IJPSE

Review of Composites formed of Thermoplastic as Organic Fibers

[{“box”:0,”content”:”

n

Home

n

 > 

n

ijpse

n

 > 

n

Article

n

Views: 1,275

n

n

n

n

n

By [foreach 286]u00a0

u00a0Swati Bhati,

[/foreach]
nJanuary 9, 2023 at 9:23 am

n

nAbstract

n

Composites made of structural monomers gave rise to thermoplastic polymers (TMCs). Due to their usage of a thermoplastic matrix, these materials really aren’t chemically reactive. TMCs may be remoulded without degrading when heated and become softer. They harden into the final shape when they cool. Thermoplastic materials bonded with plant fibers may one day be used to create impactabsorbing structure for renewable power. Its impact features of organic fiber-reinforced thermoplastic composites have not investigated, though, become the studies. The literature-reported study on natural fibres Thermal polymer composites’ highly absorbent and breakdown mode. The reaction of hemp fibre poly-lactic acid (PLA) mixtures put through a limited intensity loading with instrumented falling weight-impact apparatus. Using bidirectional and unidirectional hemp fibre composites with PLA polymer, they performed tests. the fact is threshold worth for hemp-reinforced Composite materials are greater than those for carbon and glass-reinforced materials. This study revealed that stronger forces are needed to start destruction in laminates made up of natural fibres. Jute fabric-PLA composites studied evaluated for low-velocity impact up to penetration. The internal damages of the composites have been found using the ultrasonic non-destructive inspection (NDI) approach and visually inspecting. In place of composites made from fossil energy oil, natural fibrereinforced disposable materials are predicted. Higher viscosity of molten PLA, impregnating reinforcing fibre strands is challenging when poly (lactic acid) is used as a substrate of biocomposites. Thermoplastic composites reinforced with continuous hemp fibre were created in this study employing intermediate materials made using a micro-braiding approach. Heated pressure in moulding was utilized to create unidirectional composite plates under varied moulding circumstances, such as heat, tension, and duration. Satisfactory impregnation was obtained at 190°C for the moulding temperature, producing quality of mechanical properties.

n

n

n

n

Volume :u00a0u00a08 | Issue :u00a0u00a01 | Received :u00a0u00a0July 24, 2022 | Accepted :u00a0u00a0July 30, 2022 | Published :u00a0u00a0August 3, 2022n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)] [/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue Review of Composites formed of Thermoplastic as Organic Fibers under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]
Keywords Natural fibres, thermoplastic, polymer, synthetic fibers, matrix

n

n

n

n

n

n[if 992 equals=”Transformative”]

n

n

Full Text

n

n

n

[/if 992][if 992 not_equal=”Transformative”]

n

n

Full Text

n

n

n

[/if 992] n

nn

[if 379 not_equal=””]n

[foreach 379]n

n[/foreach]

n[/if 379]

n

References

n[if 1104 equals=””]n

1. Joseph K, Mattoso LH, Toledo RD, Thomas S, De Carvalho LH, Pothen L, Kala S, James B. Natural fiber reinforced thermoplastic composites. Natural polymers and agrofibers composites. 2000; 159.
2. Faruk O, Bledzki AK, Fink HP, Sain M. Progress report on natural fiber reinforced composites. Macromolecular Materials and Engineering. 2014; 299 (1): 9–26.
3. Li X, Tabil LG, Panigrahi S. Chemical treatments of natural fiber for use in natural fiber-reinforced composites: a review. Journal of Polymers and the Environment. 2007; 15(1): 25–33.
4. Fuqua MA, Huo S, Ulven CA. Natural fiber reinforced composites. Polymer Reviews. 2012; 52(3): 259–320.
5. Unterweger C, Brüggemann O, Fürst C. Synthetic fibers and thermoplastic short‐fiber‐reinforced polymers: Properties and characterization. Polymer Composites. 2014; 35(2): 227–36.
6. Khan MZ, Hao Y, Hao H, Shaikh FU. Mechanical properties of ambient cured high strength hybrid steel and synthetic fibers reinforced geopolymer composites. Cement and Concrete Composites. 2018; 85: 133–52.
7. Sanjay MR, Siengchin S, Parameswaranpillai J, Jawaid M, Pruncu CI, Khan A. A comprehensive review of techniques for natural fibers as reinforcement in composites: Preparation, processing and characterization. Carbohydrate polymers. 2019; 207: 108–21.
8. Rangappa SM, Siengchin S. Natural fibers as perspective materials. Applied Science and Engineering Progress. 2018; 11(4).
9. Shanks RA, Hodzic A, Wong S. Thermoplastic biopolyester natural fiber composites. Journal of applied polymer science. 2004; 91(4): 2114–21.
10. Yashas Gowda TG, Sanjay MR, Subrahmanya Bhat K, Madhu P, Senthamaraikannan P, Yogesha B. Polymer matrix-natural fiber composites: An overview. Cogent Engineering. 2018; 5(1): 1446667.

nn[/if 1104] [if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””], [/if 1106]

    2. n[/foreach]

n[/if 1104]

n[if 1114 equals=”Yes”]n

n[/if 1114]

n

n

[if 424 not_equal=”Regular Issue”] Regular Issue[/if 424] Open Access Article

n

International Journal of Polymer Science & Engineering

ISSN: 2455-8745

Editors Overview

ijpse maintains an Editorial Board of practicing researchers from around the world, to ensure manuscripts are handled by editors who are experts in the field of study.

n

“},{“box”:4,”content”:”

n“},{“box”:1,”content”:”

    By  [foreach 286]n

  1. n

    Swati Bhati

    n

    2. [/foreach]

n

    [foreach 286] [if 1175 not_equal=””]n t

  1. Student,Biotechnology Multanimal Modi College,Ghaziabad, Uttar Pradesh,India

    2. n[/if 1175][/foreach]

n

n

n

n

n

Abstract

nComposites made of structural monomers gave rise to thermoplastic polymers (TMCs). Due to their usage of a thermoplastic matrix, these materials really aren’t chemically reactive. TMCs may be remoulded without degrading when heated and become softer. They harden into the final shape when they cool. Thermoplastic materials bonded with plant fibers may one day be used to create impactabsorbing structure for renewable power. Its impact features of organic fiber-reinforced thermoplastic composites have not investigated, though, become the studies. The literature-reported study on natural fibres Thermal polymer composites’ highly absorbent and breakdown mode. The reaction of hemp fibre poly-lactic acid (PLA) mixtures put through a limited intensity loading with instrumented falling weight-impact apparatus. Using bidirectional and unidirectional hemp fibre composites with PLA polymer, they performed tests. the fact is threshold worth for hemp-reinforced Composite materials are greater than those for carbon and glass-reinforced materials. This study revealed that stronger forces are needed to start destruction in laminates made up of natural fibres. Jute fabric-PLA composites studied evaluated for low-velocity impact up to penetration. The internal damages of the composites have been found using the ultrasonic non-destructive inspection (NDI) approach and visually inspecting. In place of composites made from fossil energy oil, natural fibrereinforced disposable materials are predicted. Higher viscosity of molten PLA, impregnating reinforcing fibre strands is challenging when poly (lactic acid) is used as a substrate of biocomposites. Thermoplastic composites reinforced with continuous hemp fibre were created in this study employing intermediate materials made using a micro-braiding approach. Heated pressure in moulding was utilized to create unidirectional composite plates under varied moulding circumstances, such as heat, tension, and duration. Satisfactory impregnation was obtained at 190°C for the moulding temperature, producing quality of mechanical properties.n

n

n

Keywords: Natural fibres, thermoplastic, polymer, synthetic fibers, matrix

n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)]

n[/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]

n

n

n

n[if 992 equals=”Transformative”]n

n

n

Full Text

n

n

nn[/if 992]n[if 992 not_equal=”Transformative”]n

n

Full Text

n

n

n

n

[/if 992]n[if 379 not_equal=””]

Browse Figures

n

n

[foreach 379]n

n[/foreach]

n

[/if 379]n

n

References

n[if 1104 equals=””]

1. Joseph K, Mattoso LH, Toledo RD, Thomas S, De Carvalho LH, Pothen L, Kala S, James B. Natural fiber reinforced thermoplastic composites. Natural polymers and agrofibers composites. 2000; 159.
2. Faruk O, Bledzki AK, Fink HP, Sain M. Progress report on natural fiber reinforced composites. Macromolecular Materials and Engineering. 2014; 299 (1): 9–26.
3. Li X, Tabil LG, Panigrahi S. Chemical treatments of natural fiber for use in natural fiber-reinforced composites: a review. Journal of Polymers and the Environment. 2007; 15(1): 25–33.
4. Fuqua MA, Huo S, Ulven CA. Natural fiber reinforced composites. Polymer Reviews. 2012; 52(3): 259–320.
5. Unterweger C, Brüggemann O, Fürst C. Synthetic fibers and thermoplastic short‐fiber‐reinforced polymers: Properties and characterization. Polymer Composites. 2014; 35(2): 227–36.
6. Khan MZ, Hao Y, Hao H, Shaikh FU. Mechanical properties of ambient cured high strength hybrid steel and synthetic fibers reinforced geopolymer composites. Cement and Concrete Composites. 2018; 85: 133–52.
7. Sanjay MR, Siengchin S, Parameswaranpillai J, Jawaid M, Pruncu CI, Khan A. A comprehensive review of techniques for natural fibers as reinforcement in composites: Preparation, processing and characterization. Carbohydrate polymers. 2019; 207: 108–21.
8. Rangappa SM, Siengchin S. Natural fibers as perspective materials. Applied Science and Engineering Progress. 2018; 11(4).
9. Shanks RA, Hodzic A, Wong S. Thermoplastic biopolyester natural fiber composites. Journal of applied polymer science. 2004; 91(4): 2114–21.
10. Yashas Gowda TG, Sanjay MR, Subrahmanya Bhat K, Madhu P, Senthamaraikannan P, Yogesha B. Polymer matrix-natural fiber composites: An overview. Cogent Engineering. 2018; 5(1): 1446667.

n[/if 1104][if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””],[/if 1106]

    2. n[/foreach]

n[/if 1104]

n

n[if 1114 equals=”Yes”]n

n[/if 1114]”},{“box”:2,”content”:”

Regular Issue Open Access Article

n

n

n

n

n

International Journal of Polymer Science & Engineering

n

[if 344 not_equal=””]ISSN: 2455-8745[/if 344]

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

Volume 8
Issue 1
Received July 24, 2022
Accepted July 30, 2022
Published August 3, 2022

n

n

Views: 1,275

n

n

Editor

n

n

n

Reviewer

n

n

n n

n”},{“box”:6,”content”:”“}]

Read More
IJPSE

Fabrication of a Novel and Efficient Radiation Grafted Functionalized Polymer Adsorbent and Investigation of its Applicability in the Adsorptive Removal of Cr (VI) Ion from Aqueous Solution

[{“box”:0,”content”:”

n

Home

n

 > 

n

ijpse

n

 > 

n

Article

n

Views: 1,292

n

n

n

n

n

By [foreach 286]u00a0

u00a0Nazia Rahman, Md Nahid Kayser, Md. Khairul Amin, Nirmal Chandra Dafader, Shahnaz Sultana, Md. Nabul Sardar, Md. Sohel Rana,

[/foreach]
nJanuary 9, 2023 at 9:01 am

n

nAbstract

n

The grafting of glycidyl methacrylate (GMA) onto non-woven polyethylene (PE) fabric was accomplished using a radiation-initiated grafting technique. The grafted textiles were allowed to react using triethylamine to create functioning amine groups. Upon bond formation yield, the impact of grafting intensity has been examined. Utilizing the appropriate technologies, such as FTIR, TGA, and SEM, the adsorbents were rigorously examined. There was evidence of GMA grafting and diamines according to FTIR, TGA, and Tem analyses. For the purpose of adsorbing clearance of Cr (VI) ions from aqueous solution, amino cluster GMA-g-non-woven PE films was drenched in HCl to promote anionic metal adsorption. Adsorption capacity was investigated through varying the adsorption parameters. Contact time changed from 1 to 26 h, pH changed from 1.2 to 6, temperature changed from 30 to 75ºC and initial metal ion concentration changed from 200 to 1000 mg/L. The optimal circumstance that can lead highest adsorption of Cr (VI) by the adsorbent was established to be contact time 24 hours and initial metal concentration 600 mg/L, pH 1.2 and temperature 75ºC. Langmuir and Freundlich isotherm model were used for the analysis of Cr (VI) adsorption process by the adsorbent to understand and explain the adsorption mechanism. The equilibrium experimental data of Cr (VI) adsorption exhibited better matching with Langmuir isotherm model proposing the formation of monolayer saturation on the adsorbent surface. The highest adsorption capacity derived from Langmuir isotherm model was 50.76 mg/g. The adsorption kinetics was inspected by means of pseudo-first order and pseudo-second-order models with the aid of a pseudo-second-order equation, the adsorption equilibrium of Cr (VI) ion could’ve been effectively constructed. The satisfactory outcome of investigation of desorption of Cr (VI) and reuse of the adsorbent film proposed the prospect of recycling of the polymer adsorbent in case of practical application..

n

n

n

n

Volume :u00a0u00a08 | Issue :u00a0u00a01 | Received :u00a0u00a0March 4, 2022 | Accepted :u00a0u00a0March 27, 2022 | Published :u00a0u00a0July 8, 2022n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)] [/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue Fabrication of a Novel and Efficient Radiation Grafted Functionalized Polymer Adsorbent and Investigation of its Applicability in the Adsorptive Removal of Cr (VI) Ion from Aqueous Solution under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]
Keywords Polyethylene, Glycidyl methacrylate, Radiation grafting, Chromium adsorption, Adsorption isotherm, Adsorption kinetics.

n

n

n

n

n

n[if 992 equals=”Transformative”]

n

n

Full Text

n

n

n

[/if 992][if 992 not_equal=”Transformative”]

n

n

Full Text

n

n

n

[/if 992] n

nn

[if 379 not_equal=””]n

[foreach 379]n

n[/foreach]

n[/if 379]

n

References

n[if 1104 equals=””]n

1. Lin SH, Juang RS. Heavy Metal Removal from Water by Sorption Using Surfactant Modified Montmorillonite. J. Hazard. Mater. 2002; 92: 315–326.
2. Hajeeth T, Sudha PN, Vijayalakshmi K. Removal of Cr (VI) from Aqueous Solution Using Graft Copolymer of Cellulose Extracted from Sisal Fibre with Acrylic Acid Monomer. Cellul. Chem. Technol. 2015: 49: 891–900.
3. Chowdhury M, Mostafa MG, Biswas,et al TK.Characterization of the Effluents from Leather Processing Industries. Environ. Process. 2015; 2: 173–187.
4. Lofrano G, Carotenuto M, Gautam RK, et al. Heavy Metals in Tannery Wastewater and Sludge: Environmental Concerns and Future Challenges. Heavy Met. Water. 2014; 12: 249–260.
5. Alam M.N., Sayid Mia MA, Ahmad F, Rahman MM. Adsorption of Chromium (Cr) from Tannery Wastewater Using Low-cost Spent Tea Leaves Adsorbent. Appl. Water Sci. 2018 8: 1–7.
6. Islam S, Islam F, Bakar MA, et al. Heavy Metals Concentration at Different Tannery Wastewater Canal of Chittagong City in Bangladesh. Int. J. Agric. Environ. Biotechnol. 2013; 6: 355.
7. Ünlü N, Ersoz M.Adsorption Characteristics of Heavy Metal Ions onto a Low Cost Biopolymeric Sorbent from Aqueous Solutions. J.Hazard.Mater. 2006; 136: 272–280.
8. Celik A, Demirbas A.Removal of Heavy Metal Ions from Aqueous Solutions via Adsorption onto Modified Lignin from Pulping Wastes. Energy Sources. 2005; 27: 1167–1177.
9. Kumar PS, Ramalingam S, Sathyaselvabala V,et al. Removal of Cadmium (II) from Aqueous Solution by Agricultural Waste Cashew Nut Shell. Korean J. Chem. Eng. 2012, 29: 756–768.
10. Krowiak AW. Application of Beech Sawdust for Removal of Heavy Metals from Water: Biosorption and Desorption Studies. Eur. J. Wood Wood Prod. 2013; 71: 227–236.
11. Cimen A, Bilgic A, Kursunlu AN, et al. Adsorptive Removal of Co (II), Ni (II), and Cu (II) Ions from Aqueous Media Using Chemically Modified Sporopollenin of Lycopodium clavatum as Novel Biosorbent. Desalin. Water Treat. 2014; 52: 4837–4847.
12. Schmuhl R, Krieg HM, Keizer K. Adsorption of Cu (II) and Cr (VI) Ions by Chitosan: Kinetics and Equilibrium Studies, Water SA. 2001; 27: 1–7.
13. Ho YS, Ng JCY, McKay G. Removal of Lead (II) from Effluents by Sorption on Peat Using Second-Order Kinetics. Sep. Sci. Technol. 2001;36: 241–261.
14. Shukla SR, Sakhardande VD. Metal Ion Removal by Dyed Cellulosic Materials, J. Appl. Polym. Sci. 1991 42: 829–835.
15. Nasef MM, Ting TM, Abbasi A, et al. Radiation Grafted Adsorbents for Newly Emerging Environmental Applications,” Radiat. Phys. Chem. 2014; 118, 55–60.
16. Yiǧitoǧlu M, Arslan M. Adsorption of Hexavalent Chromium from Aqueous Solutions Using 4-vinyl pyridine Grafted poly (ethylene terephthalate) fibers. Polym. Bull. 2005; 55: 259–268.
17. Ping X, Wang M, Ge X. Radiation Induced Graft Copolymerization of n-butyl acrylate onto Poly(ethylene terephthalate) (PET) Films and Thermal Properties of the Obtained Graft Copolymer. Radiat. Phys. Chem. 2011; 80: 632–637.
18. Deng S, Bai R. Removal of Trivalent and Hexavalent Chromium with Aminated Polyacrylonitrile Fibers: Performance and Mechanisms. Water Res. 2004; 38: 2424–2432.
19. Kim S, Lee TG. Removal of Cr (VI) from Aqueous Solution Using Functionalized poly(GMA-co-EGDMA)-graft-poly (allylamine), React. Funct. Polym. 2019; 134:133–140.
20. Coşkun R, Soykan C, Saçak M. Adsorption of Copper (II), Nickel (II) and Cobalt (II) Ions from aqueous Solution by Methacrylic acid/Acrylamide Monomer Mixture Grafted poly(ethylene terephthalate) Fiber. Sep. Purif. Technol. 2006; 49: 107–114.
21. Yiǧitoǧlu M, Arslan M. Selective Removal of Cr (VI) Ions from Aqueous Solutions Including Cr (VI), Cu (II) and Cd (II) Ions by 4-vinly pyridine/2-hydroxyethylmethacrylate Monomer Mixture Grafted poly(ethylene terephthalate) Fiber. J. Hazard. Mater. 2009; 166: 435–444.
22. Karakişla M. The Adsorption of Cu (II) Ion from Aqueous Solution upon Acrylic acid Grafted poly(ethylene terephthalate) Fibers. J. Appl. Polym. Sci. 2002; 87: 1216–1220.
23. Arslan M. Preparation and Use of Amine-functionalized Glycidyl methacrylate-g-poly(ethylene terephthalate) Fibers for Removal of Chromium (VI) from Aqueous Solution. Fibers Polym. 2010; 11: 325–330.
24. Abdel-Bary EM, Sarhan AA, Abdel-Razik HH. Effect of Graft Copolymerization of 2-hydroxyethyl methacrylate on the Properties of Polyester Fibres and Fabric. J. Appl. Polym. Sci. 1988; 35: 439–448.
25. Nasef MM.Gamma Radiation-induced Graft Copolymerization of Styrene onto poly (ethylene terephthalate) Films. J. Appl. Polym. Sci. 2000; 77: 1003–1012.
26. Rahman N, Hossen MS, Miah AR, et al. Removal of Cu (II), Pb (II) and Cr (VI) ions from aqueous solution using amidoximated non-woven polyethylene-g-acrylonitrile fabric, J Environ Health Sci Eng 2019; 17: 183–194.
27. Hegazy EA., Kamal H, Maziad N, et al. Membranes prepared by radiation grafting of binary monomers for adsorption of heavy metals from industrial wastes. Nucl Instrum Meth B. 1999; 151: 386–392.
28. Hegazy EA., Kamal H, Khalifa NA, et al. Separation and extraction of some heavy and toxic metal ions from their wastes by grafted membranes. J Appl Polym Sci 2001; 81: 849–860.
29. Hegazy EA, Abd El-Rehim HA, Ali AMI, et al. Characterization and application of radiation grafted membranes in treatment of intermediate active waste. Nucl Instrum Meth B 1999; 151: 393–398.
30. Abd El-Rehim HA., Hegazy EA., Ali AE. Selective removal of some heavy metal ions from aqueous solution using treated polyethylene-g-styrene/maleic anhydride membranes. React Funct Polym 2000; 43: 105–116.
31. Choi SH, Nho YC, Kim GT. Adsorption of Pb2+ and Pd2+ on polyethylene membrane with amino group modified by radiation-induced graft copolymerization. J. Appl. Polym. Sci. 1999; 7: 643–650. 32. Namasivayam C, Arası DJSE. Removal of Congo Red from Wastewater by Adsorption onto Waste Red Mud. Chemosphere. 1997; 34: 401–417.
33. Ho YS. Review of Second-order Models for Adsorption Systems. J. Hazard. Mater. 2006; 136: 681–689.
34. Langmuir I. The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum. Chem. Soc. 1998; 40, 1361–1403.
35. Freundlich HMF. Over the Adsorption in Solution. J. Phys.Chem. 1906; 57: 385–471.
36. Yaday SK, Dixit AK. Efficient Removal of Cr (VI) from Aqueous Solution onto Palm Trunk Charcoal: Kinetic and Equilibrium Studies. Chem Sci J, 2016; 7:1-7.
37. Hu XZ. Adsorption of Chromium (VI) by Ethylenediamine Modified Cross-linked Magnetic Chitosan Resin: Isotherms, Kinetics and Thermodynamics. J. Hazard. Mater. 2011; 185: 306–314.
38. Gode F, Atalay ED, Pehlivan E. Removal of Cr (VI) from Aqueous Solution Using Modified Red Pine Sawdust. J. Hazard. Mater, 2008; 152: 1201–1207.
39. Kumar ASK, Kumar CU, Rajesh V, et al. Microwavw Assisted Preparation of N-butyl Acrylate Grafted Chitosan and Its Application for Cr (VI) Adsorption, Int. J. Biol. Macromol, 2014; 66: 135–143.
40. Wu Y, Ming Z, Yang S, et al. Adsorption of Hexavalet Chromium onto Bamboo Charcoal grafted by Cu2+-N-aminopropylsilane Complexes: Optimization, Kinetic and Isotherm Studies. J. Indust. Eng. Chem. 2017;46: 222–233.
41. Sharma G, Naushad M, Al-Muhtaseb AH, et al. Fabrication and Charactyerization of Chitosan-crosslinked-poly (alginiacid) Nanohydrogel for Adsorptive Removal of Cr (VI) Metal Ion from Aqueous Medium. Int. J. Biol. Macromol. 2017; 95: 484–493.

nn[/if 1104] [if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””], [/if 1106]

    2. n[/foreach]

n[/if 1104]

n[if 1114 equals=”Yes”]n

n[/if 1114]

n

n

[if 424 not_equal=”Regular Issue”] Regular Issue[/if 424] Open Access Article

n

International Journal of Polymer Science & Engineering

ISSN: 2455-8745

Editors Overview

ijpse maintains an Editorial Board of practicing researchers from around the world, to ensure manuscripts are handled by editors who are experts in the field of study.

n

“},{“box”:4,”content”:”

n“},{“box”:1,”content”:”

    By  [foreach 286]n

  1. n

    Nazia Rahman, Md Nahid Kayser, Md. Khairul Amin, Nirmal Chandra Dafader, Shahnaz Sultana, Md. Nabul Sardar, Md. Sohel Rana

    n

    2. [/foreach]

n

    [foreach 286] [if 1175 not_equal=””]n t

  1. Principal Scientific Officer, Student, Assistant Professor, Chief Scientific Officer, Senior Scientific Officer, Scientific Officer, Student,Institute of Nuclear Science and Technology, Khulna University, Khulna University, Institute of Nuclear Science and Technology, Institute of Nuclear Science and Technology, Institute of Nuclear Science and Technology, University of Dhaka,Dhaka, Dhaka, Dhaka, Dhaka, Dhaka,Bangladesh, Bangladesh, Bangladesh, Bangladesh, Bangladesh, Bangladesh, Bangladesh

    2. n[/if 1175][/foreach]

n

n

n

n

n

Abstract

nThe grafting of glycidyl methacrylate (GMA) onto non-woven polyethylene (PE) fabric was accomplished using a radiation-initiated grafting technique. The grafted textiles were allowed to react using triethylamine to create functioning amine groups. Upon bond formation yield, the impact of grafting intensity has been examined. Utilizing the appropriate technologies, such as FTIR, TGA, and SEM, the adsorbents were rigorously examined. There was evidence of GMA grafting and diamines according to FTIR, TGA, and Tem analyses. For the purpose of adsorbing clearance of Cr (VI) ions from aqueous solution, amino cluster GMA-g-non-woven PE films was drenched in HCl to promote anionic metal adsorption. Adsorption capacity was investigated through varying the adsorption parameters. Contact time changed from 1 to 26 h, pH changed from 1.2 to 6, temperature changed from 30 to 75ºC and initial metal ion concentration changed from 200 to 1000 mg/L. The optimal circumstance that can lead highest adsorption of Cr (VI) by the adsorbent was established to be contact time 24 hours and initial metal concentration 600 mg/L, pH 1.2 and temperature 75ºC. Langmuir and Freundlich isotherm model were used for the analysis of Cr (VI) adsorption process by the adsorbent to understand and explain the adsorption mechanism. The equilibrium experimental data of Cr (VI) adsorption exhibited better matching with Langmuir isotherm model proposing the formation of monolayer saturation on the adsorbent surface. The highest adsorption capacity derived from Langmuir isotherm model was 50.76 mg/g. The adsorption kinetics was inspected by means of pseudo-first order and pseudo-second-order models with the aid of a pseudo-second-order equation, the adsorption equilibrium of Cr (VI) ion could’ve been effectively constructed. The satisfactory outcome of investigation of desorption of Cr (VI) and reuse of the adsorbent film proposed the prospect of recycling of the polymer adsorbent in case of practical application..n

n

n

Keywords: Polyethylene, Glycidyl methacrylate, Radiation grafting, Chromium adsorption, Adsorption isotherm, Adsorption kinetics.

n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)]

n[/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]

n

n

n

n[if 992 equals=”Transformative”]n

n

n

Full Text

n

n

nn[/if 992]n[if 992 not_equal=”Transformative”]n

n

Full Text

n

n

n

n

[/if 992]n[if 379 not_equal=””]

Browse Figures

n

n

[foreach 379]n

n[/foreach]

n

[/if 379]n

n

References

n[if 1104 equals=””]

1. Lin SH, Juang RS. Heavy Metal Removal from Water by Sorption Using Surfactant Modified Montmorillonite. J. Hazard. Mater. 2002; 92: 315–326.
2. Hajeeth T, Sudha PN, Vijayalakshmi K. Removal of Cr (VI) from Aqueous Solution Using Graft Copolymer of Cellulose Extracted from Sisal Fibre with Acrylic Acid Monomer. Cellul. Chem. Technol. 2015: 49: 891–900.
3. Chowdhury M, Mostafa MG, Biswas,et al TK.Characterization of the Effluents from Leather Processing Industries. Environ. Process. 2015; 2: 173–187.
4. Lofrano G, Carotenuto M, Gautam RK, et al. Heavy Metals in Tannery Wastewater and Sludge: Environmental Concerns and Future Challenges. Heavy Met. Water. 2014; 12: 249–260.
5. Alam M.N., Sayid Mia MA, Ahmad F, Rahman MM. Adsorption of Chromium (Cr) from Tannery Wastewater Using Low-cost Spent Tea Leaves Adsorbent. Appl. Water Sci. 2018 8: 1–7.
6. Islam S, Islam F, Bakar MA, et al. Heavy Metals Concentration at Different Tannery Wastewater Canal of Chittagong City in Bangladesh. Int. J. Agric. Environ. Biotechnol. 2013; 6: 355.
7. Ünlü N, Ersoz M.Adsorption Characteristics of Heavy Metal Ions onto a Low Cost Biopolymeric Sorbent from Aqueous Solutions. J.Hazard.Mater. 2006; 136: 272–280.
8. Celik A, Demirbas A.Removal of Heavy Metal Ions from Aqueous Solutions via Adsorption onto Modified Lignin from Pulping Wastes. Energy Sources. 2005; 27: 1167–1177.
9. Kumar PS, Ramalingam S, Sathyaselvabala V,et al. Removal of Cadmium (II) from Aqueous Solution by Agricultural Waste Cashew Nut Shell. Korean J. Chem. Eng. 2012, 29: 756–768.
10. Krowiak AW. Application of Beech Sawdust for Removal of Heavy Metals from Water: Biosorption and Desorption Studies. Eur. J. Wood Wood Prod. 2013; 71: 227–236.
11. Cimen A, Bilgic A, Kursunlu AN, et al. Adsorptive Removal of Co (II), Ni (II), and Cu (II) Ions from Aqueous Media Using Chemically Modified Sporopollenin of Lycopodium clavatum as Novel Biosorbent. Desalin. Water Treat. 2014; 52: 4837–4847.
12. Schmuhl R, Krieg HM, Keizer K. Adsorption of Cu (II) and Cr (VI) Ions by Chitosan: Kinetics and Equilibrium Studies, Water SA. 2001; 27: 1–7.
13. Ho YS, Ng JCY, McKay G. Removal of Lead (II) from Effluents by Sorption on Peat Using Second-Order Kinetics. Sep. Sci. Technol. 2001;36: 241–261.
14. Shukla SR, Sakhardande VD. Metal Ion Removal by Dyed Cellulosic Materials, J. Appl. Polym. Sci. 1991 42: 829–835.
15. Nasef MM, Ting TM, Abbasi A, et al. Radiation Grafted Adsorbents for Newly Emerging Environmental Applications,” Radiat. Phys. Chem. 2014; 118, 55–60.
16. Yiǧitoǧlu M, Arslan M. Adsorption of Hexavalent Chromium from Aqueous Solutions Using 4-vinyl pyridine Grafted poly (ethylene terephthalate) fibers. Polym. Bull. 2005; 55: 259–268.
17. Ping X, Wang M, Ge X. Radiation Induced Graft Copolymerization of n-butyl acrylate onto Poly(ethylene terephthalate) (PET) Films and Thermal Properties of the Obtained Graft Copolymer. Radiat. Phys. Chem. 2011; 80: 632–637.
18. Deng S, Bai R. Removal of Trivalent and Hexavalent Chromium with Aminated Polyacrylonitrile Fibers: Performance and Mechanisms. Water Res. 2004; 38: 2424–2432.
19. Kim S, Lee TG. Removal of Cr (VI) from Aqueous Solution Using Functionalized poly(GMA-co-EGDMA)-graft-poly (allylamine), React. Funct. Polym. 2019; 134:133–140.
20. Coşkun R, Soykan C, Saçak M. Adsorption of Copper (II), Nickel (II) and Cobalt (II) Ions from aqueous Solution by Methacrylic acid/Acrylamide Monomer Mixture Grafted poly(ethylene terephthalate) Fiber. Sep. Purif. Technol. 2006; 49: 107–114.
21. Yiǧitoǧlu M, Arslan M. Selective Removal of Cr (VI) Ions from Aqueous Solutions Including Cr (VI), Cu (II) and Cd (II) Ions by 4-vinly pyridine/2-hydroxyethylmethacrylate Monomer Mixture Grafted poly(ethylene terephthalate) Fiber. J. Hazard. Mater. 2009; 166: 435–444.
22. Karakişla M. The Adsorption of Cu (II) Ion from Aqueous Solution upon Acrylic acid Grafted poly(ethylene terephthalate) Fibers. J. Appl. Polym. Sci. 2002; 87: 1216–1220.
23. Arslan M. Preparation and Use of Amine-functionalized Glycidyl methacrylate-g-poly(ethylene terephthalate) Fibers for Removal of Chromium (VI) from Aqueous Solution. Fibers Polym. 2010; 11: 325–330.
24. Abdel-Bary EM, Sarhan AA, Abdel-Razik HH. Effect of Graft Copolymerization of 2-hydroxyethyl methacrylate on the Properties of Polyester Fibres and Fabric. J. Appl. Polym. Sci. 1988; 35: 439–448.
25. Nasef MM.Gamma Radiation-induced Graft Copolymerization of Styrene onto poly (ethylene terephthalate) Films. J. Appl. Polym. Sci. 2000; 77: 1003–1012.
26. Rahman N, Hossen MS, Miah AR, et al. Removal of Cu (II), Pb (II) and Cr (VI) ions from aqueous solution using amidoximated non-woven polyethylene-g-acrylonitrile fabric, J Environ Health Sci Eng 2019; 17: 183–194.
27. Hegazy EA., Kamal H, Maziad N, et al. Membranes prepared by radiation grafting of binary monomers for adsorption of heavy metals from industrial wastes. Nucl Instrum Meth B. 1999; 151: 386–392.
28. Hegazy EA., Kamal H, Khalifa NA, et al. Separation and extraction of some heavy and toxic metal ions from their wastes by grafted membranes. J Appl Polym Sci 2001; 81: 849–860.
29. Hegazy EA, Abd El-Rehim HA, Ali AMI, et al. Characterization and application of radiation grafted membranes in treatment of intermediate active waste. Nucl Instrum Meth B 1999; 151: 393–398.
30. Abd El-Rehim HA., Hegazy EA., Ali AE. Selective removal of some heavy metal ions from aqueous solution using treated polyethylene-g-styrene/maleic anhydride membranes. React Funct Polym 2000; 43: 105–116.
31. Choi SH, Nho YC, Kim GT. Adsorption of Pb2+ and Pd2+ on polyethylene membrane with amino group modified by radiation-induced graft copolymerization. J. Appl. Polym. Sci. 1999; 7: 643–650. 32. Namasivayam C, Arası DJSE. Removal of Congo Red from Wastewater by Adsorption onto Waste Red Mud. Chemosphere. 1997; 34: 401–417.
33. Ho YS. Review of Second-order Models for Adsorption Systems. J. Hazard. Mater. 2006; 136: 681–689.
34. Langmuir I. The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum. Chem. Soc. 1998; 40, 1361–1403.
35. Freundlich HMF. Over the Adsorption in Solution. J. Phys.Chem. 1906; 57: 385–471.
36. Yaday SK, Dixit AK. Efficient Removal of Cr (VI) from Aqueous Solution onto Palm Trunk Charcoal: Kinetic and Equilibrium Studies. Chem Sci J, 2016; 7:1-7.
37. Hu XZ. Adsorption of Chromium (VI) by Ethylenediamine Modified Cross-linked Magnetic Chitosan Resin: Isotherms, Kinetics and Thermodynamics. J. Hazard. Mater. 2011; 185: 306–314.
38. Gode F, Atalay ED, Pehlivan E. Removal of Cr (VI) from Aqueous Solution Using Modified Red Pine Sawdust. J. Hazard. Mater, 2008; 152: 1201–1207.
39. Kumar ASK, Kumar CU, Rajesh V, et al. Microwavw Assisted Preparation of N-butyl Acrylate Grafted Chitosan and Its Application for Cr (VI) Adsorption, Int. J. Biol. Macromol, 2014; 66: 135–143.
40. Wu Y, Ming Z, Yang S, et al. Adsorption of Hexavalet Chromium onto Bamboo Charcoal grafted by Cu2+-N-aminopropylsilane Complexes: Optimization, Kinetic and Isotherm Studies. J. Indust. Eng. Chem. 2017;46: 222–233.
41. Sharma G, Naushad M, Al-Muhtaseb AH, et al. Fabrication and Charactyerization of Chitosan-crosslinked-poly (alginiacid) Nanohydrogel for Adsorptive Removal of Cr (VI) Metal Ion from Aqueous Medium. Int. J. Biol. Macromol. 2017; 95: 484–493.

n[/if 1104][if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””],[/if 1106]

    2. n[/foreach]

n[/if 1104]

n

n[if 1114 equals=”Yes”]n

n[/if 1114]”},{“box”:2,”content”:”

Regular Issue Open Access Article

n

n

n

n

n

International Journal of Polymer Science & Engineering

n

[if 344 not_equal=””]ISSN: 2455-8745[/if 344]

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

Volume 8
Issue 1
Received March 4, 2022
Accepted March 27, 2022
Published July 8, 2022

n

n

Views: 1,292

n

n

Editor

n

n

n

Reviewer

n

n

n n

n”},{“box”:6,”content”:”“}]

Read More
IJPSE

Synthesis Innovative Cyclic Formazan Compounds for the First Time and Evaluation of Their Biological Activity

[{“box”:0,”content”:”

n

Home

n

 > 

n

ijpse

n

 > 

n

Article

n

Views: 1,302

n

n

n

n

n

By [foreach 286]u00a0

u00a0Nagham Mahmood Aljamali,

[/foreach]
nJanuary 9, 2023 at 10:30 am

n

nAbstract

n

The research included the invention of cyclic formazan compounds for the first time in this research that carried out in April 2021, where the usual formazan compounds were previously attended, but in the current research we attended the cyclic formazan compounds as innovative compounds and after that they were diagnosed by reliable chemical means of measurement, that provided vibrant indication of their chemical constructions via numerous technical apparatuses similar (FT IR-Bands, 1H.NMRPeeaks, Mass-Identification). Melting points, other studies represented by antimicrobial Evaluation., These Compounds have been distinguished by their bright colors and their using as fixed dyes for many tissues and as anti-corrosion materials , and as a ligands with transitional elements as coordination complexes., The results appeared good evidence for efficiency of Innovative Cyclic formazan derivatives that compounds gave high inhibition in bacteria more than other compounds via creation of band of formazan (-N=C-N=N-) in innovated derivative more than initial materials beginning Aldamine compounds that produced inhibition action of bacteria.

n

n

n

n

Volume :u00a0u00a07 | Issue :u00a0u00a02 | Received :u00a0u00a0December 9, 2021 | Accepted :u00a0u00a0December 27, 2021 | Published :u00a0u00a0December 31, 2021n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)] [/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue Synthesis Innovative Cyclic Formazan Compounds for the First Time and Evaluation of Their Biological Activity under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]
Keywords Cyclic formazan, formazan, imine, schiff base, Azo, antimicrobial study.

n

n

n

n

n

n[if 992 equals=”Transformative”]

n

n

Full Text

n

n

n

[/if 992][if 992 not_equal=”Transformative”]

n

n

Full Text

n

n

n

[/if 992] n

nn

[if 379 not_equal=””]n

[foreach 379]n

n[/foreach]

n[/if 379]

n

References

n[if 1104 equals=””]n

1. Nagham Mahmood Aljamali. Inventing of Macrocyclic Formazan Compounds and Studying Them Against Breast Cancer for The first Time Globally. Annals of pharma research. 2021; 9 (7): 525-533. Available at:https://www.annalsofpharmaresearch.com/index.php?journal=apr&page =article&op=view&path%5B%5D=38.
2. Nagham Mahmood Aljamali. Creation of Innovated Macrocyclic Sulfazan-Formazan Compounds and Linear Sulfazan-Formazan for the first Time Globally with their Assay as Antifungal., Biomedical. Journal of Scientific & Technical Research. 2021; 40(3): 32266-3227, DOI: 10.26717/BJSTR.2021.40.006453.
3. Nagham Mahmood Aljamali. Review on (Azo, Formazane, Sulfazane)-Compounds. International Journal of Innovations in Scientific Engineering. 2019; 10: 19-45.
4. Grant CM. Role of the glutathione/glutaredoxin and thioredoxin systems in yeast growth and response to stress conditions””. Molecular Microbiology. 2001; 39(3): 533–541. doi:10.1046/j.1365-2958.2001.02283.x.
5. Miad Mohmed, Sabreen Ali Abdalrahman., Wassan Ala Shubber., et.al. Formation of Oxadiazole Derivatives Ligands from Condensation and Imination Reaction with References To Spectral Investigation, Thermal and Microbial Assay. Biochem. Cell. Arch. 2018;18(1): 847-853.
6. Nagham Mahmood Aljamali. The Various Preparation Methods in Synthetic Chemistry.1st ed. Chattisgarh, India: Evincepub Publishing house. 2019. ISBN :978-93-88277-82-2.
7. Nagham Mahmood Aljamali. Reactions and Mechanisms. 1st ed. IJMRA Publication. 2018. ISBN: 978- 93-87176-25-6.
8. Nagham Mahmood Aljamali. Experimental Methods for Preparation of Mannich Bases, Formazan, Normal and Cyclic Sulfur Compounds. 1st edition. Chattisgarh, India: Evince pub Publishing House; 2018. ISBN: 978-93-87905-19-1.
9. Nagham Mahmood Aljamali. Alternative Methods in Organic Synthesis. 1th–Edition. Europe: Eliva Press SRL; 2020. ISBN: 9798680201176.
10. Nagham Mahmood Aljamali. Effect of Conditions and Catalysis on Products. 1st Ed. Europe: Eliva Press SRL; 2021. ISBN: 9781636482286.
11. Nagham Mahmood Aljamali. Synthesis and Biological Study of Hetero (Atoms and Cycles) Compounds. Der Pharma Chemica. 2016; 8(6): 40-48.
12. Matheus ME, de Almeida Violante F, Garden SJ. Isatins inhibit cyclooxygenase-2 and inducible nitric oxide synthase in a mouse macrophage cell line. Eur J Pharmacol. 2007; 556(1-3) :200–206.
13. Karm Alan, Hasaneen Kudhair Abdullabass, et.al. Invention of (Gluta. Sulfazane-Cefixime) Compounds as Inhibitors of Cancerous Tumors. Journal of Cardiovascular Disease Research. 2020; 11(2): 44-55. DOI: 10.31838/jcdr.2020.11.02.09.
14. Nagham Mahmood Aljamali. Synthesis and Chemical Identification of Macro Compounds of (Thiazol and Imidazol). Research J. Pharm. and Tech. 2015; 8(1): 78-84. DOI: 10.5958/0974-360X.2015.00016.5.
15. Mestaf M, Nawfel Muhammed Baqer Muhsin., NeuroQuantology, 2019.,17,11, 11-16.,10.14704/nq.2019. 17.11.NQ19108.
16. Nagham Mahmood Aljamali. Synthesis of Antifungal Chemical Compounds from Fluconazole with (Pharma-Chemical) Studying. Research journal of Pharmaceutical, biological and chemical sciences. 2017; 8 (3): 564 -573.
17. Mehta SL, Manhas N, Raghubiz R. Molecular targets in cerebral ischemia for developing novel therapeutics. Brain Res Rev. 2007; 54: 34–66.
18. Meaaed M, Nagham Mahmood Aljamali, Nadheema A A. Preparation, Spectral Investigation, Thermal Analysis, Biochemical Studying of New (Oxadiazole -Five Membered Ring)-Ligands. Journal of Global Pharmacy Technology. 2018;10(1): 20-29.
19. Nagham Mahmood Aljamali. Survey on Methods of Preparation and Cyclization of Heterocycles. International Journal of Chemical and Molecular Engineering. 2020; 6(2): 19–36.
20. Mieaad M, Wassan Ala Shubber., Sabreen Ali Abdalrahman, et.al. New Azomethine- Azo Heterocyclic Ligands Via Cyclization of Ester. Research Journal of Pharmacy and Technology. 2018; 11(6): 2555-2560., DOI: 10.5958/0974-360X. 2018. 00472.9 .
21. Hasaneen Kudhair Abdullabass, Aseel Mahmood Jawad, et.al. Synthesis of drugs derivatives as inhibitors of cancerous cells., Biochem. Cell. Arch. 2020; 20(2). DocID: https://connectjournals.com/03896.2020.20.5315.
22. Nagham Mahmood Aljamali, Intisar Obaid Alfatlawi. Synthesis of Sulfur Heterocyclic Compounds and Study of Expected Biological Activity. Research J. Pharm. and Tech. 2015; 8(9): 1225-1242. DOI: 10.5958/0974-360X.2015 .00224.3.
23. Nagham Mahmood Aljamali, Kam Alwan. Development of Trimethoprim Drug and Innovation of Sulfazane-Trimethoprim Derivatives as Anticancer Agents. Biomedical & Pharmacology Journal. 2020; 13(2): 613-625. http://dx.doi.org/10.13005/bpj/1925.
24. Hussein Ali Ahmed, Nagham Mahmood Aljamali. Preparation, Characterization, Antibacterial Study, Toxicity Study of New Phenylene diamine- Formazan Derivatives. Indian Journal of Forensic Medicine & Toxicology. 2021; 15(2).
25. Nagham Mahmood Aljamali, Hussein Mejbel Azeez. Synthesis and Characterization of Some New Formazan – Cefixime and Study of Against Breast Cancer Cells. Annals of R.S.C.B. 2021; 25(4): 8562-8578. ISSN:1583-6258.
26. Nagham Mahmood Aljamali, Asmaa, Kefah Mahdi. Synthesis, Identification and Anticancer Studying of Heterocyclic- Mefenamic Drug via Thiosemicarbazide., Annals of R.S.C.B. 2021; 25(4): 8521-8537. ISSN:1583-6258.
27. Nagham Mahmood Aljamali, Tabark Emad Al-Faham. Synthesis, Identification, Chromatographic Studying of Formazane –Phenylenediamine Derivatives., Annals of R.S.C.B., ISSN:1583-6258, Vol. 25, Issue 4, 2021.
28. Intisar Obaid Alfatlawi, Nuha S S, Zainab M J., et.al. Synthesis of New Organic Compounds Via Three Components Reaction with Studying of (Identification, Thermal Behavior, Bioactivity on Bacteria of Teeth). Journal of Global Pharma Technology. 2017;11(9): 157-164.
29. Naumann d’Alnoncourt, Raoul; Csepei, Lénárd-István; Hävecker, Michael; et.al. The reaction network in propane oxidation over phase-pure MoVTeNb M1 oxide catalysts. Journal of Catalysis. 2014;311: 369–385.
30. Nagham Mahmood Aljamali.; Saher Mahmood Jawd.; Zainab M J., et.al. Inhibition activity of (Azo–acetyl acetone) on bacteria of mouth. Research Journal of Pharmacy and Technology. 2017; 10(6):1683-1686. DOI: 10.5958/0974-360X.2017.00297.9.
31. Mokrani, Touhami; van Reenen, Albert; Amer, Ismael. Molecular weight and toxicity effect on morphological and mechanical properties of Ziegler–Natta catalyzed isotactic polypropylenes””. Polímeros. 2015; 25(6): 556–563. doi:10.1590/0104-1428.2158 . ISSN 0104-1428.
32. Dub, Pavel A.; Gordon, John C.The role of the metal-bound N–H functionality in Noyori-type molecular catalysts””. Nature Reviews Chemistry. 2018; 2(12): 396–408.
33. Nagham Mahmood Aljamali. (Synthesis, Investigation, Chromatography, Thermal)- Behavior of (Five, Seven)- Membered Ring with Azo and Anil Compounds. Pak. J. Biotechnol. 2018; 15(1): 219-239.
34. Aseel Mahmood Jawad., Nagham Mahmood Aljamali, Saher Mahmood Jawd. Development and Preparation of ciprofloxacin Drug Derivatives for Treatment of Microbial Contamination in Hospitals and Environment. Indian Journal of Forensic Medicine & Toxicology. 2020; 14(2): 1115-1122.
35. Nagham Mahmood Aljamali. Spectral and Laboratory Diagnostics of Compounds. 1st –Edition. Europe: Eliva Press SRL; 2021. ISBN: 9781636482118.
36. Shireen R. Rasool, Nagham Mahmood Aljamali, Ali Jassim Al-Zuhairi. Guanine substituted heterocyclic derivatives as bioactive compounds. Biochem. Cell. Arch. 2020; 20: 3651-3655, 2020, DocID: https://connectjournals.com/03896.2020.20.3651.
37. Pompella A, Visvikis A, Paolicchi A, et.al. The changing faces of glutathione, protagonist””. Biochemical Pharmacology. 2003; 66(8):1499–1503.doi:10.1016/S0006-2952 (03) 00504-5.
38. Wonisch W, Schaur RJ. Chapter 2: Chemistry of Glutathione””. In Grill D, Tausz T, De Kok L (eds.). Significance of glutathione in plant adaptation to the environment. Germany: Springer; 2001. ISBN 978-1-4020-0178-9 – via Google Books.
39. Aljamali D, Mahmood N, Jawad SF. Preparation, Spectral Characterization, Thermal Study, and Antifungal Assay of (Formazane-Mefenamic acid)-Derivatives. Egyptian Journal of Chemistry. 2022; 65(2): 449-457.
40. Pastore A, Piemonte F, Locatelli M, et.al. Determination of blood total, reduced, and oxidized glutathione in pediatric subjects. Clinical chemistry. 2001;47(8):1467-1470.
41. Lu SC (2013). Glutathione synthesis. Biochimica et Biophysica Acta. 2013; 1830(5): 3143–3153. doi:10.10 16/j.bbagen.2012.09.008. PMC 3549305. PMID 22995213.
42. Halprin KM, Ohkawara A. The measurement of glutathione in human epidermis using glutathione reductase””. The Journal of Investigative Dermatology. 1967; 48(2): 149–152. doi:10.1038/jid.1967.24 . PMID 6020678.
43. Couto N, Malys N, Gaskell SJ, et.al. Partition and turnover of glutathione reductase from Saccharomyces cerevisiae: a proteomic approach””. Journal of Proteome Research. 2013; 12(6): 2885–2894. doi:10.1021 /pr4001948. PMID 23631642.
44. Dringen R. Metabolism and functions of glutathione in brain””. Progress in Neurobiology. 2000; 62(6): 649–671. doi:10.1016/s0301-0082(99)00060-x. PMID 10880854.
45. Scholz, RW. Graham KS. Gumpricht E. et.al. Mechanism of interaction of vitamin E and glutathione in the protection against membrane lipid peroxidation””. Ann NY Acad Sci. 1989; 570(1): 514–517. Bibcode:1989NYASA. 570.514S. doi:10.1111/j.1749-6632.1989.tb14973.x.
46. Hughes RE. Reduction of dehydroascorbic acid by animal tissues. Nature. 1964; 203(4949): 1068–1069. Bibcode: 1964Natur.203.1068H. doi:10.1038/2031068a0. PMID 14223080.
47. Ha SB, Smith AP, Howden R, et.al. Phytochelatin synthase genes from Arabidopsis and the yeast Schizosaccharomyces pombe. The Plant Cell. 1999; 11(6): 1153–1164. doi:10.1105/tpc.11.6.1153. JSTOR 3870806 . PMC 144235. P MID 10368185.
48. Steullet P, Neijt HC, Cuénod M, et.al. Synaptic plasticity impairment and hypofunction of NMDA receptors induced by glutathione deficit: relevance to schizophrenia. Neuroscience. 2006; 137(3): 807–819. doi:10.1016/j.neuroscience.2005.10.014 . PMID 16330153.
49. Aseel Mahmood Jawad, Nagham Mahmood Aljamali. Innovation, Preparation of Cephalexin Drug Derivatives and Studying of (Toxicity & Resistance of Infection). International Journal of Psychosocial Rehabilitation. 2020; 24(4): 3754-3767.
50. Nawfel M B, Hayder H K, Noor H D, et.al. Preparation of Chemical Inhibitors to Treat the Corrosion and Erosion of Machines. International Journal of Engineering, Applied and Management Sciences Paradigms. 2019; 54(3): 89-93.
51. Maulucci G, Labate V, Mele M, et.al. High-resolution imaging of redox signaling in live cells through an oxidation-sensitive yellow fluorescent protein. ScienceSignaling. 2008; 1 (43):pl3. doi:10.1126/scisignal .143pl3.
52. M. N Abdmajed, Nagham Mahmood Aljamali., Preparation of Benzothiazole-Formazane Reagents and Studying of (Spectral, Thermal, Scanning Microscopy, Biological Evaluation)., International Journal of Pharmaceutical Research. 2021;13(1): 4290-4300.
53. Abd Ali H, Nagham Mahmood Aljamali. Chalcone-Heterocyclic Derivatives (Synthesis, Spectral Identification, Microbial Evaluation). International Journal of Pharmaceutical Research. 2021; 13(1): 4234-4242.
54. Nor A., Sad S., Nagham Mahmood Aljamali. Synthesis, Characterization and Thermal Analysis for New Amoxil Ligands. Asian Journal of Chemistry. 2019; 31(5): 1022-1026.
55. Rajaa Abdul Ameer Ghafil, Nor A Alrb, Nagham Mahmood Aljamali. Synthesis of Triazole Derivatives via Multi Components Reaction and Studying of (Organic Characterization, Chromatographic Behavior, Chem-Physical Properties). Egypt. J. Chem. 2020; 63(11):4163-4174. DOI: 10.21608/EJCHEM.2020.23541.2399.
56. Aljamali NM. Review in azo compounds and its biological activity. Biochem Anal Biochem. 2015; 4(2):1-4. doi:10.4172/2161-1009.1000169.
57. F. Jawad, Nagham Mahmood Aljamali. Preparation, Investigation and Study of Biological Applications of Tyrosine Derivatives against Breast Cancer Cells. NeuroQuantology. 2021; 19 (9): 117-125, doi: 10.14704/nq.2021.19.9.NQ21144.
58. Aljamali NM, Jawad SF. Preparation, Diagnosis and Evaluation of Cyclic-Tryptophan Derivatives as Anti Breast Cancer Agents. Biomedical and Pharmacology Journal. 2021;14(4):1983-1991. Available from: https://bit.ly/3HuvlVG.
59. Bishop C, Hudson VM, Hilton SC, et.al. A pilot study of the effect of inhaled buffered reduced glutathione on the clinical status of patients with cystic fibrosis. Chest. 2005 Jan 1;127(1):308-317. doi:10.1378/chest .127.1 .308. PMID 15653998.
60. Mandal PK, Tripathi M, Sugunan S. Brain oxidative stress: detection and mapping of anti-oxidant marker ‘Glutathione’ in different brain regions of healthy male/female, MCI and Alzheimer patients using non-invasive magnetic resonance spectroscopy. Biochemical and Biophysical Research Communications. 2012; 417(1): 43–48. doi:10.1016/j.bbrc.2011.11.047. PMID 22120629.

nn[/if 1104] [if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””], [/if 1106]

    2. n[/foreach]

n[/if 1104]

n[if 1114 equals=”Yes”]n

n[/if 1114]

n

n

[if 424 not_equal=”Regular Issue”] Regular Issue[/if 424] Open Access Article

n

International Journal of Polymer Science & Engineering

ISSN: 2455-8745

Editors Overview

ijpse maintains an Editorial Board of practicing researchers from around the world, to ensure manuscripts are handled by editors who are experts in the field of study.

n

“},{“box”:4,”content”:”

n“},{“box”:1,”content”:”

    By  [foreach 286]n

  1. n

    Nagham Mahmood Aljamali

    n

    2. [/foreach]

n

    [foreach 286] [if 1175 not_equal=””]n t

  1. ,,,

    2. n[/if 1175][/foreach]

n

n

n

n

n

Abstract

nThe research included the invention of cyclic formazan compounds for the first time in this research that carried out in April 2021, where the usual formazan compounds were previously attended, but in the current research we attended the cyclic formazan compounds as innovative compounds and after that they were diagnosed by reliable chemical means of measurement, that provided vibrant indication of their chemical constructions via numerous technical apparatuses similar (FT IR-Bands, 1H.NMRPeeaks, Mass-Identification). Melting points, other studies represented by antimicrobial Evaluation., These Compounds have been distinguished by their bright colors and their using as fixed dyes for many tissues and as anti-corrosion materials , and as a ligands with transitional elements as coordination complexes., The results appeared good evidence for efficiency of Innovative Cyclic formazan derivatives that compounds gave high inhibition in bacteria more than other compounds via creation of band of formazan (-N=C-N=N-) in innovated derivative more than initial materials beginning Aldamine compounds that produced inhibition action of bacteria.n

n

n

Keywords: Cyclic formazan, formazan, imine, schiff base, Azo, antimicrobial study.

n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)]

n[/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]

n

n

n

n[if 992 equals=”Transformative”]n

n

n

Full Text

n

n

nn[/if 992]n[if 992 not_equal=”Transformative”]n

n

Full Text

n

n

n

n

[/if 992]n[if 379 not_equal=””]

Browse Figures

n

n

[foreach 379]n

n[/foreach]

n

[/if 379]n

n

References

n[if 1104 equals=””]

1. Nagham Mahmood Aljamali. Inventing of Macrocyclic Formazan Compounds and Studying Them Against Breast Cancer for The first Time Globally. Annals of pharma research. 2021; 9 (7): 525-533. Available at:https://www.annalsofpharmaresearch.com/index.php?journal=apr&page =article&op=view&path%5B%5D=38.
2. Nagham Mahmood Aljamali. Creation of Innovated Macrocyclic Sulfazan-Formazan Compounds and Linear Sulfazan-Formazan for the first Time Globally with their Assay as Antifungal., Biomedical. Journal of Scientific & Technical Research. 2021; 40(3): 32266-3227, DOI: 10.26717/BJSTR.2021.40.006453.
3. Nagham Mahmood Aljamali. Review on (Azo, Formazane, Sulfazane)-Compounds. International Journal of Innovations in Scientific Engineering. 2019; 10: 19-45.
4. Grant CM. Role of the glutathione/glutaredoxin and thioredoxin systems in yeast growth and response to stress conditions””. Molecular Microbiology. 2001; 39(3): 533–541. doi:10.1046/j.1365-2958.2001.02283.x.
5. Miad Mohmed, Sabreen Ali Abdalrahman., Wassan Ala Shubber., et.al. Formation of Oxadiazole Derivatives Ligands from Condensation and Imination Reaction with References To Spectral Investigation, Thermal and Microbial Assay. Biochem. Cell. Arch. 2018;18(1): 847-853.
6. Nagham Mahmood Aljamali. The Various Preparation Methods in Synthetic Chemistry.1st ed. Chattisgarh, India: Evincepub Publishing house. 2019. ISBN :978-93-88277-82-2.
7. Nagham Mahmood Aljamali. Reactions and Mechanisms. 1st ed. IJMRA Publication. 2018. ISBN: 978- 93-87176-25-6.
8. Nagham Mahmood Aljamali. Experimental Methods for Preparation of Mannich Bases, Formazan, Normal and Cyclic Sulfur Compounds. 1st edition. Chattisgarh, India: Evince pub Publishing House; 2018. ISBN: 978-93-87905-19-1.
9. Nagham Mahmood Aljamali. Alternative Methods in Organic Synthesis. 1th–Edition. Europe: Eliva Press SRL; 2020. ISBN: 9798680201176.
10. Nagham Mahmood Aljamali. Effect of Conditions and Catalysis on Products. 1st Ed. Europe: Eliva Press SRL; 2021. ISBN: 9781636482286.
11. Nagham Mahmood Aljamali. Synthesis and Biological Study of Hetero (Atoms and Cycles) Compounds. Der Pharma Chemica. 2016; 8(6): 40-48.
12. Matheus ME, de Almeida Violante F, Garden SJ. Isatins inhibit cyclooxygenase-2 and inducible nitric oxide synthase in a mouse macrophage cell line. Eur J Pharmacol. 2007; 556(1-3) :200–206.
13. Karm Alan, Hasaneen Kudhair Abdullabass, et.al. Invention of (Gluta. Sulfazane-Cefixime) Compounds as Inhibitors of Cancerous Tumors. Journal of Cardiovascular Disease Research. 2020; 11(2): 44-55. DOI: 10.31838/jcdr.2020.11.02.09.
14. Nagham Mahmood Aljamali. Synthesis and Chemical Identification of Macro Compounds of (Thiazol and Imidazol). Research J. Pharm. and Tech. 2015; 8(1): 78-84. DOI: 10.5958/0974-360X.2015.00016.5.
15. Mestaf M, Nawfel Muhammed Baqer Muhsin., NeuroQuantology, 2019.,17,11, 11-16.,10.14704/nq.2019. 17.11.NQ19108.
16. Nagham Mahmood Aljamali. Synthesis of Antifungal Chemical Compounds from Fluconazole with (Pharma-Chemical) Studying. Research journal of Pharmaceutical, biological and chemical sciences. 2017; 8 (3): 564 -573.
17. Mehta SL, Manhas N, Raghubiz R. Molecular targets in cerebral ischemia for developing novel therapeutics. Brain Res Rev. 2007; 54: 34–66.
18. Meaaed M, Nagham Mahmood Aljamali, Nadheema A A. Preparation, Spectral Investigation, Thermal Analysis, Biochemical Studying of New (Oxadiazole -Five Membered Ring)-Ligands. Journal of Global Pharmacy Technology. 2018;10(1): 20-29.
19. Nagham Mahmood Aljamali. Survey on Methods of Preparation and Cyclization of Heterocycles. International Journal of Chemical and Molecular Engineering. 2020; 6(2): 19–36.
20. Mieaad M, Wassan Ala Shubber., Sabreen Ali Abdalrahman, et.al. New Azomethine- Azo Heterocyclic Ligands Via Cyclization of Ester. Research Journal of Pharmacy and Technology. 2018; 11(6): 2555-2560., DOI: 10.5958/0974-360X. 2018. 00472.9 .
21. Hasaneen Kudhair Abdullabass, Aseel Mahmood Jawad, et.al. Synthesis of drugs derivatives as inhibitors of cancerous cells., Biochem. Cell. Arch. 2020; 20(2). DocID: https://connectjournals.com/03896.2020.20.5315.
22. Nagham Mahmood Aljamali, Intisar Obaid Alfatlawi. Synthesis of Sulfur Heterocyclic Compounds and Study of Expected Biological Activity. Research J. Pharm. and Tech. 2015; 8(9): 1225-1242. DOI: 10.5958/0974-360X.2015 .00224.3.
23. Nagham Mahmood Aljamali, Kam Alwan. Development of Trimethoprim Drug and Innovation of Sulfazane-Trimethoprim Derivatives as Anticancer Agents. Biomedical & Pharmacology Journal. 2020; 13(2): 613-625. http://dx.doi.org/10.13005/bpj/1925.
24. Hussein Ali Ahmed, Nagham Mahmood Aljamali. Preparation, Characterization, Antibacterial Study, Toxicity Study of New Phenylene diamine- Formazan Derivatives. Indian Journal of Forensic Medicine & Toxicology. 2021; 15(2).
25. Nagham Mahmood Aljamali, Hussein Mejbel Azeez. Synthesis and Characterization of Some New Formazan – Cefixime and Study of Against Breast Cancer Cells. Annals of R.S.C.B. 2021; 25(4): 8562-8578. ISSN:1583-6258.
26. Nagham Mahmood Aljamali, Asmaa, Kefah Mahdi. Synthesis, Identification and Anticancer Studying of Heterocyclic- Mefenamic Drug via Thiosemicarbazide., Annals of R.S.C.B. 2021; 25(4): 8521-8537. ISSN:1583-6258.
27. Nagham Mahmood Aljamali, Tabark Emad Al-Faham. Synthesis, Identification, Chromatographic Studying of Formazane –Phenylenediamine Derivatives., Annals of R.S.C.B., ISSN:1583-6258, Vol. 25, Issue 4, 2021.
28. Intisar Obaid Alfatlawi, Nuha S S, Zainab M J., et.al. Synthesis of New Organic Compounds Via Three Components Reaction with Studying of (Identification, Thermal Behavior, Bioactivity on Bacteria of Teeth). Journal of Global Pharma Technology. 2017;11(9): 157-164.
29. Naumann d’Alnoncourt, Raoul; Csepei, Lénárd-István; Hävecker, Michael; et.al. The reaction network in propane oxidation over phase-pure MoVTeNb M1 oxide catalysts. Journal of Catalysis. 2014;311: 369–385.
30. Nagham Mahmood Aljamali.; Saher Mahmood Jawd.; Zainab M J., et.al. Inhibition activity of (Azo–acetyl acetone) on bacteria of mouth. Research Journal of Pharmacy and Technology. 2017; 10(6):1683-1686. DOI: 10.5958/0974-360X.2017.00297.9.
31. Mokrani, Touhami; van Reenen, Albert; Amer, Ismael. Molecular weight and toxicity effect on morphological and mechanical properties of Ziegler–Natta catalyzed isotactic polypropylenes””. Polímeros. 2015; 25(6): 556–563. doi:10.1590/0104-1428.2158 . ISSN 0104-1428.
32. Dub, Pavel A.; Gordon, John C.The role of the metal-bound N–H functionality in Noyori-type molecular catalysts””. Nature Reviews Chemistry. 2018; 2(12): 396–408.
33. Nagham Mahmood Aljamali. (Synthesis, Investigation, Chromatography, Thermal)- Behavior of (Five, Seven)- Membered Ring with Azo and Anil Compounds. Pak. J. Biotechnol. 2018; 15(1): 219-239.
34. Aseel Mahmood Jawad., Nagham Mahmood Aljamali, Saher Mahmood Jawd. Development and Preparation of ciprofloxacin Drug Derivatives for Treatment of Microbial Contamination in Hospitals and Environment. Indian Journal of Forensic Medicine & Toxicology. 2020; 14(2): 1115-1122.
35. Nagham Mahmood Aljamali. Spectral and Laboratory Diagnostics of Compounds. 1st –Edition. Europe: Eliva Press SRL; 2021. ISBN: 9781636482118.
36. Shireen R. Rasool, Nagham Mahmood Aljamali, Ali Jassim Al-Zuhairi. Guanine substituted heterocyclic derivatives as bioactive compounds. Biochem. Cell. Arch. 2020; 20: 3651-3655, 2020, DocID: https://connectjournals.com/03896.2020.20.3651.
37. Pompella A, Visvikis A, Paolicchi A, et.al. The changing faces of glutathione, protagonist””. Biochemical Pharmacology. 2003; 66(8):1499–1503.doi:10.1016/S0006-2952 (03) 00504-5.
38. Wonisch W, Schaur RJ. Chapter 2: Chemistry of Glutathione””. In Grill D, Tausz T, De Kok L (eds.). Significance of glutathione in plant adaptation to the environment. Germany: Springer; 2001. ISBN 978-1-4020-0178-9 – via Google Books.
39. Aljamali D, Mahmood N, Jawad SF. Preparation, Spectral Characterization, Thermal Study, and Antifungal Assay of (Formazane-Mefenamic acid)-Derivatives. Egyptian Journal of Chemistry. 2022; 65(2): 449-457.
40. Pastore A, Piemonte F, Locatelli M, et.al. Determination of blood total, reduced, and oxidized glutathione in pediatric subjects. Clinical chemistry. 2001;47(8):1467-1470.
41. Lu SC (2013). Glutathione synthesis. Biochimica et Biophysica Acta. 2013; 1830(5): 3143–3153. doi:10.10 16/j.bbagen.2012.09.008. PMC 3549305. PMID 22995213.
42. Halprin KM, Ohkawara A. The measurement of glutathione in human epidermis using glutathione reductase””. The Journal of Investigative Dermatology. 1967; 48(2): 149–152. doi:10.1038/jid.1967.24 . PMID 6020678.
43. Couto N, Malys N, Gaskell SJ, et.al. Partition and turnover of glutathione reductase from Saccharomyces cerevisiae: a proteomic approach””. Journal of Proteome Research. 2013; 12(6): 2885–2894. doi:10.1021 /pr4001948. PMID 23631642.
44. Dringen R. Metabolism and functions of glutathione in brain””. Progress in Neurobiology. 2000; 62(6): 649–671. doi:10.1016/s0301-0082(99)00060-x. PMID 10880854.
45. Scholz, RW. Graham KS. Gumpricht E. et.al. Mechanism of interaction of vitamin E and glutathione in the protection against membrane lipid peroxidation””. Ann NY Acad Sci. 1989; 570(1): 514–517. Bibcode:1989NYASA. 570.514S. doi:10.1111/j.1749-6632.1989.tb14973.x.
46. Hughes RE. Reduction of dehydroascorbic acid by animal tissues. Nature. 1964; 203(4949): 1068–1069. Bibcode: 1964Natur.203.1068H. doi:10.1038/2031068a0. PMID 14223080.
47. Ha SB, Smith AP, Howden R, et.al. Phytochelatin synthase genes from Arabidopsis and the yeast Schizosaccharomyces pombe. The Plant Cell. 1999; 11(6): 1153–1164. doi:10.1105/tpc.11.6.1153. JSTOR 3870806 . PMC 144235. P MID 10368185.
48. Steullet P, Neijt HC, Cuénod M, et.al. Synaptic plasticity impairment and hypofunction of NMDA receptors induced by glutathione deficit: relevance to schizophrenia. Neuroscience. 2006; 137(3): 807–819. doi:10.1016/j.neuroscience.2005.10.014 . PMID 16330153.
49. Aseel Mahmood Jawad, Nagham Mahmood Aljamali. Innovation, Preparation of Cephalexin Drug Derivatives and Studying of (Toxicity & Resistance of Infection). International Journal of Psychosocial Rehabilitation. 2020; 24(4): 3754-3767.
50. Nawfel M B, Hayder H K, Noor H D, et.al. Preparation of Chemical Inhibitors to Treat the Corrosion and Erosion of Machines. International Journal of Engineering, Applied and Management Sciences Paradigms. 2019; 54(3): 89-93.
51. Maulucci G, Labate V, Mele M, et.al. High-resolution imaging of redox signaling in live cells through an oxidation-sensitive yellow fluorescent protein. ScienceSignaling. 2008; 1 (43):pl3. doi:10.1126/scisignal .143pl3.
52. M. N Abdmajed, Nagham Mahmood Aljamali., Preparation of Benzothiazole-Formazane Reagents and Studying of (Spectral, Thermal, Scanning Microscopy, Biological Evaluation)., International Journal of Pharmaceutical Research. 2021;13(1): 4290-4300.
53. Abd Ali H, Nagham Mahmood Aljamali. Chalcone-Heterocyclic Derivatives (Synthesis, Spectral Identification, Microbial Evaluation). International Journal of Pharmaceutical Research. 2021; 13(1): 4234-4242.
54. Nor A., Sad S., Nagham Mahmood Aljamali. Synthesis, Characterization and Thermal Analysis for New Amoxil Ligands. Asian Journal of Chemistry. 2019; 31(5): 1022-1026.
55. Rajaa Abdul Ameer Ghafil, Nor A Alrb, Nagham Mahmood Aljamali. Synthesis of Triazole Derivatives via Multi Components Reaction and Studying of (Organic Characterization, Chromatographic Behavior, Chem-Physical Properties). Egypt. J. Chem. 2020; 63(11):4163-4174. DOI: 10.21608/EJCHEM.2020.23541.2399.
56. Aljamali NM. Review in azo compounds and its biological activity. Biochem Anal Biochem. 2015; 4(2):1-4. doi:10.4172/2161-1009.1000169.
57. F. Jawad, Nagham Mahmood Aljamali. Preparation, Investigation and Study of Biological Applications of Tyrosine Derivatives against Breast Cancer Cells. NeuroQuantology. 2021; 19 (9): 117-125, doi: 10.14704/nq.2021.19.9.NQ21144.
58. Aljamali NM, Jawad SF. Preparation, Diagnosis and Evaluation of Cyclic-Tryptophan Derivatives as Anti Breast Cancer Agents. Biomedical and Pharmacology Journal. 2021;14(4):1983-1991. Available from: https://bit.ly/3HuvlVG.
59. Bishop C, Hudson VM, Hilton SC, et.al. A pilot study of the effect of inhaled buffered reduced glutathione on the clinical status of patients with cystic fibrosis. Chest. 2005 Jan 1;127(1):308-317. doi:10.1378/chest .127.1 .308. PMID 15653998.
60. Mandal PK, Tripathi M, Sugunan S. Brain oxidative stress: detection and mapping of anti-oxidant marker ‘Glutathione’ in different brain regions of healthy male/female, MCI and Alzheimer patients using non-invasive magnetic resonance spectroscopy. Biochemical and Biophysical Research Communications. 2012; 417(1): 43–48. doi:10.1016/j.bbrc.2011.11.047. PMID 22120629.

n[/if 1104][if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””],[/if 1106]

    2. n[/foreach]

n[/if 1104]

n

n[if 1114 equals=”Yes”]n

n[/if 1114]”},{“box”:2,”content”:”

Regular Issue Open Access Article

n

n

n

n

n

International Journal of Polymer Science & Engineering

n

[if 344 not_equal=””]ISSN: 2455-8745[/if 344]

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

Volume 7
Issue 2
Received December 9, 2021
Accepted December 27, 2021
Published December 31, 2021

n

n

Views: 1,302

n

n

Editor

n

n

n

Reviewer

n

n

n n

n”},{“box”:6,”content”:”“}]

Read More
IJPSE

Fabrication of a Novel and Efficient Radiation Grafted Functionalized Polymer Adsorbent and Investigation of its Applicability in the Adsorptive Removal of Cr (VI) Ion from Aqueous Solution

[{“box”:0,”content”:”

n

Home

n

 > 

n

ijpse

n

 > 

n

Article

n

Views: 1,310

n

n

n

n

n

By [foreach 286]u00a0

u00a0Nazia Rahman, Md Nahid Kayser, Md. Khairul Amin, Nirmal Chandra Dafader, Shahnaz Sultana, Md. Nabul Sardar, Md. Sohel Rana,

[/foreach]
nJanuary 9, 2023 at 8:53 am

n

nAbstract

n

The grafting of glycidyl methacrylate (GMA) onto non-woven polyethylene (PE) fabric was accomplished using a radiation-initiated grafting technique. The grafted textiles were allowed to react using triethylamine to create functioning amine groups. Upon bond formation yield, the impact of grafting intensity has been examined. Utilizing the appropriate technologies, such as FTIR, TGA, and SEM, the adsorbents were rigorously examined. There was evidence of GMA grafting and diamines according to FTIR, TGA, and Tem analyses. For the purpose of adsorbing clearance of Cr (VI) ions from aqueous solution, amino cluster GMA-g-non-woven PE films was drenched in HCl to promote anionic metal adsorption. Adsorption capacity was investigated through varying the adsorption parameters. Contact time changed from 1 to 26 h, pH changed from 1.2 to 6, temperature changed from 30 to 75ºC and initial metal ion concentration changed from 200 to 1000 mg/L. The optimal circumstance that can lead highest adsorption of Cr (VI) by the adsorbent was established to be contact time 24 hours and initial metal concentration 600 mg/L, pH 1.2 and temperature 75ºC. Langmuir and Freundlich isotherm model were used for the analysis of Cr (VI) adsorption process by the adsorbent to understand and explain the adsorption mechanism. The equilibrium experimental data of Cr (VI) adsorption exhibited better matching with Langmuir isotherm model proposing the formation of monolayer saturation on the adsorbent surface. The highest adsorption capacity derived from Langmuir isotherm model was 50.76 mg/g. The adsorption kinetics was inspected by means of pseudo-first order and pseudo-second-order models with the aid of a pseudo-second-order equation, the adsorption equilibrium of Cr (VI) ion could’ve been effectively constructed. The satisfactory outcome of investigation of desorption of Cr (VI) and reuse of the adsorbent film proposed the prospect of recycling of the polymer adsorbent in case of practical application.

n

n

n

n

Volume :u00a0u00a08 | Issue :u00a0u00a01 | Received :u00a0u00a0March 4, 2022 | Accepted :u00a0u00a0March 27, 2022 | Published :u00a0u00a0July 8, 2022n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)] [/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue Fabrication of a Novel and Efficient Radiation Grafted Functionalized Polymer Adsorbent and Investigation of its Applicability in the Adsorptive Removal of Cr (VI) Ion from Aqueous Solution under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]
Keywords Polyethylene, Glycidyl methacrylate, Radiation grafting, Chromium adsorption, Adsorption isotherm, Adsorption kinetics.

n

n

n

n

n

n[if 992 equals=”Transformative”]

n

n

Full Text

n

n

n

[/if 992][if 992 not_equal=”Transformative”]

n

n

Full Text

n

n

n

[/if 992] n

nn

[if 379 not_equal=””]n

[foreach 379]n

n[/foreach]

n[/if 379]

n

References

n[if 1104 equals=””]n

1. Lin SH, Juang RS. Heavy Metal Removal from Water by Sorption Using Surfactant Modified Montmorillonite. J. Hazard. Mater. 2002; 92: 315–326.
2. Hajeeth T, Sudha PN, Vijayalakshmi K. Removal of Cr (VI) from Aqueous Solution Using Graft Copolymer of Cellulose Extracted from Sisal Fibre with Acrylic Acid Monomer. Cellul. Chem. Technol. 2015: 49: 891–900.
3. Chowdhury M, Mostafa MG, Biswas,et al TK.Characterization of the Effluents from Leather Processing Industries. Environ. Process. 2015; 2: 173–187.
4. Lofrano G, Carotenuto M, Gautam RK, et al. Heavy Metals in Tannery Wastewater and Sludge: Environmental Concerns and Future Challenges. Heavy Met. Water. 2014; 12: 249–260.
5. Alam M.N., Sayid Mia MA, Ahmad F, Rahman MM. Adsorption of Chromium (Cr) from Tannery Wastewater Using Low-cost Spent Tea Leaves Adsorbent. Appl. Water Sci. 2018 8: 1–7.
6. Islam S, Islam F, Bakar MA, et al. Heavy Metals Concentration at Different Tannery Wastewater Canal of Chittagong City in Bangladesh. Int. J. Agric. Environ. Biotechnol. 2013; 6: 355.
7. Ünlü N, Ersoz M.Adsorption Characteristics of Heavy Metal Ions onto a Low Cost Biopolymeric Sorbent from Aqueous Solutions. J.Hazard.Mater. 2006; 136: 272–280.
8. Celik A, Demirbas A.Removal of Heavy Metal Ions from Aqueous Solutions via Adsorption onto Modified Lignin from Pulping Wastes. Energy Sources. 2005; 27: 1167–1177.
9. Kumar PS, Ramalingam S, Sathyaselvabala V,et al. Removal of Cadmium (II) from Aqueous Solution by Agricultural Waste Cashew Nut Shell. Korean J. Chem. Eng. 2012, 29: 756–768.
10. Krowiak AW. Application of Beech Sawdust for Removal of Heavy Metals from Water: Biosorption and Desorption Studies. Eur. J. Wood Wood Prod. 2013; 71: 227–236.
11. Cimen A, Bilgic A, Kursunlu AN, et al. Adsorptive Removal of Co (II), Ni (II), and Cu (II) Ions from Aqueous Media Using Chemically Modified Sporopollenin of Lycopodium clavatum as Novel Biosorbent. Desalin. Water Treat. 2014; 52: 4837–4847.
12. Schmuhl R, Krieg HM, Keizer K. Adsorption of Cu (II) and Cr (VI) Ions by Chitosan: Kinetics and Equilibrium Studies, Water SA. 2001; 27: 1–7.
13. Ho YS, Ng JCY, McKay G. Removal of Lead (II) from Effluents by Sorption on Peat Using Second-Order Kinetics. Sep. Sci. Technol. 2001;36: 241–261.
14. Shukla SR, Sakhardande VD. Metal Ion Removal by Dyed Cellulosic Materials, J. Appl. Polym. Sci. 1991 42: 829–835.
15. Nasef MM, Ting TM, Abbasi A, et al. Radiation Grafted Adsorbents for Newly Emerging Environmental Applications,” Radiat. Phys. Chem. 2014; 118, 55–60.
16. Yiǧitoǧlu M, Arslan M. Adsorption of Hexavalent Chromium from Aqueous Solutions Using 4-vinyl pyridine Grafted poly (ethylene terephthalate) fibers. Polym. Bull. 2005; 55: 259–268.
17. Ping X, Wang M, Ge X. Radiation Induced Graft Copolymerization of n-butyl acrylate onto Poly(ethylene terephthalate) (PET) Films and Thermal Properties of the Obtained Graft Copolymer. Radiat. Phys. Chem. 2011; 80: 632–637.
18. Deng S, Bai R. Removal of Trivalent and Hexavalent Chromium with Aminated Polyacrylonitrile Fibers: Performance and Mechanisms. Water Res. 2004; 38: 2424–2432.
19. Kim S, Lee TG. Removal of Cr (VI) from Aqueous Solution Using Functionalized poly(GMA-co-EGDMA)-graft-poly (allylamine), React. Funct. Polym. 2019; 134:133–140.
20. Coşkun R, Soykan C, Saçak M. Adsorption of Copper (II), Nickel (II) and Cobalt (II) Ions from aqueous Solution by Methacrylic acid/Acrylamide Monomer Mixture Grafted poly(ethylene terephthalate) Fiber. Sep. Purif. Technol. 2006; 49: 107–114.
21. Yiǧitoǧlu M, Arslan M. Selective Removal of Cr (VI) Ions from Aqueous Solutions Including Cr (VI), Cu (II) and Cd (II) Ions by 4-vinly pyridine/2-hydroxyethylmethacrylate Monomer Mixture Grafted poly(ethylene terephthalate) Fiber. J. Hazard. Mater. 2009; 166: 435–444.
22. Karakişla M. The Adsorption of Cu (II) Ion from Aqueous Solution upon Acrylic acid Grafted poly(ethylene terephthalate) Fibers. J. Appl. Polym. Sci. 2002; 87: 1216–1220.
23. Arslan M. Preparation and Use of Amine-functionalized Glycidyl methacrylate-g-poly(ethylene terephthalate) Fibers for Removal of Chromium (VI) from Aqueous Solution. Fibers Polym. 2010; 11: 325–330.
24. Abdel-Bary EM, Sarhan AA, Abdel-Razik HH. Effect of Graft Copolymerization of 2-hydroxyethyl methacrylate on the Properties of Polyester Fibres and Fabric. J. Appl. Polym. Sci. 1988; 35: 439–448.
25. Nasef MM.Gamma Radiation-induced Graft Copolymerization of Styrene onto poly (ethylene terephthalate) Films. J. Appl. Polym. Sci. 2000; 77: 1003–1012.
26. Rahman N, Hossen MS, Miah AR, et al. Removal of Cu (II), Pb (II) and Cr (VI) ions from aqueous solution using amidoximated non-woven polyethylene-g-acrylonitrile fabric, J Environ Health Sci Eng 2019; 17: 183–194.
27. Hegazy EA., Kamal H, Maziad N, et al. Membranes prepared by radiation grafting of binary monomers for adsorption of heavy metals from industrial wastes. Nucl Instrum Meth B. 1999; 151: 386–392.
28. Hegazy EA., Kamal H, Khalifa NA, et al. Separation and extraction of some heavy and toxic metal ions from their wastes by grafted membranes. J Appl Polym Sci 2001; 81: 849–860.
29. Hegazy EA, Abd El-Rehim HA, Ali AMI, et al. Characterization and application of radiation grafted membranes in treatment of intermediate active waste. Nucl Instrum Meth B 1999; 151: 393–398.
30. Abd El-Rehim HA., Hegazy EA., Ali AE. Selective removal of some heavy metal ions from aqueous solution using treated polyethylene-g-styrene/maleic anhydride membranes. React Funct Polym 2000; 43: 105–116.
31. Choi SH, Nho YC, Kim GT. Adsorption of Pb2+ and Pd2+ on polyethylene membrane with amino group modified by radiation-induced graft copolymerization. J. Appl. Polym. Sci. 1999; 7: 643–650. 32. Namasivayam C, Arası DJSE. Removal of Congo Red from Wastewater by Adsorption onto Waste Red Mud. Chemosphere. 1997; 34: 401–417.
33. Ho YS. Review of Second-order Models for Adsorption Systems. J. Hazard. Mater. 2006; 136: 681–689.
34. Langmuir I. The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum. Chem. Soc. 1998; 40, 1361–1403.
35. Freundlich HMF. Over the Adsorption in Solution. J. Phys.Chem. 1906; 57: 385–471.
36. Yaday SK, Dixit AK. Efficient Removal of Cr (VI) from Aqueous Solution onto Palm Trunk Charcoal: Kinetic and Equilibrium Studies. Chem Sci J, 2016; 7:1-7.
37. Hu XZ. Adsorption of Chromium (VI) by Ethylenediamine Modified Cross-linked Magnetic Chitosan Resin: Isotherms, Kinetics and Thermodynamics. J. Hazard. Mater. 2011; 185: 306–314.
38. Gode F, Atalay ED, Pehlivan E. Removal of Cr (VI) from Aqueous Solution Using Modified Red Pine Sawdust. J. Hazard. Mater, 2008; 152: 1201–1207.
39. Kumar ASK, Kumar CU, Rajesh V, et al. Microwavw Assisted Preparation of N-butyl Acrylate Grafted Chitosan and Its Application for Cr (VI) Adsorption, Int. J. Biol. Macromol, 2014; 66: 135–143.
40. Wu Y, Ming Z, Yang S, et al. Adsorption of Hexavalet Chromium onto Bamboo Charcoal grafted by Cu2+-N-aminopropylsilane Complexes: Optimization, Kinetic and Isotherm Studies. J. Indust. Eng. Chem. 2017;46: 222–233.
41. Sharma G, Naushad M, Al-Muhtaseb AH, et al. Fabrication and Charactyerization of Chitosan-crosslinked-poly (alginiacid) Nanohydrogel for Adsorptive Removal of Cr (VI) Metal Ion from Aqueous Medium. Int. J. Biol. Macromol. 2017; 95: 484–493.

nn[/if 1104] [if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””], [/if 1106]

    2. n[/foreach]

n[/if 1104]

n[if 1114 equals=”Yes”]n

n[/if 1114]

n

n

[if 424 not_equal=”Regular Issue”] Regular Issue[/if 424] Open Access Article

n

International Journal of Polymer Science & Engineering

ISSN: 2455-8745

Editors Overview

ijpse maintains an Editorial Board of practicing researchers from around the world, to ensure manuscripts are handled by editors who are experts in the field of study.

n

“},{“box”:4,”content”:”

n“},{“box”:1,”content”:”

    By  [foreach 286]n

  1. n

    Nazia Rahman, Md Nahid Kayser, Md. Khairul Amin, Nirmal Chandra Dafader, Shahnaz Sultana, Md. Nabul Sardar, Md. Sohel Rana

    n

    2. [/foreach]

n

    [foreach 286] [if 1175 not_equal=””]n t

  1. Principal Scientific Officer, Student, Assistant Professor, Chief Scientific Officer, Senior Scientific Officer, Scientific Officer, Student,Institute of Nuclear Science and Technology, Khulna University, Khulna University, Institute of Nuclear Science and Technology, Institute of Nuclear Science and Technology, Institute of Nuclear Science and Technology, University of Dhaka,Dhaka, Dhaka, Dhaka, Dhaka, Dhaka,Bangladesh, Bangladesh, Bangladesh, Bangladesh, Bangladesh, Bangladesh, Bangladesh

    2. n[/if 1175][/foreach]

n

n

n

n

n

Abstract

nThe grafting of glycidyl methacrylate (GMA) onto non-woven polyethylene (PE) fabric was accomplished using a radiation-initiated grafting technique. The grafted textiles were allowed to react using triethylamine to create functioning amine groups. Upon bond formation yield, the impact of grafting intensity has been examined. Utilizing the appropriate technologies, such as FTIR, TGA, and SEM, the adsorbents were rigorously examined. There was evidence of GMA grafting and diamines according to FTIR, TGA, and Tem analyses. For the purpose of adsorbing clearance of Cr (VI) ions from aqueous solution, amino cluster GMA-g-non-woven PE films was drenched in HCl to promote anionic metal adsorption. Adsorption capacity was investigated through varying the adsorption parameters. Contact time changed from 1 to 26 h, pH changed from 1.2 to 6, temperature changed from 30 to 75ºC and initial metal ion concentration changed from 200 to 1000 mg/L. The optimal circumstance that can lead highest adsorption of Cr (VI) by the adsorbent was established to be contact time 24 hours and initial metal concentration 600 mg/L, pH 1.2 and temperature 75ºC. Langmuir and Freundlich isotherm model were used for the analysis of Cr (VI) adsorption process by the adsorbent to understand and explain the adsorption mechanism. The equilibrium experimental data of Cr (VI) adsorption exhibited better matching with Langmuir isotherm model proposing the formation of monolayer saturation on the adsorbent surface. The highest adsorption capacity derived from Langmuir isotherm model was 50.76 mg/g. The adsorption kinetics was inspected by means of pseudo-first order and pseudo-second-order models with the aid of a pseudo-second-order equation, the adsorption equilibrium of Cr (VI) ion could’ve been effectively constructed. The satisfactory outcome of investigation of desorption of Cr (VI) and reuse of the adsorbent film proposed the prospect of recycling of the polymer adsorbent in case of practical application.n

n

n

Keywords: Polyethylene, Glycidyl methacrylate, Radiation grafting, Chromium adsorption, Adsorption isotherm, Adsorption kinetics.

n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)]

n[/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]

n

n

n

n[if 992 equals=”Transformative”]n

n

n

Full Text

n

n

nn[/if 992]n[if 992 not_equal=”Transformative”]n

n

Full Text

n

n

n

n

[/if 992]n[if 379 not_equal=””]

Browse Figures

n

n

[foreach 379]n

n[/foreach]

n

[/if 379]n

n

References

n[if 1104 equals=””]

1. Lin SH, Juang RS. Heavy Metal Removal from Water by Sorption Using Surfactant Modified Montmorillonite. J. Hazard. Mater. 2002; 92: 315–326.
2. Hajeeth T, Sudha PN, Vijayalakshmi K. Removal of Cr (VI) from Aqueous Solution Using Graft Copolymer of Cellulose Extracted from Sisal Fibre with Acrylic Acid Monomer. Cellul. Chem. Technol. 2015: 49: 891–900.
3. Chowdhury M, Mostafa MG, Biswas,et al TK.Characterization of the Effluents from Leather Processing Industries. Environ. Process. 2015; 2: 173–187.
4. Lofrano G, Carotenuto M, Gautam RK, et al. Heavy Metals in Tannery Wastewater and Sludge: Environmental Concerns and Future Challenges. Heavy Met. Water. 2014; 12: 249–260.
5. Alam M.N., Sayid Mia MA, Ahmad F, Rahman MM. Adsorption of Chromium (Cr) from Tannery Wastewater Using Low-cost Spent Tea Leaves Adsorbent. Appl. Water Sci. 2018 8: 1–7.
6. Islam S, Islam F, Bakar MA, et al. Heavy Metals Concentration at Different Tannery Wastewater Canal of Chittagong City in Bangladesh. Int. J. Agric. Environ. Biotechnol. 2013; 6: 355.
7. Ünlü N, Ersoz M.Adsorption Characteristics of Heavy Metal Ions onto a Low Cost Biopolymeric Sorbent from Aqueous Solutions. J.Hazard.Mater. 2006; 136: 272–280.
8. Celik A, Demirbas A.Removal of Heavy Metal Ions from Aqueous Solutions via Adsorption onto Modified Lignin from Pulping Wastes. Energy Sources. 2005; 27: 1167–1177.
9. Kumar PS, Ramalingam S, Sathyaselvabala V,et al. Removal of Cadmium (II) from Aqueous Solution by Agricultural Waste Cashew Nut Shell. Korean J. Chem. Eng. 2012, 29: 756–768.
10. Krowiak AW. Application of Beech Sawdust for Removal of Heavy Metals from Water: Biosorption and Desorption Studies. Eur. J. Wood Wood Prod. 2013; 71: 227–236.
11. Cimen A, Bilgic A, Kursunlu AN, et al. Adsorptive Removal of Co (II), Ni (II), and Cu (II) Ions from Aqueous Media Using Chemically Modified Sporopollenin of Lycopodium clavatum as Novel Biosorbent. Desalin. Water Treat. 2014; 52: 4837–4847.
12. Schmuhl R, Krieg HM, Keizer K. Adsorption of Cu (II) and Cr (VI) Ions by Chitosan: Kinetics and Equilibrium Studies, Water SA. 2001; 27: 1–7.
13. Ho YS, Ng JCY, McKay G. Removal of Lead (II) from Effluents by Sorption on Peat Using Second-Order Kinetics. Sep. Sci. Technol. 2001;36: 241–261.
14. Shukla SR, Sakhardande VD. Metal Ion Removal by Dyed Cellulosic Materials, J. Appl. Polym. Sci. 1991 42: 829–835.
15. Nasef MM, Ting TM, Abbasi A, et al. Radiation Grafted Adsorbents for Newly Emerging Environmental Applications,” Radiat. Phys. Chem. 2014; 118, 55–60.
16. Yiǧitoǧlu M, Arslan M. Adsorption of Hexavalent Chromium from Aqueous Solutions Using 4-vinyl pyridine Grafted poly (ethylene terephthalate) fibers. Polym. Bull. 2005; 55: 259–268.
17. Ping X, Wang M, Ge X. Radiation Induced Graft Copolymerization of n-butyl acrylate onto Poly(ethylene terephthalate) (PET) Films and Thermal Properties of the Obtained Graft Copolymer. Radiat. Phys. Chem. 2011; 80: 632–637.
18. Deng S, Bai R. Removal of Trivalent and Hexavalent Chromium with Aminated Polyacrylonitrile Fibers: Performance and Mechanisms. Water Res. 2004; 38: 2424–2432.
19. Kim S, Lee TG. Removal of Cr (VI) from Aqueous Solution Using Functionalized poly(GMA-co-EGDMA)-graft-poly (allylamine), React. Funct. Polym. 2019; 134:133–140.
20. Coşkun R, Soykan C, Saçak M. Adsorption of Copper (II), Nickel (II) and Cobalt (II) Ions from aqueous Solution by Methacrylic acid/Acrylamide Monomer Mixture Grafted poly(ethylene terephthalate) Fiber. Sep. Purif. Technol. 2006; 49: 107–114.
21. Yiǧitoǧlu M, Arslan M. Selective Removal of Cr (VI) Ions from Aqueous Solutions Including Cr (VI), Cu (II) and Cd (II) Ions by 4-vinly pyridine/2-hydroxyethylmethacrylate Monomer Mixture Grafted poly(ethylene terephthalate) Fiber. J. Hazard. Mater. 2009; 166: 435–444.
22. Karakişla M. The Adsorption of Cu (II) Ion from Aqueous Solution upon Acrylic acid Grafted poly(ethylene terephthalate) Fibers. J. Appl. Polym. Sci. 2002; 87: 1216–1220.
23. Arslan M. Preparation and Use of Amine-functionalized Glycidyl methacrylate-g-poly(ethylene terephthalate) Fibers for Removal of Chromium (VI) from Aqueous Solution. Fibers Polym. 2010; 11: 325–330.
24. Abdel-Bary EM, Sarhan AA, Abdel-Razik HH. Effect of Graft Copolymerization of 2-hydroxyethyl methacrylate on the Properties of Polyester Fibres and Fabric. J. Appl. Polym. Sci. 1988; 35: 439–448.
25. Nasef MM.Gamma Radiation-induced Graft Copolymerization of Styrene onto poly (ethylene terephthalate) Films. J. Appl. Polym. Sci. 2000; 77: 1003–1012.
26. Rahman N, Hossen MS, Miah AR, et al. Removal of Cu (II), Pb (II) and Cr (VI) ions from aqueous solution using amidoximated non-woven polyethylene-g-acrylonitrile fabric, J Environ Health Sci Eng 2019; 17: 183–194.
27. Hegazy EA., Kamal H, Maziad N, et al. Membranes prepared by radiation grafting of binary monomers for adsorption of heavy metals from industrial wastes. Nucl Instrum Meth B. 1999; 151: 386–392.
28. Hegazy EA., Kamal H, Khalifa NA, et al. Separation and extraction of some heavy and toxic metal ions from their wastes by grafted membranes. J Appl Polym Sci 2001; 81: 849–860.
29. Hegazy EA, Abd El-Rehim HA, Ali AMI, et al. Characterization and application of radiation grafted membranes in treatment of intermediate active waste. Nucl Instrum Meth B 1999; 151: 393–398.
30. Abd El-Rehim HA., Hegazy EA., Ali AE. Selective removal of some heavy metal ions from aqueous solution using treated polyethylene-g-styrene/maleic anhydride membranes. React Funct Polym 2000; 43: 105–116.
31. Choi SH, Nho YC, Kim GT. Adsorption of Pb2+ and Pd2+ on polyethylene membrane with amino group modified by radiation-induced graft copolymerization. J. Appl. Polym. Sci. 1999; 7: 643–650. 32. Namasivayam C, Arası DJSE. Removal of Congo Red from Wastewater by Adsorption onto Waste Red Mud. Chemosphere. 1997; 34: 401–417.
33. Ho YS. Review of Second-order Models for Adsorption Systems. J. Hazard. Mater. 2006; 136: 681–689.
34. Langmuir I. The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum. Chem. Soc. 1998; 40, 1361–1403.
35. Freundlich HMF. Over the Adsorption in Solution. J. Phys.Chem. 1906; 57: 385–471.
36. Yaday SK, Dixit AK. Efficient Removal of Cr (VI) from Aqueous Solution onto Palm Trunk Charcoal: Kinetic and Equilibrium Studies. Chem Sci J, 2016; 7:1-7.
37. Hu XZ. Adsorption of Chromium (VI) by Ethylenediamine Modified Cross-linked Magnetic Chitosan Resin: Isotherms, Kinetics and Thermodynamics. J. Hazard. Mater. 2011; 185: 306–314.
38. Gode F, Atalay ED, Pehlivan E. Removal of Cr (VI) from Aqueous Solution Using Modified Red Pine Sawdust. J. Hazard. Mater, 2008; 152: 1201–1207.
39. Kumar ASK, Kumar CU, Rajesh V, et al. Microwavw Assisted Preparation of N-butyl Acrylate Grafted Chitosan and Its Application for Cr (VI) Adsorption, Int. J. Biol. Macromol, 2014; 66: 135–143.
40. Wu Y, Ming Z, Yang S, et al. Adsorption of Hexavalet Chromium onto Bamboo Charcoal grafted by Cu2+-N-aminopropylsilane Complexes: Optimization, Kinetic and Isotherm Studies. J. Indust. Eng. Chem. 2017;46: 222–233.
41. Sharma G, Naushad M, Al-Muhtaseb AH, et al. Fabrication and Charactyerization of Chitosan-crosslinked-poly (alginiacid) Nanohydrogel for Adsorptive Removal of Cr (VI) Metal Ion from Aqueous Medium. Int. J. Biol. Macromol. 2017; 95: 484–493.

n[/if 1104][if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””],[/if 1106]

    2. n[/foreach]

n[/if 1104]

n

n[if 1114 equals=”Yes”]n

n[/if 1114]”},{“box”:2,”content”:”

Regular Issue Open Access Article

n

n

n

n

n

International Journal of Polymer Science & Engineering

n

[if 344 not_equal=””]ISSN: 2455-8745[/if 344]

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

Volume 8
Issue 1
Received March 4, 2022
Accepted March 27, 2022
Published July 8, 2022

n

n

Views: 1,310

n

n

Editor

n

n

n

Reviewer

n

n

n n

n”},{“box”:6,”content”:”“}]

Read More
IJPSE

Study of Heavy Metal ion Adsorption from Synthetic Wastewater with the Help of Biomass and Analysis of Mathematical Model

[{“box”:0,”content”:”

n

Home

n

 > 

n

ijpse

n

 > 

n

Article

n

Views: 1,269

n

n

n

n

n

By [foreach 286]u00a0

u00a0Rishabh Mudgal, Megha Gupta, Govind Madhav,

[/foreach]
nJanuary 9, 2023 at 10:16 am

n

nAbstract

n

The biofilm matrix is a mixture of secreted polymers, metabolites and nutrients ingested, lysis solution products, and even particle debris. This matrix, which is polyanionic by nature, is essential for the activated carbon of metal cations. In this study, the heavy metal adsorption mechanism in biofilms is modelled in one spatial dimension. The numerical method is a free-boundary value issue for nonlinear parabolic and quadratic partial differential equations. Parabolic equations control the evolution of the substrate, while hyperbolic equations control the growth of cellulose and exogenous polymeric substances (EPS). Every equation is related to every other equation. The model is allencompassing and may be used to a wide range of microbe populations, EPS, and substrates. In numerical analysis, the spatial rivalry between heterotrophic and autotrophic organisms using oxygen as a common substrate is considered. The model can replicate the transport and adsorption of heavy metals into biofilms as well as the distribution pattern of microbial species and substrate concentrations. It can also represent the dynamics of biofilm development. Using the approach of characteristics, numerical simulations are created for typical cases. Results show that the model can capture the key aspects of the heavy metal adsorption system on EPS. The biosorption procedure considers several process variables, including concentration, contact duration, ionic strength, energy, pores, pore volume, available sites, velocity, and factors related to activity, diffusion, and dispersion. In this review article, we outline the main physical and chemical mechanisms in the adsorbents of heavy metals on numerous types of widely used biosorbents. The most popular dynamic and steady state mathematical models for bioremediation in group and resolved columns are compiled here. Coupled nonlinear partial differential equations are produced because of the mathematical modelling of dynamic process models. It is recommended to use approximate approaches to research the sensitive analysis of key parameters.

n

n

n

n

Volume :u00a0u00a08 | Issue :u00a0u00a01 | Received :u00a0u00a0July 21, 2022 | Accepted :u00a0u00a0July 23, 2022 | Published :u00a0u00a0August 3, 2022n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)] [/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue Study of Heavy Metal ion Adsorption from Synthetic Wastewater with the Help of Biomass and Analysis of Mathematical Model under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]
Keywords Heavy metal Ion, adsorption, wastewater, mathematical model

n

n

n

n

n

n[if 992 equals=”Transformative”]

n

n

Full Text

n

n

n

[/if 992][if 992 not_equal=”Transformative”]

n

n

Full Text

n

n

n

[/if 992] n

nn

[if 379 not_equal=””]n

[foreach 379]n

n[/foreach]

n[/if 379]

n

References

n[if 1104 equals=””]n

1. Alomá, I., Martín-Lara, M., Rodríguez, I., Blázquez, G. and Calero, M. Removal of nickel (II) ions from aqueous solutions by biosorption on sugarcane bagasse. Journal of the Taiwan Institute of Chemical Engineers. 2012; 43(2).pp.275-281.
2. Safa, Y., Bhatti, H., Bhatti, I. Asgher, M. Removal of direct Red-31 and direct Orange-26 by low cost rice husk: Influence of immobilisation and pretreatments. The Canadian Journal of Chemical Engineering.2011;89(6).1554-1565.
3. Mondal D, Nandi B, Purkait M. Removal of mercury (II) from aqueous solution using bamboo leaf powder: Equilibrium, thermodynamic and kinetic studies. Journal of Environmental Chemical Engineering. 2013;1(4):891-898.
4. Roy A, Adhikari B, Majumder S. Equilibrium, Kinetic, and Thermodynamic Studies of Azo Dye Adsorption from Aqueous Solution by Chemically Modified Lignocellulosic Jute Fiber. Industrial & Engineering Chemistry Research. 2013;52(19):6502-6512.
5. Sobhanardakani S, Parvizimosaed H, Olyaie E. Heavy metals removal from wastewaters using organic solid waste—rice husk. Environmental Science and Pollution Research. 2013;20(8):5265-5271.
6. Saha R, Mukherjee K, Saha I, Ghosh A, Ghosh S, Saha B. Removal of hexavalent chromium from water by adsorption on mosambi (Citrus limetta) peel. Research on Chemical Intermediates. 2012;39(5):2245-2257.
7. Hossain M, Ngo H, Guo W, Nguyen T, Vigneswaran S. Performance of cabbage and cauliflower wastes for heavy metals removal. Desalination and Water Treatment. 2013;52(4-6):844-860.
8. Ben-Ali S, Jaouali I, Souissi-Najar S, Ouederni A. Characterization and adsorption capacity of raw pomegranate peel biosorbent for copper removal. Journal of Cleaner Production. 2017;142:3809-3821.
9. Alencar W, Acayanka E, Lima E, Royer B, de Souza F, Lameira J et al. Application of Mangifera indica (mango) seeds as a biosorbent for removal of Victazol Orange 3R dye from aqueous solution and study of the biosorption mechanism. Chemical Engineering Journal. 2012;209:577-588.
10. Hameed B, Ahmad A. Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass. Journal of Hazardous Materials. 2009;164(2-3):870-875.
11. Hameed B. Grass waste: A novel sorbent for the removal of basic dye from aqueous solution. Journal of Hazardous Materials. 2009;166(1):233-238.
12. Hameed B. Removal of cationic dye from aqueous solution using jackfruit peel as non-conventional low-cost adsorbent. Journal of Hazardous Materials. 2009;162(1):344-350.
13. Hameed B. Spent tea leaves: A new non-conventional and low-cost adsorbent for removal of basic dye from aqueous solutions. Journal of Hazardous Materials. 2009;161(2-3):753-759.
14. Dhir, B., Kumar, R. (2010). ‘Adsorption of Heavy Metals by Salvinia Biomass and Agricultural Residues’, International Journal of Environmental Research, 4(3), pp. 427-432. doi: 10.22059/ijer.2010.61.
15. Asgher M, Bhatti H. Removal of reactive blue 19 and reactive blue 49 textile dyes by citrus waste biomass from aqueous solution: Equilibrium and kinetic study. The Canadian Journal of Chemical Engineering. 2011;90(2):412-419.

nn[/if 1104] [if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””], [/if 1106]

    2. n[/foreach]

n[/if 1104]

n[if 1114 equals=”Yes”]n

n[/if 1114]

n

n

[if 424 not_equal=”Regular Issue”] Regular Issue[/if 424] Open Access Article

n

International Journal of Polymer Science & Engineering

ISSN: 2455-8745

Editors Overview

ijpse maintains an Editorial Board of practicing researchers from around the world, to ensure manuscripts are handled by editors who are experts in the field of study.

n

“},{“box”:4,”content”:”

n“},{“box”:1,”content”:”

    By  [foreach 286]n

  1. n

    Rishabh Mudgal, Megha Gupta, Govind Madhav

    n

    2. [/foreach]

n

    [foreach 286] [if 1175 not_equal=””]n t

  1. Student, Student, Student,University School of Chemical Tech. Guru Gobind Singh Indraprastha University, University School of Chemical Tech. Guru Gobind Singh Indraprastha University, University School of Chemical Tech. Guru Gobind Singh Indraprastha University,Delhi, Delhi, Delhi,India, India, India

    2. n[/if 1175][/foreach]

n

n

n

n

n

Abstract

nThe biofilm matrix is a mixture of secreted polymers, metabolites and nutrients ingested, lysis solution products, and even particle debris. This matrix, which is polyanionic by nature, is essential for the activated carbon of metal cations. In this study, the heavy metal adsorption mechanism in biofilms is modelled in one spatial dimension. The numerical method is a free-boundary value issue for nonlinear parabolic and quadratic partial differential equations. Parabolic equations control the evolution of the substrate, while hyperbolic equations control the growth of cellulose and exogenous polymeric substances (EPS). Every equation is related to every other equation. The model is allencompassing and may be used to a wide range of microbe populations, EPS, and substrates. In numerical analysis, the spatial rivalry between heterotrophic and autotrophic organisms using oxygen as a common substrate is considered. The model can replicate the transport and adsorption of heavy metals into biofilms as well as the distribution pattern of microbial species and substrate concentrations. It can also represent the dynamics of biofilm development. Using the approach of characteristics, numerical simulations are created for typical cases. Results show that the model can capture the key aspects of the heavy metal adsorption system on EPS. The biosorption procedure considers several process variables, including concentration, contact duration, ionic strength, energy, pores, pore volume, available sites, velocity, and factors related to activity, diffusion, and dispersion. In this review article, we outline the main physical and chemical mechanisms in the adsorbents of heavy metals on numerous types of widely used biosorbents. The most popular dynamic and steady state mathematical models for bioremediation in group and resolved columns are compiled here. Coupled nonlinear partial differential equations are produced because of the mathematical modelling of dynamic process models. It is recommended to use approximate approaches to research the sensitive analysis of key parameters.n

n

n

Keywords: Heavy metal Ion, adsorption, wastewater, mathematical model

n[if 424 equals=”Regular Issue”][This article belongs to International Journal of Polymer Science & Engineering(ijpse)]

n[/if 424][if 424 equals=”Special Issue”][This article belongs to Special Issue under section in International Journal of Polymer Science & Engineering(ijpse)] [/if 424]

n

n

n

n[if 992 equals=”Transformative”]n

n

n

Full Text

n

n

nn[/if 992]n[if 992 not_equal=”Transformative”]n

n

Full Text

n

n

n

n

[/if 992]n[if 379 not_equal=””]

Browse Figures

n

n

[foreach 379]n

n[/foreach]

n

[/if 379]n

n

References

n[if 1104 equals=””]

1. Alomá, I., Martín-Lara, M., Rodríguez, I., Blázquez, G. and Calero, M. Removal of nickel (II) ions from aqueous solutions by biosorption on sugarcane bagasse. Journal of the Taiwan Institute of Chemical Engineers. 2012; 43(2).pp.275-281.
2. Safa, Y., Bhatti, H., Bhatti, I. Asgher, M. Removal of direct Red-31 and direct Orange-26 by low cost rice husk: Influence of immobilisation and pretreatments. The Canadian Journal of Chemical Engineering.2011;89(6).1554-1565.
3. Mondal D, Nandi B, Purkait M. Removal of mercury (II) from aqueous solution using bamboo leaf powder: Equilibrium, thermodynamic and kinetic studies. Journal of Environmental Chemical Engineering. 2013;1(4):891-898.
4. Roy A, Adhikari B, Majumder S. Equilibrium, Kinetic, and Thermodynamic Studies of Azo Dye Adsorption from Aqueous Solution by Chemically Modified Lignocellulosic Jute Fiber. Industrial & Engineering Chemistry Research. 2013;52(19):6502-6512.
5. Sobhanardakani S, Parvizimosaed H, Olyaie E. Heavy metals removal from wastewaters using organic solid waste—rice husk. Environmental Science and Pollution Research. 2013;20(8):5265-5271.
6. Saha R, Mukherjee K, Saha I, Ghosh A, Ghosh S, Saha B. Removal of hexavalent chromium from water by adsorption on mosambi (Citrus limetta) peel. Research on Chemical Intermediates. 2012;39(5):2245-2257.
7. Hossain M, Ngo H, Guo W, Nguyen T, Vigneswaran S. Performance of cabbage and cauliflower wastes for heavy metals removal. Desalination and Water Treatment. 2013;52(4-6):844-860.
8. Ben-Ali S, Jaouali I, Souissi-Najar S, Ouederni A. Characterization and adsorption capacity of raw pomegranate peel biosorbent for copper removal. Journal of Cleaner Production. 2017;142:3809-3821.
9. Alencar W, Acayanka E, Lima E, Royer B, de Souza F, Lameira J et al. Application of Mangifera indica (mango) seeds as a biosorbent for removal of Victazol Orange 3R dye from aqueous solution and study of the biosorption mechanism. Chemical Engineering Journal. 2012;209:577-588.
10. Hameed B, Ahmad A. Batch adsorption of methylene blue from aqueous solution by garlic peel, an agricultural waste biomass. Journal of Hazardous Materials. 2009;164(2-3):870-875.
11. Hameed B. Grass waste: A novel sorbent for the removal of basic dye from aqueous solution. Journal of Hazardous Materials. 2009;166(1):233-238.
12. Hameed B. Removal of cationic dye from aqueous solution using jackfruit peel as non-conventional low-cost adsorbent. Journal of Hazardous Materials. 2009;162(1):344-350.
13. Hameed B. Spent tea leaves: A new non-conventional and low-cost adsorbent for removal of basic dye from aqueous solutions. Journal of Hazardous Materials. 2009;161(2-3):753-759.
14. Dhir, B., Kumar, R. (2010). ‘Adsorption of Heavy Metals by Salvinia Biomass and Agricultural Residues’, International Journal of Environmental Research, 4(3), pp. 427-432. doi: 10.22059/ijer.2010.61.
15. Asgher M, Bhatti H. Removal of reactive blue 19 and reactive blue 49 textile dyes by citrus waste biomass from aqueous solution: Equilibrium and kinetic study. The Canadian Journal of Chemical Engineering. 2011;90(2):412-419.

n[/if 1104][if 1104 not_equal=””]n

    [foreach 1102]n t

  1. [if 1106 equals=””], [/if 1106][if 1106 not_equal=””],[/if 1106]

    2. n[/foreach]

n[/if 1104]

n

n[if 1114 equals=”Yes”]n

n[/if 1114]”},{“box”:2,”content”:”

Regular Issue Open Access Article

n

n

n

n

n

International Journal of Polymer Science & Engineering

n

[if 344 not_equal=””]ISSN: 2455-8745[/if 344]

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

n

Volume 8
Issue 1
Received July 21, 2022
Accepted July 23, 2022
Published August 3, 2022

n

n

Views: 1,269

n

n

Editor

n

n

n

Reviewer

n

n

n n

n”},{“box”:6,”content”:”“}]

Read More
IJPSE

Fabrication of Gas Sensors Using Biopolymer Composites

[{“box”:0,”content”:”

n

n

International Journal of Polymer Science & Engineering

ISSN: 2455-8745

Editors Overview

ijpse maintains an Editorial Board of practicing researchers from around the world, to ensure manuscripts are handled by editors who are experts in the field of study.

n

n

n

n

n

n

Open Access

n

Special Issue

n

Topic

n

n Fabrication of Gas Sensors Using Biopolymer Compositesn

n

Abstract Submission Deadline : November 30, 2023

n

Manuscript Submission Deadline : December 25, 2023

n [if 457 equals=”Special Issue”]

[This article belongs to Special Issue Fabrication of Gas Sensors Using Biopolymer Composites under section ijpse in International Journal of Polymer Science & Engineering(ijpse)] [/if 457]n

n Special Issue Descriptionn

Biopolymers are very promising materials for very sensitive and selective gas and vapor sensors because of their abundance, biocompatibility, and special characteristics. For the development of electrical noses (e-noses) for a variety of applications in industrial, environmental monitoring, illness monitoring, defense, and public safety, new research initiatives are focusing on the creation of highly selective biopolymer composite receptors and new transducer platforms. Gas sensors with biopolymer films, self-assembled monolayers of biopolymers, carbon nanoparticle-doped biopolymer films, biopolymers hybridized with conducting organic polymers, as well as carbon nanotubes modified with biopolymers, have all been developed and tested in recent years for a variety of gasses and vapors. Biopolymer-based sensors are challenging conventional inorganic and organic sensors because they have reasonable sensitivity, selectivity, response time, and reversibility.

n [if 233 not_equal=””]Editor [foreach 234]n

,

n [/foreach][/if 233]n Keywordsn

Biopolymers, Nanotubes , Reversibility , Polymer molecule , Proteoglycans, Polysaccharides, Nucleic acids, Collagen

n Manuscript Submission informationn

Manuscripts should be submitted online via the manuscript Engine. Once you register on APID, click here to go to the submission form. Manuscripts can be submitted until the deadline.n All submissions that pass pre-check are peer-reviewed. Accepted papers will be published continuously in the journal (as soon as accepted) and will be listed together on the special issue website. Research articles, review articles as well as short communications are invited. For planned papers, a title and short abstract (about 100 words) can be sent to the email address:[email protected] for announcement on this website.n Submitted manuscripts should not have been published previously, nor be under consideration for publication elsewhere (except conference proceedings papers). All manuscripts are thoroughly refereed through a Double-blind peer-review process. A guide for authors and other relevant information for the submission of manuscripts is available on the Instructions for Authors page.

n Participating journals:n

n

[foreach 176] n 2455-8745n [/foreach]

n

n

Journal Name

nInternational Journal of Polymer Science & Engineeringn

n

n

Abbrivation

n ijpsen

n

n

ISSN

n

n 2455-8745

n

n

Since

n

2015

n

n

APC

950u00a0 $

n

nn

n

n

n[if 259 not_equal=””]

Published articles

View Published Paper[/if 259]n

n

n

n

n

n