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Vemuri Manohar Theodore,
Bondala Ramakrishna,
Raghuveer Dontikurti,
Dumpala Bhanuchandra Rao,
Apparao Damarasingu,
- M. Tech Scholar, Department of Mechanical Engineering, Aditya Institute of Technology and Management, Tekkali, Andhra Pradesh, India
- Professor, Department of Mechanical Engineering, Aditya Institute of Technology and Management, Tekkali, Andhra Pradesh, India
- Assistant Professor, Department of Mechanical Engineering, Aditya Institute of Technology and Management, Tekkali, Andhra Pradesh, India
- Assistant Professor, Department of Mechanical Engineering, Aditya Institute of Technology and Management, Tekkali, Andhra Pradesh, India
- Assistant Professor, Department of Mechanical Engineering, Aditya Institute of Technology and Management, Tekkali, Andhra Pradesh, India
Abstract
This work focuses on the development and evaluation of rice starch–charcoal–based composite materials to overcome the limitations of natural composites with low thermal properties. In order to examine the impact of filler concentration on thermal and structural performance, eight composite specimens were created by altering the ratios of rice starch and charcoal. TGA, DTA, AFM, SEM, and measurements of thermal conductivity and effusivity were used to thoroughly characterize the composites. Because of its high carbon content and porous structure, which may offer significant heat absorption and be helpful for boosting thermal stability and transmitting heat alongside the starch matrix, charcoal was selected to serve as functional reinforcement. Due to their weak thermal resistance, most traditional starch-based composites are not suitable for energy storage applications and cannot tolerate high temperatures. Due to the higher degradation temperature in TGA and higher heat absorption peaks in the DTA studies, the addition of charcoal improved the thermal resistance deficiencies in these composites. Improved particle dispersion and interfacial bonding within the starch matrix were suggested by the surface morphology obtained by SEM and AFM, which demonstrated a more uniform microstructure and decreased porosity with increased charcoal loading. Fill concentration was further shown to be advantageous over heat transfer characteristics in thermal analysis. With increasing charcoal content, the thermal effusivity of the composites grew steadily until specimen 8, which had the greatest bamboo charcoal content, reached its maximum of 1075 Ws½/m²K. Similarly, the trend of thermal conductivity and stability confirmed that adding more charcoal improved the composite’s capacity to absorb and store heat. Therefore, the rice starch-charcoal composite with a greater filler amount generally received improved thermal responsiveness, dimensional stability, and surface integrity. Therefore, our results present the creation of charcoal-reinforced starch composites as extremely interesting candidate materials for applications in packaging, energy management systems, and thermal insulation that can be handled economically and sustainably. As a result, the project opens the door for potential environmentally friendly thermal composites made from inexpensive, renewable natural materials.
Keywords: Charcoal Composites, Rice Starch, Thermal Analysis, SEM, AFM.
Vemuri Manohar Theodore, Bondala Ramakrishna, Raghuveer Dontikurti, Dumpala Bhanuchandra Rao, Apparao Damarasingu. Thermal and Morphological Characterization of Rice Starch–Charcoal Composites for Eco-Friendly Engineering Applications. Journal of Polymer & Composites. 2026; 14(02):-.
Vemuri Manohar Theodore, Bondala Ramakrishna, Raghuveer Dontikurti, Dumpala Bhanuchandra Rao, Apparao Damarasingu. Thermal and Morphological Characterization of Rice Starch–Charcoal Composites for Eco-Friendly Engineering Applications. Journal of Polymer & Composites. 2026; 14(02):-. Available from: https://journals.stmjournals.com/jopc/article=2026/view=240567
References
- Jang, S., Xiangxu, L., & Cho, U. R. (2018). Effect of bamboo charcoal powder on the curing characteristics, mechanical properties, and thermal properties of styrene-butadiene rubber with bamboo charcoal powder. Journal of Applied Polymer Science, 130(13), 4534–4541. https://doi.org/10.1002/app.4541
- Wang, S., Zhang, Y., & Zhang, J. (2020). Development of biodegradable flame-retardant bamboo charcoal composites. Polymers, 12(10), 2217. https://doi.org/10.3390/polym12102217
- Kremensas, A., Kairytė, A., Vaitkus, S., Vėjelis, S., & Balčiūnas, G. (2019). Mechanical performance of biodegradable thermoplastic polymer-based biocomposite boards from hemp shivs and corn starch for the building industry. Materials, 12(6), 845. https://doi.org/10.3390/ma12060845
- Pandecha, K., Pongtornkulpanich, A., & Chaiwong, S. (2016). Thermal properties of corn husk fiber as insulation for flat plate solar collector. Renewable Energy, 87, 302–309. https://doi.org/10.1016/j.renene.2015.10.037
- Balčiūnas, G., Vėjelis, S., Lekūnaitė-Lukošiūnė, L., & Kremensas, A. (2016). Assessment of structure influence on thermal conductivity of hemp shives composite. Environmental Engineering and Management Journal, 15(3), 705–711. https://doi.org/10.30638/eemj.2016.075
- Bovo, M., Della Torre, A., & Santoro, D. (2022). Contribution to thermal and acoustic characterization of corn cob for bio-based building insulation applications. Science of the Total Environment, 806, 150456. https://doi.org/10.1016/j.scitotenv.2021.150456
- Zou, D., Zhang, Y., & Zhang, J. (2022). Effect of different amounts of bamboo charcoal on the properties of polylactic acid composites. Composites Part A: Applied Science and Manufacturing, 152, 106648. https://doi.org/10.1016/j.compositesa.2021.106648
- Wang, S., Zhang, Y., & Zhang, J. (2020). Development of biodegradable flame-retardant bamboo charcoal composites. Polymers, 12(10), 2217. https://doi.org/10.3390/polym12102217
- Kremensas, A., Kairytė, A., Vaitkus, S., Vėjelis, S., & Balčiūnas, G. (2019). Mechanical performance of biodegradable thermoplastic polymer-based biocomposite boards from hemp shivs and corn starch for the building industry. Materials, 12(6), 845. https://doi.org/10.3390/ma12060845
- Pandecha, K., Pongtornkulpanich, A., & Chaiwong, S. (2016). Thermal properties of corn husk fiber as insulation for flat plate solar collector. Renewable Energy, 87, 302–309. https://doi.org/10.1016/j.renene.2015.10.037
- Balčiūnas, G., Vėjelis, S., Lekūnaitė-Lukošiūnė, L., & Kremensas, A. (2016). Assessment of structure influence on thermal conductivity of hemp shives composite. Environmental Engineering and Management Journal, 15(3), 705–711. https://doi.org/10.30638/eemj.2016.075
- Bovo, M., Della Torre, A., & Santoro, D. (2022). Contribution to thermal and acoustic characterization of corn cob for bio-based building insulation applications. Science of the Total Environment, 806, 150456. https://doi.org/10.1016/j.scitotenv.2021.150456
- Karuppiah, G., Kuttalam, K. C., Palaniappan, M., Santulli, C., & Palanisamy, S. (2020). Multiobjective Optimization of Fabrication Parameters of Jute Fiber/Polyester Composites with Egg Shell Powder and Nanoclay Filler. Molecules, 25(23), 5579. https://doi.org/10.3390/molecules25235579
- G. Padmanabhan, S. Rajesh, S. Karthikeyan, Sivasubramanian Palanisamy, R.A. Ilyas, Nadir Ayrilmis, ElSayed M. Tag-eldin, & Mohamed Kchaou (2024). Evaluation of mechanical properties and Fick’s diffusion behaviour of aluminum-DMEM reinforced with hemp/bamboo/basalt woven fiber metal laminates (WFML) under different stacking sequences. Ain Shams Engineering Journal, 15, 102759, https://doi.org/10.1016/j.asej.2024.102759
- Ayrilmis N, Kanat G, Yildiz Avsar E, Palanisamy S, Ashori A. (2024). Utilizing waste manhole covers and fibreboard as reinforcing fillers for thermoplastic composites. Journal of Reinforced Plastics and Composites. 44, 1177/07316844241238507
- Ramasubbu, R., Kayambu, A., Palanisamy, S., and Ayrilmis, N. (2024). Mechanical properties of epoxy composites reinforced with Areca catechu fibers containing silicon carbide.BioResources, 19, 10.15376/biores.19.2.2353-2370
- Aruchamy, K., Karuppusamy, M., Krishnakumar , S., Palanisamy, S., Jayamani, M., Sureshkumar , K., Ali, S. K., and Al-Farraj, S. A. (2025). Enhancement of mechanical properties of hybrid polymer composites using palmyra palm and coconut sheath fibers: The role of tamarind shell powder. BioResourcesI,20, 10.15376/biores.20.1.698-724
- Kar, A., Pandiarajan, N., Saikia, D., & Palanisamy, S. (2024). Effect of fiber loading on the mechanical, morphological, and dynamic mechanical characteristics of Calamus tenuis fiber reinforced epoxy composites. Journal of Vinyl and Additive Technology, 31(1), 224–240. https://doi.org/10.1002/vnl.22167

Journal of Polymer & Composites
| Volume | 14 |
| 02 | |
| Received | 12/11/2025 |
| Accepted | 21/11/2025 |
| Published | 23/04/2026 |
| Publication Time | 162 Days |
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