Carbon Dioxide as a Fundamental Component in Sustainable Organic Synthesis

Year : 2025 | Volume : 03 | Issue : 02 | Page : 22 34
    By

    V. Basil Hans,

  1. Research Professor, Department of Commerce and Management, Srinivas University, Mangalore, Karnataka, India

Abstract

A lot of people are interested in carbon dioxide (CO₂) as a cheap, plentiful, and safe source of carbon for making chemical processes more sustainable. Using it as a C1 building block in organic synthesis is a promising way to make products with added value while having less of an impact on the environment. This article examines current advancements in CO₂ fixation into organic compounds, emphasising the creation of effective catalytic systems for synthesising carboxylic acids, ureas, carbonates, and cyclic carbonates. The focus is on transformations mediated by transition metals and organocatalysts, as well as new methods that use photochemical and electrochemical activation of CO₂ at low temperatures. Innovative catalyst design and reaction engineering help solve problems like CO₂’s low reactivity and 17thermodynamic stability. This work emphasises the potential of carbon dioxide as a renewable carbon source in green chemistry and stresses the necessity of including CO₂ utilisation into future synthetic techniques to facilitate circular economy models.

Keywords: Carbon dioxide utilisation, sustainable synthesis, CO₂ fixation, green chemistry, catalytic transformation

[This article belongs to International Journal of Advance in Molecular Engineering ]

How to cite this article:
V. Basil Hans. Carbon Dioxide as a Fundamental Component in Sustainable Organic Synthesis. International Journal of Advance in Molecular Engineering. 2025; 03(02):22-34.
How to cite this URL:
V. Basil Hans. Carbon Dioxide as a Fundamental Component in Sustainable Organic Synthesis. International Journal of Advance in Molecular Engineering. 2025; 03(02):22-34. Available from: https://journals.stmjournals.com/ijame/article=2025/view=228165


References

  1. Mohammad O, A. Onwudili J, Yuan Q. Possible Large-Scale Use of CO(2) for Making Salicylic Acid Using a Suspension-Based Kolbe–Schmitt Reaction in Toluene. Two thousand twenty-four. ncbi.nlm.nih.gov
  2. Luo J, Larrosa I. C−H carboxylation of aromatic compounds by CO(2) fixation. 2017. ncbi.nlm.nih.gov
  3. Thibault Cantat. Transformation et usage de CO2: Que peut apporter la chimie? PhD-Day Université de Brest, Brest, France, December 2018. ffcea-02340788f
  4. Sang R, Hu Y, Razzaq R, Mollaert G et al. A useful idea for employing carbon dioxide in catalytic carbonylations. 2022. ncbi.nlm.nih.gov
  5. Monfared A, Mohammadi R, Hosseinian A, Sarhandi S, et al. Cycloaddition of atmospheric CO(2) to epoxides in solvent-free conditions: a simple way to make carbonates according to green chemistry standards. 2019. ncbi.nlm.nih.gov
  6. Ambrose K. Cobalt and chromium amino-bis(phenolate) complexes for epoxide homopolymerization and copolymerisation with carbon dioxide. 2019.
  7. Jensen M, H. Rønne M, K. Ravn A, W. Juhl R, and others Carbon dioxide electroreduction that can be scaled up and is linked to carbonylation chemistry. 2017. ncbi.nlm.nih.gov
  8. Genovese, C., Schuster, M.E., and Gibson, E.K.et al.Operando spectroscopic investigation of carbon dioxide electro-reduction by iron species on nitrogen-doped carbon.Nat Commun 9, 935 (2018). https://doi.org/10.1038/s41467-018-03138-7
  9. Poliakoff, M., Leitner, W., and Streng, E. S. (2015). The twelve rules of CO2 Chemistry. Faraday Discussions, https://doi.org/10.1039/c5fd90078f
  10. Usman M, Rehman A, Saleem F, Abbas A, and others. An review of current developments in the synthesis of cyclic carbonates from CO(2) cycloaddition to bio-based epoxides and glycerol. 2023. ncbi.nlm.nih.gov
  11. Moriuchi T, Sakuramoto T, Matsutani T, Kawai R, and others. Oxovanadium(v)-catalyzed amination of carbon dioxide at ambient pressure for urea production. 2021. ncbi.nlm.nih.gov
  12. Matsutani T, Aoyama K, Moriuchi T. Oxovanadium(V)-Catalyzed Synthesis of Ureas from Disilylamines and Carbon Dioxide at Ambient Pressure. 2022. ncbi.nlm.nih.gov
  13. Matthessen R, Fransaer J, Binnemans K, E De Vos D. Electrocarboxylation: moving towards a more sustainable and effective way to make useful carboxylic acids. 2014. ncbi.nlm.nih.gov
  14. Sulley G, L. Gregory G, T. D. Chen T, Peña Carrodeguas L et al. Switchable catalysis enhances the characteristics of CO(2)-derived polymers, including poly(cyclohexene carbonate-b-ε-decalactone-b-cyclohexene carbonate) adhesives, elastomers, and toughened plastics. Twenty twenty. ncbi.nlm.nih.gov
  15. Xu H, Shaban M, Wang S, Alkayal A, and others. Getting oxygen from carbon dioxide: making CO and epoxidation at the same time. 2021. ncbi.nlm.nih.gov
  16. Wei D, Sang R, Moazezbarabadi A, Junge H, and others. Homogeneous Carbon Capture and Catalytic Hydrogenation: Progressing Towards a Chemical Hydrogen Battery System. 2022. ncbi.nlm.nih.gov
  17. Mohamadpour F. A new use for concentrated solar radiation (CSR) as a renewable heat source for making tetrahydrobenzo[b]pyran scaffolds without using a catalyst or solvent. 2023. ncbi.nlm.nih.gov
  18. Monticelli S, Talbot A, Gotico P, Caillé F et al. Unlocking full and rapid conversion in photocatalytic carbon dioxide reduction for radio-carbonylation applications. 2023. ncbi.nlm.nih.gov
  19. Naims H. The economics of capturing and using carbon dioxide from a supply and demand point of view. 2016. ncbi.nlm.nih.gov

Regular Issue Subscription Review Article
Volume 03
Issue 02
Received 17/09/2025
Accepted 20/09/2025
Published 27/09/2025
Publication Time 10 Days



My IP

PlumX Metrics