This is an unedited manuscript accepted for publication and provided as an Article in Press for early access at the author’s request. The article will undergo copyediting, typesetting, and galley proof review before final publication. Please be aware that errors may be identified during production that could affect the content. All legal disclaimers of the journal apply.
Patlola Chandra Sekhar,
T. Malyadri,
B. Satyanarayana,
- Student, Department of Mechanical Engineering, VNR Vignana Jyothi Institute of Engineering and Technology, Hyderabad, Telangana, India
- Assistant Professor, Department of Mechanical Engineering, VNR Vignana Jyothi Institute of Engineering and Technology, Hyderabad, Telangana, India
- Professor, Department of Mechanical Engineering, VNR Vignana Jyothi Institute of Engineering and Technology, Hyderabad, Telangana, India
Abstract
Bio-based polymer composites are becoming more popular due to the growing need for sustainable and biodegradable materials in additive manufacturing. PLA-kraft lignin composites were created and their mechanical performance in fused deposition modeling (FDM) applications was assessed in this work. Polylactic acid (PLA) was mixed with Kraft lignin, a sustainable by-product of the paper industry, at weight percentages of 0%, 1%, 3%, 5%, and 7%. Melt blending was utilized to prepare the composites, which were then extruded into 1.75 mm diameter filaments that were used to create standard test specimens using an FDM 3D printer under ideal processing circumstances. Tensile, flexural, and impact tests were used to examine the mechanical characteristics of the printed specimens in compliance with ASTM guidelines. According to the findings, tensile strength increased with lignin addition up to 5 weight percent, suggesting improved load transmission and interfacial contact. However, additional increases in lignin content caused a minor decrease because to agglomeration effects. As the lignin content increased, the flexural strength and modulus gradually decreased, indicating the composites’ increased stiffness and decreased flexibility. The brittle behavior of PLA–lignin composites was confirmed by the finding that impact strength decreased with increasing lignin content. In order to establish a balance between strength, stiffness, and toughness, an ideal lignin content of 3-5 weight percent was found. By proving that kraft lignin may be used as sustainable filler in PLA for 3D printing applications, this study advances the creation of environmentally friendly composite materials with enhanced performance attributes.
Keywords: Polylactic Acid (PLA), Kraft Lignin, Fused Deposition Modeling (FDM), Melt blending, Biodegradable Composites.
Patlola Chandra Sekhar, T. Malyadri, B. Satyanarayana. Investigation on mechanical performance of 3D printed PLA-Kraft Lignin composites. Journal of Polymer & Composites. 2026; 14(03):-.
Patlola Chandra Sekhar, T. Malyadri, B. Satyanarayana. Investigation on mechanical performance of 3D printed PLA-Kraft Lignin composites. Journal of Polymer & Composites. 2026; 14(03):-. Available from: https://journals.stmjournals.com/jopc/article=2026/view=247821
References
- Obielodan J, Vergenz K, Aqil D, Wu J, Ellistrem LM. Characterization of PLA/lignin biocomposites for 3D printing.
- Rodríguez-Fabià S, Chinga-Carrasco G. Effects of a poly (hydroxyalkanoate) elastomer and kraft pulp fibres on biocomposite properties and three-dimensional (3D) printability of filaments for fused deposition modelling. Journal of Bioresources and Bioproducts. 2022 Aug 1;7(3):161-72.
- Makri SP, Klonos PA, Marra G, Karathanasis AZ, Deligkiozi I, Valera MÁ, Mangas A, Nikolaidis N, Terzopoulou Z, Kyritsis A, Bikiaris DN. Structure–property relationships in renewable composites of poly (lactic acid) reinforced by low amounts of micro-and nano-kraft-lignin. Soft Matter. 2024;20(25):5014-27.
- Chen J, Chen Y. Lignin as a sustainable filler in composites: Fabrications, mechanical properties, and applications.
- Mimini V, Sykacek E, Syed Hashim SN, Holzweber J, Hettegger H, Fackler K, Potthast A, Mundigler N, Rosenau T. Compatibility of kraft lignin, organosolv lignin and lignosulfonate with PLA in 3D printing. Journal of wood chemistry and technology. 2019 Jan 2;39(1):14-30.
- Kun D, Pukánszky B. Polymer/lignin blends: Interactions, properties, applications. European Polymer Journal. 2017 Aug 1;93:618-41.
- Peltola H. Morphological Effects of Lignocellulosic Fibres on Poly (Lactic Acid) Biocomposites.
- Gellerstedt G. Softwood kraft lignin: Raw material for the future. Industrial Crops and Products. 2015 Dec 23;77:845-54.
- Argyropoulos DD, Crestini C, Dahlstrand C, Furusjö E, Gioia C, Jedvert K, Henriksson G, Hulteberg C, Lawoko M, Pierrou C, Samec JS. Kraft lignin: a valuable, sustainable resource, opportunities and challenges. ChemSusChem. 2023 Dec 7;16(23):e202300492.
- Dessbesell L, Paleologou M, Leitch M, Pulkki R, Xu CC. Global lignin supply overview and kraft lignin potential as an alternative for petroleum-based polymers. Renewable and sustainable energy reviews. 2020 May 1;123:109768.
- Chakar FS, Ragauskas AJ. Review of current and future softwood kraft lignin process chemistry. Industrial crops and products. 2004 Sep 1;20(2):131-41.
- Rahman NA, Anuar H, Ali F, Suhr J. Mechanical and Thermal Properties of 3D Printed Polylactic Acid Reinforced Alkaline Lignin with Epoxidized Palm Oil Bio-Composites. InProceeding of 5th International Conference on Advances in Manufacturing and Materials Engineering: ICAMME 2022, 9—10 August, Kuala Lumpur, Malaysia 2023 May 14 (pp. 161-167). Singapore: Springer Nature Singapore.
- Liao J, Brosse N, Pizzi A, Hoppe S, Zhou X, Du G. Characterization and 3D printability of poly (lactic acid)/acetylated tannin composites. Industrial Crops and Products. 2020 Jul 1;149:112320.
- Hong SH, Park JH, Kim OY, Hwang SH. Preparation of chemically modified lignin-reinforced PLA biocomposites and their 3D printing performance. Polymers. 2021 Feb 23;13(4):667.
- Liao J, Brosse N, Pizzi A, Hoppe S, Zhou X, Du G. Characterization and 3D printability of poly (lactic acid)/acetylated tannin composites. Industrial Crops and Products. 2020 Jul 1;149:112320.
- Guessasma S, Stephant N, Durand S, Belhabib S. Digital light processing route for 3D printing of acrylate-modified PLA/lignin blends: microstructure and mechanical performance. Polymers. 2024 May 9;16(10):1342.
- Makri SP, Xanthopoulou E, Valera MA, Mangas A, Marra G, Ruiz V, Koltsakidis S, Tzetzis D, Zoikis Karathanasis A, Deligkiozi I, Nikolaidis N. Poly (lactic acid) composites with lignin and nanolignin synthesized by in situ reactive processing. Polymers. 2023 May 19;15(10):2386.
- Alshammari S. Development of Highly Loaded Polylactic Acid/Lignin Biocomposites for Material Extrusion Additive Manufacturing(Doctoral dissertation, University of Massachusetts Lowell).
- Obielodan JO, Delwiche M, Clark D, Downing C, Huntoon D, Wu T. Comparing the mechanical and thermal properties of polylactic acid/organosolv lignin biocomposites made of different biomass for 3D printing applications. Journal of Engineering Materials and Technology. 2022 Apr 1;144(2):021009.
- Ryu JA, Choi SR, Park JS, Ahn JH, Lee JM. Changes in properties of 3D printing filaments by extruding at different temperatures and lignin contents. Journal of Korea TAPPI. 2020 Jun 30;52(3):120-8.
- Esakkimuthu ES, DeVallance D, Pylypchuk I, Moreno A, Sipponen MH. Multifunctional lignin-poly (lactic acid) biocomposites for packaging applications. Frontiers in bioengineering and biotechnology. 2022 Oct 3;10:1025076.
- Terzopoulou Z, Xanthopoulou E, Pardalis N, Pappa CP, Torofias S, Triantafyllidis KS, Bikiaris DN. Synthesis and characterization of poly (lactic acid) composites with organosolv lignin. Molecules. 2022 Nov 23;27(23):8143.
- Hu J, Zhang Q, Lee DJ. Kraft lignin biorefinery: A perspective. Bioresource Technology. 2018 Jan 1;247:1181-3.
- Brodin I, Sjöholm E, Gellerstedt G. The behavior of kraft lignin during thermal treatment. Journal of Analytical and Applied Pyrolysis. 2010 Jan 1;87(1):70-7.
- Alekhina M, Ershova O, Ebert A, Heikkinen S, Sixta H. Softwood kraft lignin for value-added applications: Fractionation and structural characterization. Industrial Crops and Products. 2015 Apr 1;66:220-8.
- Agustiany EA, Rasyidur Ridho M, Rahmi DN M, Madyaratri EW, Falah F, Lubis MA, Solihat NN, Syamani FA, Karungamye P, Sohail A, Nawawi DS. Recent developments in lignin modification and its application in lignin‐based green composites: a review. Polymer Composites. 2022 Aug;43(8):4848-65.
- Amirah N, Rahman A, Anuar H. Mechanical and thermal properties of polylactic acid filled lignin powder biocomposite filaments with epoxidized palm oil for sustainable 3D printing application. PERINTIS eJournal. 2021;11:23-39.
- Murillo-Morales G, Sethupathy S, Zhang M, Xu L, Ghaznavi A, Xu J, Yang B, Sun J, Zhu D. Characterization and 3D printing of a biodegradable polylactic acid/thermoplastic polyurethane blend with laccase-modified lignin as a nucleating agent. International Journal of Biological Macromolecules. 2023 May 1;236:123881.
- Souza GF, Oliveira RR, Barros JJ, Kodali D, Rangari V, Moura EA. Preparation and characterization of 3D printed biobased composites from a PBAT/PLA blend with lignin and titanium dioxide. InTMS Annual Meeting & Exhibition 2024 Feb 3 (pp. 615-627). Cham: Springer Nature Switzerland.

Journal of Polymer & Composites
| Volume | 14 |
| 03 | |
| Received | 12/05/2026 |
| Accepted | 08/06/2026 |
| Published | 27/06/2026 |
| Publication Time | 46 Days |
Login
PlumX Metrics