Dielectric Studies of 0.5Ba0.8Ca0.2TiO3.0.5CaCu3Ti4O12 Nanoceramic Fabricated by Chemo-mechanical Process

Year : 2025 | Volume : 13 | Special Issue 02 | Page : 12 21
    By

    Gajendra Singh Lodhi,

  • Jyoti Sharma,

  • Jayanta Kumar Mahato,

  • Laxman Singh,

  • Atendra Kumar,

  1. Research Scholar, School of Basic and Applied Sciences, Shobhit Institute of Engineering and Technology (Deemed-to-be-University), Meerut, Uttar Pradesh, India
  2. Professor, School of Basic and Applied Sciences, Shobhit Institute of Engineering and Technology (Deemed-to-be-University), Meerut, Uttar Pradesh, India
  3. Associate Professor, School of Engineering and Technology, Shobhit Institute of Engineering and Technology (Deemed-to-be-University), Meerut, Uttar Pradesh, India
  4. Associate Professor, Department of chemistry, Siddharth University, Kapilvastu, Siddharth Nagar, Uttar Pradesh, India
  5. Professor, Department of Chemistry, Simdega College, Simdega (A constituent unit of Ranchi University), Jharkhand, India

Abstract

The present investigation is aimed toward investigate a straightforward, inexpensive, and environmentally friendly chemo-mechanical method for preparing high-dielectric materials, specifically 0.5Ba0.8Ca0.2TiO3.0.5CaCu3Ti4O12 (BCT-CCTO), by combining metal nitrate combustion with solid TiO2 powder and titanium isopropoxide, Ti (OR)4. The composite was prepared by the mixing of individual materials of Ba0.8Ca0.2TiO3 and CaCu3Ti4O12 through the chemo-mechanical method. Initially, 99% pure Ba (NO3)3, Cu (NO3)2∙3H2O, TiO2 and glycine were taken in their stoichiometry ratios. The composites were further sintered at 950ºC and 1000°C for 15 hrs. The presence of a major peak in BCT-CCTO composite at 1000°C 15 hrs. was investigated in the X-ray diffraction analysis which clearly confirmed the phase formation of BCT-CCTO composite. The surface morphology, the elemental homogenous composition of the element as a specific portion, and the electronic state of the metal ions of the BCT-CCTO composite were confirmed through SEM, EDX mapping, and XPS spectra respectively. It is observed that bimodal type of grain morphologies of several hundreds of nanometers are formed in the composites. It is also confirmed from TEM observation that the presence of spherical and homogenous-sized particles which resemble platelets of BCT-CCTO composite materials. Moreover, the results obtained at certain frequencies and temperatures are detailed in dielectric relaxation processes and because of interfacial polarization, a high dielectric constant was seen at low frequencies and high temperatures.

Keywords: X-ray diffraction, SEM, EDX, TEM, XPS, Dielectric constant.

[This article belongs to Special Issue under section in Journal of Polymer and Composites (jopc)]

How to cite this article:
Gajendra Singh Lodhi, Jyoti Sharma, Jayanta Kumar Mahato, Laxman Singh, Atendra Kumar. Dielectric Studies of 0.5Ba0.8Ca0.2TiO3.0.5CaCu3Ti4O12 Nanoceramic Fabricated by Chemo-mechanical Process. Journal of Polymer and Composites. 2025; 13(02):12-21.
How to cite this URL:
Gajendra Singh Lodhi, Jyoti Sharma, Jayanta Kumar Mahato, Laxman Singh, Atendra Kumar. Dielectric Studies of 0.5Ba0.8Ca0.2TiO3.0.5CaCu3Ti4O12 Nanoceramic Fabricated by Chemo-mechanical Process. Journal of Polymer and Composites. 2025; 13(02):12-21. Available from: https://journals.stmjournals.com/jopc/article=2025/view=193479


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Special Issue Subscription Original Research
Volume 13
Special Issue 02
Received 21/09/2024
Accepted 23/12/2024
Published 11/01/2025
Publication Time 112 Days
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