Advanced Functional Nanocomposites: Graphene Oxide Integration into Polyvinyl Alcohol Matrix

Year : 2025 | Volume : 13 | Issue : 03 | Page : 50-59
    By

    Indradeep Kumar,

  • Nandakumar V,

  • R.Kiruthika,

  • Santhi M George,

  • T. Himaja,

  • M.V. Someswararao,

  • Shankramma S. Kerur,

  • V Saravanan,

  • Velmurugan Paramasivam,

  1. Assistant Professor, Amity Institute of Technology, Amity University, Noida, Uttar Pradesh, India
  2. Associate Professor, Department of Physics, Maharanis Science College for Women (Autonomous), Mysuru, Karnataka, India
  3. Assistant Professor, Department of Chemistry, Sri Sairam Institute of Technology, Chennai, Tamil Nadu, India
  4. Associate Professor, Department of Science and Humanities, RMK Engineering College, Kavaraipettai, Chennai, Tamil Nadu, India
  5. Assistant Professor, Department of Electrical and Electronics Engineering, Aditya University, Surampalem, Andhra Pradesh, India
  6. Associate Professor, Department of Engineering Physics, S. R. K. R. Engineering College (Autonomous), West Godavari, Andhra Pradesh, India
  7. Assistant Professor, Department of Chemistry, KLE Technological University, Dr.M.S. Sheshgiri Campus, Belagavi, Karnataka,
  8. Professor, Department of Physics, Indra Ganesan College of Engineering, Trichy, Tamil Nadu, India
  9. Professor, Department of Automotive Engineering, Faculty of Mechanical and Industrial Engineering, Bahir Dar Institute of Technology (BiT), Bahir Dar University, P.O. Box 26, Bahir Dar, , Ethiopia

Abstract

This research explores how incorporating graphene oxide (GO) into polyvinyl alcohol (PVA) can improve its mechanical and thermal characteristics, with the goal of creating multifunctional nanocomposites suitable for advanced technological applications. GO was introduced into the PVA matrix at 0.5, 1, and 2 wt% via a scalable solution casting method. The resulting nanocomposites were characterized mechanically, thermally, and spectroscopically. Tensile testing revealed a significant improvement in mechanical performance, with tensile strength increasing from 30 MPa (pure PVA) to 51 MPa at 2 wt% GO—a 70% enhancement—due to efficient stress transfer and nanoscale reinforcement via hydrogen bonding. Young’s modulus also rose from 1.2 GPa to 2.5 GPa, indicating greater stiffness from restricted chain mobility. Thermogravimetric analysis (TGA) showed a shift in decomposition onset from 240°C to 295°C, attributed to GO’s barrier effect and stable interfacial bonding. Thermal conductivity improved from 0.20 W/mK to 0.42 W/mK at 2 wt% GO due to phonon-conductive pathways formed by well-dispersed GO nanosheets. FTIR spectroscopy confirmed strong interfacial interactions, with red-shifts in O–H and C=O stretching bands indicating hydrogen bonding and potential partial esterification. These enhancements confirm GO’s role as a multifunctional reinforcement, making the GO–PVA nanocomposites promising for flexible electronics, thermally conductive substrates, eco-friendly packaging, and structural biomaterials.

Keywords: Graphene oxide, polyvinyl alcohol, mechanical reinforcement, thermal conductivity, FTIR analysis.

[This article belongs to Journal of Polymer and Composites ]

How to cite this article:
Indradeep Kumar, Nandakumar V, R.Kiruthika, Santhi M George, T. Himaja, M.V. Someswararao, Shankramma S. Kerur, V Saravanan, Velmurugan Paramasivam. Advanced Functional Nanocomposites: Graphene Oxide Integration into Polyvinyl Alcohol Matrix. Journal of Polymer and Composites. 2025; 13(03):50-59.
How to cite this URL:
Indradeep Kumar, Nandakumar V, R.Kiruthika, Santhi M George, T. Himaja, M.V. Someswararao, Shankramma S. Kerur, V Saravanan, Velmurugan Paramasivam. Advanced Functional Nanocomposites: Graphene Oxide Integration into Polyvinyl Alcohol Matrix. Journal of Polymer and Composites. 2025; 13(03):50-59. Available from: https://journals.stmjournals.com/jopc/article=2025/view=209955


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References

  1. Peppas NA, Huang Y. Nanoscale technology of mucoadhesive interactions. Adv Drug Deliv Rev. 2004;56(11):1675–87.
  2. Zhang X, Huang Y, Wang X, Wang Y, Chen L. Preparation and properties of PVA/graphene oxide composite films. Carbohydr Polym. 2011;86(2):506–12.
  3. Caló E, Khutoryanskiy VV. Biomedical applications of hydrogels: A review of patents and commercial products. Eur Polym J. 2015;65:252–67.
  4. Mohit R, Siengchin S. Bio-based polymer composites for automotive and aerospace industries. Polymers (Basel). 2019;11(2):292.
  5. Zhai M, Hu H, Gao C. Poly(vinyl alcohol)/cellulose nanocrystal/graphene oxide nanocomposites with improved mechanical properties. Carbohydr Polym. 2017;176:224–31.
  6. Moustafa H, Guizani C, Dufresne A. Sustainable biodegradable PVA-based materials. Eur Polym J. 2018;108:1–12.
  7. Da Silva MA, Barbosa R, Silva LMA, de Oliveira HP. Biodegradable blends of PVA and starch for packaging applications: Recent advances and future trends. J Appl Polym Sci. 2021;138(17):50201.
  8. Dreyer DR, Park S, Bielawski CW, Ruoff RS. The chemistry of graphene oxide. Chem Soc Rev. 2010;39(1):228–40.
  9. Stankovich S, Dikin DA, Dommett GHB, Kohlhaas KM, Zimney EJ, Stach EA, et al. Graphene-based composite materials. Nature. 2006;442(7100):282–6.
  10. Kim H, Abdala AA, Macosko CW. Graphene/polymer nanocomposites. Macromolecules. 2010;43(16):6515–30.
  11. Zhao X, Zhang Q, Chen D, Lu P. Enhanced mechanical properties of graphene-based poly(vinyl alcohol) composites. Macromolecules. 2010;43(5):2357–63.
  12. Park S, Ruoff RS. Chemical methods for the production of graphenes. Nat Nanotechnol. 2009;4(4):217–24.
  13. Shen J, Hu Y, Shi M, Li N, Ye M. Layer-by-layer self-assembly of graphene nanoplatelets. Langmuir. 2012;28(3):1566–72.
  14. Xu Z, Gao C. Graphene chiral liquid crystals and macroscopic assembled fibres. Nat Commun. 2011;2(1):571.
  15. Bai H, Li C, Shi G. Functional composite materials based on chemically converted graphene. Adv Mater. 2011;23(9):1089–115.
  16. Huang Y, Wang J, Fu C, Wu Y. Multifunctional graphene oxide/PVA nanocomposites for barrier and mechanical reinforcement. J Mater Sci. 2016;51(2):944–56.
  17. Wu Q, Wang X, Wang H, Zhang Y. Preparation and characterization of flame-retardant polyvinyl alcohol/graphene oxide composites. Polym Compos. 2016;37(2):342–9.
  18. Liu T, Wang Y, Li X, Zhang Y, Sun Z. Enhanced mechanical properties of PVA nanocomposites with graphene oxide. RSC Adv. 2015;5(3):1910–6.
  19. Kim S, Hwang SW, Yu YH, Lee MH. Thermal and mechanical characteristics of PVA/graphene oxide nanocomposites. J Ind Eng Chem. 2016;34:190–5.
  20. Shtein M, Nadiv R, Buzaglo M, Regev O. Graphene-based hybrid composites for efficient thermal management of electronic devices. ACS Appl Mater Interfaces. 2015;7(42):23725–30.
  21. Yu A, Ramesh P, Itkis ME, Bekyarova E, Haddon RC. Graphite nanoplatelet–epoxy composite thermal interface materials. J Phys Chem C. 2007;111(21):7565–9.
  22. Fang M, Wang K, Lu H, Yang Y, Nutt S. Covalent polymer functionalization of graphene nanosheets and mechanical properties of composites. J Mater Chem. 2009;19(38):7098–105.
  23. Yoon SW, Kim HJ, Jang JH. Preparation of PVA nanocomposites with improved flame retardancy using GO and phosphorous compounds. Polym Degrad Stab. 2014;102:173–8.
  24. Zhang L, Zhou Y, Wang Q, Xue Q. Enhanced water vapor barrier properties of PVA films by incorporating exfoliated graphene oxide nanosheets. J Membr Sci. 2018;563:321–8.
  25. Li J, Zhuang S, Wang Y, Chen Y. Antibacterial activity of graphene oxide–silver nanocomposites for water disinfection. J Hazard Mater. 2017;322:48–56.
  26. Bao C, Guo Y, Song L, Hu Y. Graphene oxide–based fire-retardant coatings. J Mater Chem. 2013;1(31):918–26.
  27. Xu Y, Zhang Z, Gu Y, Wu C. Electrical conductivity and mechanical properties of PVA/rGO composites. Compos Sci Technol. 2019;182:107751.
  28. Kuila T, Bose S, Khanra P, Mishra AK, Kim NH, Lee JH. Recent advances in graphene-based polymer composites. Prog Polym Sci. 2012;37(7):1061–105.
  29. Wang J, Zheng Y, Luo Z. Effect of graphene oxide on thermal and mechanical properties of PVA composites. Appl Surf Sci. 2017;393:338–46.
  30. Ahmed S, Anis A. Structural and thermal characteristics of PVA/GO nanocomposites synthesized by solution casting. J Therm Anal Calorim. 2018;132(1):137–46.
  31. Tang Z, Kang H, Shen Z, Guo B, Zhang L. Graphene-based polymer nanocomposites for flexible electronics. Mater Sci Eng R Rep. 2020;142:100580.
  32. Xu et al. (2019), Compos Sci Technol, 182, 107751 – on electrical conductivity and mechanical properties of PVA/rGO composites.
  33. Tang et al. (2020), Mater Sci Eng R Rep, 142, 100580 – on graphene-based nanocomposites for flexible electronics;
  34. Da Silva et al. (2021), J Appl Polym Sci, 138(17):50201 – on biodegradable blends for packaging applications of GO-PVA composites.
  35. Ahmed & Anis (2018), J Therm Anal Calorim, 132(1):137–46 – on GO-PVA thermal behaviour of composites.
  36. Wang et al. (2017), Appl Surf Sci, 393:338–46 – on thermal and mechanical improvements in GO–PVA systems.

Regular Issue Subscription Original Research
Volume 13
Issue 03
Received 05/04/2025
Accepted 17/04/2025
Published 25/04/2025
Publication Time 20 Days


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