Influence of Catalyst Type and Reaction Conditions on Biodiesel Conversion of Pine and Soapnut Oils

Year : 2025 | Volume : 12 | Issue : 03 | Page : 39 48
    By

    C. Manikandan,

  • C. Syed Aalam,

  1. Research scholar, Department of Mechanical Engineering, FEAT, Annamalai University, Tamil Nadu, India
  2. Assistant Professor, Department of Mechanical Engineering, FEAT, Annamalai University, Tamil Nadu, India

Abstract

Biodiesel produced from non-edible oils is becoming an important replacement for petroleum diesel because it is renewable, environmentally friendly, and suitable for use in existing diesel engines. It helps reduce air pollution, lowers dependence on fossil fuels, and supports sustainable energy development. Pine oil and soapnut oil are two promising non-edible feedstocks because they are easy to obtain, inexpensive, and contain chemical compounds that can be effectively converted into biodiesel. Although these oils are good raw materials, their conversion into high-quality biodiesel mainly depends on the catalyst used and the process conditions applied during transesterification. The present study examines how different types of catalysts—alkaline, acidic, heterogeneous (solid), and bio-catalysts—affect the conversion of pine and soapnut oils into biodiesel. Key process variables such as methanol-to-oil ratio, catalyst concentration, reaction temperature, and reaction time were carefully adjusted and studied. These parameters were selected because they influence reaction speed, product quality, and overall biodiesel yield. Since pine oil and soapnut oil have different free fatty acid levels and chemical structures, each oil responded differently to the reaction conditions, requiring slight adjustments to achieve optimal results. The findings show that alkaline catalysts produced the highest biodiesel yield and the fastest conversion rate, making them suitable for large-scale applications. Acid catalysts were more effective for oils with high free fatty acid content but required longer reaction time. Heterogeneous catalysts showed advantages such as easy separation, reusability, and reduced waste generation, although their reaction rate was slower. Bio-catalysts, while environmentally friendly, resulted in moderate conversion compared to chemical catalysts. Overall, this study provides useful information for selecting the most suitable catalysts and reaction conditions for producing biodiesel from pine and soapnut oils. The results support ongoing efforts to develop clean, affordable, and sustainable fuel alternatives for future energy needs.

Keywords: Catalyst, Reaction Conditions, Biodiesel, Pine Oil, Soapnut Oil

[This article belongs to Journal of Automobile Engineering and Applications ]

How to cite this article:
C. Manikandan, C. Syed Aalam. Influence of Catalyst Type and Reaction Conditions on Biodiesel Conversion of Pine and Soapnut Oils. Journal of Automobile Engineering and Applications. 2025; 12(03):39-48.
How to cite this URL:
C. Manikandan, C. Syed Aalam. Influence of Catalyst Type and Reaction Conditions on Biodiesel Conversion of Pine and Soapnut Oils. Journal of Automobile Engineering and Applications. 2025; 12(03):39-48. Available from: https://journals.stmjournals.com/joaea/article=2025/view=234135


References

  1. Thangaraj, B., & Solomon, P. R., “Catalysis in biodiesel production — a review,” Clean Energy, vol. 3, no. 1, pp. 2–23, 2019.
  2. Chandra Kishore, S., Perumal, S., Atchudan, R., Sundramoorthy, A. K., Alagan, M., Sangaraju, S., & Lee, Y. R., “A Review of Biomass-Derived Heterogeneous Catalysts for Biodiesel Production,” Catalysts, vol. 12, no. 12, art. 1501, 2022.
  3. Zhang, Q., Wang, J., Zhang, X., Deng, T., Zhang, Y., & Ma, P., “Metal oxide-based heterogeneous acid catalysts for sustainable biodiesel synthesis: recent advances and key challenges,” RSC Advances, vol. 15, pp. 31683–31705, 2025.
  4. Ajala, E. O., Ajala, M. A., Sonusi, A. D., & Ayinla, I. K., “Nano-synthesis of solid acid catalysts from waste-iron-filling for biodiesel production using high free fatty acid waste cooking oil,” Scientific Reports, vol. 10, art. 13256, 2020.
  5. Abidin, S. Z., Mohammed, M. L., & Saha, B., “Two-Stage Conversion of Used Cooking Oil to Biodiesel Using Ion Exchange Resins as Catalysts,” Catalysts, vol. 13, no. 8, art. 1209, 2023.
  6. Quayson, E., Amoah, J., Hama, S., Kondo, A., & Ogino, C., “Immobilized lipases for biodiesel production: current and future greening opportunities,” Renewable and Sustainable Energy Reviews, vol. 134, art. 110355, 2020.
  7. Santos, S., Puna, J., & Gomes, J., “A review on bio-based catalysts (immobilized enzymes) used for biodiesel production,” Energies, vol. 13, no. 11, art. 3013, 2020.
  8. Zou, T., Duan, Y.-d., Wang, Q.-e., & Cheng, H.-m., “Preparation of Immobilized Lipase on Silica Clay as a Potential Biocatalyst on Synthesis of Biodiesel,” Catalysts, vol. 10, no. 11, art. 1266, 2020.
  9. Xie, W., & Huang, M., “Enzymatic production of biodiesel using immobilized lipase on core-shell structured Fe₃O₄@MIL-100(Fe) composites,” Catalysts, vol. 9, no. 10, art. 850, 2019.
  10. Khujamberdiev, R., & Cho, H. M., “Synthesis and Characterization of Nanoparticles in Transforming Biodiesel into a Sustainable Fuel,” Molecules, vol. 30, no. 6, art. 1352, 2025.
  11. Hanif, M., Ahmad, A., Hussain, S., & Saleem, M., “Nano-magnetic CaO/Fe₂O₃ catalysts for efficient biodiesel production from non-edible oils,” Journal of Molecular Catalysis A: Chemical, vol. 425, pp. 45–58, 2023.
  12. Carrera, S. A., Martínez, M., & García, R., “Design of recoverable magnetic catalysts for biodiesel synthesis from waste oils,” Catalysis Today, vol. 370, pp. 121–135, 2022.
  13. Badgujar, K. C., Patil, R. B., & Lee, J. H., “Sustainable production of biodiesel by immobilized lipase catalysis,” Renewable Energy, vol. 180, pp. 202–217, 2022.
  14. Alonazi, M., Khan, M., & Almutairi, F., “Combined immobilized lipases for enhanced biodiesel production,” Energy Conversion and Management, vol. 273, art. 116422, 2023.
  15. Prabhahar, M., Kumar, R., & Singh, S., “Performance of Pine Oil Biodiesel Blend in CRDI Diesel Engine,” International Journal of Renewable Energy Research, vol. 14, no. 1, pp. 55–70, 2024.
  16. Kumar, D., Sharma, P., & Joshi, V., “Extraction and Optimization of Pine Oil Transesterification Process for Biodiesel,” International Journal of Engineering Trends and Technology, vol. 31, no. 3, pp. 121–130, 2024.
  17. Chen, Y. H., Lin, W. L., & Huang, C. C., “Properties of Soapnut (Sapindus mukorossi) Oil Biodiesel,” Journal of Renewable and Sustainable Energy, vol. 7, no. 2, art. 88, 2024.
  18. Rathi, S., Singh, P., & Gupta, N., “Preparation and Characterization of Soapnut Biodiesel,” International Journal of Bioenergy Research, vol. 5, no. 4, pp. 240–252, 2019.
  19. Kumar, S., Sharma, R., & Singh, M., “Biodiesel Production from Pine Oil Using TiO₂–ZnO Nanocatalyst,” International Journal of Nanotechnology Applications, vol. 16, no. 1, pp. 17–29, 2023.
  20. Shankar, R., Reddy, P., & Chandra, T., “Optimized Biodiesel Production from Pine Oil,” Conference on Renewable Fuels and Energy Systems, vol. 1, pp. 77–82, 2025.
  21. Manikandan C., Syed Aalam, C. (2024). Impact of Pine Oil Blend in CRDI Diesel Engine with Different Injection Pressures. SSRG International Journal of Mechanical Engineering, 11(9), 83-92.
  22. Manikandan, C., & Syed Aalam, C. (2024). Extraction and Optimization of Transesterification Process to Produce Pine Biodiesel Using Nano Catalyst. International Journal of Engineering Trends and Technology, 72(7), 111-117.
  23. Chandrasekaran, M., & Aalam, C. S. (2024). Recent trends in biodiesel production techniques: A Review. International Journal of Advanced Engineering Research and Science, 11(12), 70–83.
  24. Manikandan Chandrasekaran, C. Syed Aalam. (2025). Evaluating the Performance, Emissions, and Combustion Characteristics of CRDI Diesel Engines Using Pine Oil Blends as a Sustainable Fuel Alternative. International Journal of Machine Systems and Manufacturing Technology, 03(01), 24-33.
  25. Manikandan Chandrasekaran, C. Syed Aalam, S. Devi, K. Manikandan. (2024). Analysis of Performance, Emissions, and Combustion in a CRDI Diesel Engine Operating on Soapnut Oil as Fuel. International Journal of Recent Engineering Science, 11(6), 54-62.
  26. Manikandan, C. Syed Aalam, Performance and Emission Characteristics of Biodiesel-Blend in CRDI Diesel Engine – A Review, Int. J. Sci. R. Tech., 2025, 2 (12), 1-12.

Regular Issue Subscription Original Research
Volume 12
Issue 03
Received 05/12/2025
Accepted 08/12/2025
Published 15/12/2025
Publication Time 10 Days


Login


My IP

PlumX Metrics