways. Importantly, the incorporation of these fillers improved electrical performance without compromising flexibility. These findings establish a direct link between filler dispersion, microstructural organization, and macroscopic functionality, offering valuable design guidelines for robust, long-lasting nanocomposites in flexible electronics, wearable sensors, and next-generation energy devices.

Keywords: Polymer nanocomposites, Carbon nanotubes (CNTs), Silver nanoparticles (AgNPs), Conductivity retention, Thermal stability, Morphological analysis.

[This article belongs to Special Issue under section in Journal of Polymer & Composites (jopc)]

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How to cite this article:
Mohit Tiwari, K. Senthil Kumar, Sajith Erat, Tanima Bhowmik, P. Neopolean, Savita Verma, K.P. Yuvaraj, Ram Subbiah. Development of Self-Healing Circuit Boards Using Shape Memory Polymer Composites. Journal of Polymer & Composites. 2025; 13(06):746-770.
How to cite this URL:
Mohit Tiwari, K. Senthil Kumar, Sajith Erat, Tanima Bhowmik, P. Neopolean, Savita Verma, K.P. Yuvaraj, Ram Subbiah. Development of Self-Healing Circuit Boards Using Shape Memory Polymer Composites. Journal of Polymer & Composites. 2025; 13(06):746-770. Available from: https://journals.stmjournals.com/jopc/article=2025/view=222994


References

  1. Arati, B. (2023). Manufacturing and characterization of self-healing polymer materials intended for the electrical insulation of future power modules (Doctoral dissertation, Université Paul Sabatier-Toulouse III).
  2. Li, G., & Feng, X. (Eds.). (2022). Recent advances in smart self-healing polymers and composites.
  3. Arati, B., Bley, V., Pichon, P. Y., & Teyssedre, G. (2023). New self-healing dielectric for high-reliability, high-performance PCB-embedding materials for power electronics applications. IEEE Access, 11, 133967-133978.
  4. Sarrafan, S., & Li, G. (2024). Conductive and Ferromagnetic Syntactic Foam with Shape Memory and Self‐Healing/Recycling Capabilities. Advanced Functional Materials, 34(11), 2308085.
  5. Tan, Y. J., Susanto, G. J., Anwar Ali, H. P., & Tee, B. C. (2021). Progress and roadmap for intelligent self‐healing materials in autonomous robotics. Advanced Materials, 33(19), 2002800.
  6. Sabet, M. (2024). Unveiling advanced self-healing mechanisms in graphene polymer composites for next-generation applications in aerospace, automotive, and electronics. Polymer-Plastics Technology and Materials, 63(15), 2032-2059.
  7. Ford, M. J., Ohm, Y., Chin, K., & Majidi, C. (2022). Composites of functional polymers: Toward physical intelligence using flexible and soft materials. Journal of Materials Research, 1-23.
  8. Zhou, Y., Li, L., Han, Z., Li, Q., He, J., & Wang, Q. (2022). Self-healing polymers for electronics and energy devices. Chemical Reviews, 123(2), 558-612.
  9. Jayabalakrishnan, D., Muruga, D. N., Bhaskar, K., Pavan, P., Balaji, K., Rajakumar, P. S., … & Prabhahar, M. (2021). Self-Healing materials–A review. Materials Today: Proceedings, 45, 7195-7199.
  10. Yan, S., Zhang, F., Luo, L., Wang, L., Liu, Y., & Leng, J. (2023). Shape memory polymer composites: 4D printing, smart structures, and applications. Research, 6, 0234.
  11. Mahmud, S., Konlan, J., Deicaza, J., & Li, G. (2023). Coir/glass hybrid fiber reinforced thermoset polymer composite laminates with room-temperature self-healing and shape memory functions. Industrial Crops and Products, 201, 116895.
  12. Jayabalakrishnan, D., Muruga, D. N., Bhaskar, K., Pavan, P., Balaji, K., Rajakumar, P. S., … & Prabhahar, M. (2021). Self-Healing materials–A review. Materials Today: Proceedings, 45, 7195-7199.
  13. Razzaq, M. Y., Gonzalez-Gutierrez, J., Mertz, G., Ruch, D., Schmidt, D. F., & Westermann, S. (2022). 4D printing of multicomponent shape-memory polymer formulations. Applied Sciences, 12(15), 7880.
  14. Chen, M., Chen, B., Li, D., Luo, W., & Zhang, H. (2023). Development of a Multistimulus Response Silicon-Bridged/Fe3O4 Epoxy Vitrimer: Controllable Welding, Crack Healing, and Shape Memory. ACS Applied Polymer Materials, 5(12), 9931-9939.
  15. Leungpuangkaew, S., Amornkitbamrung, L., Phetnoi, N., Sapcharoenkun, C., Jubsilp, C., Ekgasit, S., & Rimdusit, S. (2023). Magnetic-and light-responsive shape memory polymer nanocomposites from bio-based benzoxazine resin and iron oxide nanoparticles. Advanced Industrial and Engineering Polymer Research, 6(3), 215-225.
  16. Li, Y., Zhang, F., Liu, Y., & Leng, J. (2024). A tailorable series of elastomeric‐to‐rigid, selfhealable, shape memory bismaleimide. Small, 20(15), 2307244.
  17. Abedin, R., Konlan, J., Feng, X., Mensah, P., & Li, G. (2022). A hybrid shape memory polymer filled metallic foam composite: Shape restoring, strain sensing, Joule heating, strengthening, and toughening. Smart Materials and Structures, 31(9), 095009.
  18. Patnaik, T. K., Achary, S. P., Behera, J., & Mishra, S. (2023). Polymer Nanocomposites with Improved Electrical and Thermal Properties for Smart Electronic Material Applications. In Manufacturing and Processing of Advanced Materials (pp. 239-251). Bentham Science Publishers.
  19. Dallaev, R. (2024). Advances in materials with self-healing properties: a brief review. Materials, 17(10), 2464.
  20. Mahmood, A., Perveen, F., Chen, S., Akram, T., & Irfan, A. (2024). Polymer composites in 3D/4D printing: materials, advances, and prospects. Molecules, 29(2), 319.
  21. Ren, L., Wang, Z., Ren, L., Han, Z., Zhou, X. L., Song, Z., & Liu, Q. (2023). 4D printing of shape-adaptive tactile sensor with tunable sensing characteristics. Composites Part B: Engineering, 265, 110959.
  22. Qin, T., Liao, W., Yu, L., Zhu, J., Wu, M., Peng, Q., … & Zeng, H. (2022). Recent progress in conductive self‐healing hydrogels for flexible sensors. Journal of Polymer Science, 60(18), 2607-2634.
  23. Benas, J. S., Liang, F. C., Venkatesan, M., Yan, Z. L., Chen, W. C., Han, S. T., … & Kuo, C. C. (2023). Recent development of sustainable self-healable electronic skin applications, a review with insight. Chemical Engineering Journal, 466, 142945.
  24. Gao, Q., Chen, Z., Liu, C., Wang, Y., Zhu, J., & Gao, C. (2024). Helical TPU/Ag@ K2Ti4O9 fibers with shape memory performance for highly stretchable and sensitive strain sensors. Journal of Alloys and Compounds, 980, 173547.
  25. Gopalakrishnan, T., Chandrasekaran, M., Saravanan, R., & Murugan, P. (2022). An ample review on compatibility and competence of shape memory alloys for enhancing composites. Advances in Materials Science and Engineering, 2022(1), 6988731.
  26. Dayyoub, T., Maksimkin, A. V., Filippova, O. V., Tcherdyntsev, V. V., & Telyshev, D. V. (2022). Shape memory polymers as smart materials: A review. Polymers, 14(17), 3511.
  27. Alshebly, Y. S. (2023). Development of 4D-printed shape memory polymer actuators for induced-strain shape change (Doctoral dissertation, University of Nottingham).
  28. Ji, Q., Wang, X. V., Wang, L., & Feng, L. (2022). Online reinforcement learning for the shape morphing adaptive control of 4D printed shape memory polymer. Control Engineering Practice, 126, 105257.
  29. Zhao, Y., Ohm, Y., Liao, J., Luo, Y., Cheng, H. Y., Won, P., … & Majidi, C. (2023). A self-healing electrically conductive organogel composite. Nature Electronics, 6(3), 206-215.
  30. Choi, S. B., Meena, J. S., & Kim, J. W. (2023). Revolutionizing thermal stability and self-healing in pressure sensors: a novel approach. Advanced Fiber Materials, 5(6), 2028-2039.
  31. Roppolo, I., Caprioli, M., Pirri, C. F., & Magdassi, S. (2024). 3D Printing of Self‐Healing Materials. Advanced Materials, 36(9), 2305537.
  32. Li, H., Chen, Z., Yu, S., Jian, B., Yin, H., & Ge, Q. (2024). Selective near-infrared laser programming for shape-memory polymer–carbon nanotube composite material 4D printing. Programmable Materials, 2, e6.
  33. Kumar, A., Singla, Y. K., Biswas, P., Heidari, M., & Thangavel, S. (2024). Resurrection Structure: New Generation of Bio-Inspired Nanocomposites and Laminates. In Fracture Behavior of Nanocomposites and Reinforced Laminate Structures (pp. 427-440). Cham: Springer Nature Switzerland.
  34. Li, Z., Lu, J., Ji, T., Xue, Y., Zhao, L., Zhao, K., … & Jiang, Z. (2024). Self‐healing hydrogel bioelectronics. Advanced Materials, 36(21), 2306350.
  35. Wang, W., Xiang, Y., Yu, J., & Yang, L. (2023). Development and prospect of smart materials and structures for aerospace sensing systems and applications. Sensors, 23(3), 1545.
  36. Majidi, C., Alizadeh, K., Ohm, Y., Silva, A., & Tavakoli, M. (2022). Liquid metal polymer composites: From printed stretchable circuits to soft actuators. Flexible and Printed Electronics, 7(1), 013002.
  37. Enferadi, A., Baniassadi, M., & Baghani, M. (2024). Fractal circuit architectures for spatially controlled heating and multi-modal shape programming of electro-active shape memory polymers. International Journal of Applied Mechanics, 16(6), 2441003.
  38. Jiang, K., Wang, H., Long, Y., Han, Y., Zhang, H., & Weng, Q. (2023). Injectable miniaturized shape-memory electronic device for continuous glucose monitoring. Device, 1(5).
  39. Liu, Y., Wang, Y., Yang, X., Zheng, J., Huang, W., Zhang, Y., … & Wang, X. (2023). 3D‐Architected low melting point alloys foam microstructure‐reinforced polymer composite with superior stiffness‐switchable for soft actuator. Polymer Composites, 44(12), 8805-8818.
  40. Fang, L., Yan, W., Chen, S., Duan, Q., Herath, M., Epaarachchi, J., … & Lu, C. (2023). Light and shape‐memory polymers: characterization, preparation, stimulation, and application. Macromolecular Materials and Engineering, 308(12), 2300158.

Special Issue Subscription Original Research
Volume 13
Special Issue 06
Received 10/05/2025
Accepted 22/07/2025
Published 08/08/2025
Publication Time 90 Days


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