Material-Level Degradation of Magnetorheological Fluids Under Long-Term Cyclic Shear

Notice

This is an unedited manuscript accepted for publication and provided as an Article in Press for early access at the author’s request. The article will undergo copyediting, typesetting, and galley proof review before final publication. Please be aware that errors may be identified during production that could affect the content. All legal disclaimers of the journal apply.

Year : 2026 | Volume : 14 | 01 | Page :
    By

    Dewi Utami,

  • Saiful Amri Mazlan,

  • Nur Azmah Nordin,

  • Mohd Aidy Faizal Johari,

  • Ubaidilla,

  1. Researcher, Department of Engineering Materials and Structures (eMast) iKohza, Malaysia-Japan International Institute of Technology (MJIIT), Universiti Teknologi, Kuala Lumpur, , Malaysia
  2. Professor, Department of Engineering Materials and Structures (eMast) iKohza / Automotive Development Centre, Institute for Sustainable Transport (IST), Universiti Teknologi, Kuala Lumpur, , Malaysia
  3. Senior Lecturer, Department of Engineering Materials and Structures (eMast) iKohza / Automotive Development Centre, Institute for Sustainable Transport (IST), Universiti Teknologi,, Kuala Lumpur, , Malaysia
  4. Postdoctoral Researcher, Department of Engineering Materials and Structures (eMast) iKohza, Malaysia-Japan International Institute of Technology (MJIIT), Universiti Teknologi,, Kuala Lumpur, , Malaysia
  5. Professor, Mechanical Engineering Department, Faculty of Engineering, Universitas Sebelas Maret, J1. Ir. Sutami 36A, Ketingan, Surakarta, 57126, Central Java, , Indonesia

Abstract

The long-term functional stability of magnetorheological fluids (MRF) remains a key limitation for their reliable use in adaptive systems and continuously operated magnetorheological devices. In this study, the intrinsic evolution of rheological properties in a commercial MRF (MRC-C1L) is systematically examined under prolonged cyclic loading, with the aim of isolating material-level degradation mechanisms independent of device-related effects. The fluid was subjected to 120,000 low-strain oscillatory shear cycles under a constant magnetic field, simulating extended service conditions while avoiding macroscopic structural failure. Rheological measurements revealed a progressive decrease of approximately 13 percent in magnetically induced shear stress, indicating partial irreversibility in field-induced particle chain formation and microstructural densification within the suspension. Microstructural characterization using scanning electron microscopy confirmed the morphological integrity of the carbonyl iron particles, with no evidence of fragmentation or severe wear. However, energy-dispersive X-ray spectroscopy detected a measurable increase in surface oxygen content from 1.4 percent to 1.5 percent, suggesting the onset of mild oxidative processes at the particle-fluid interface. These findings indicate that early-stage oxidative interfacial modification, rather than mechanical damage, is the dominant degradation pathway under low-strain cyclic loading, promoting irreversible particle clustering and a gradual loss of magnetorheological performance. The results provide new insight into the physicochemical aging behavior of MRF and offer practical guidance for the design of oxidation-resistant formulations with enhanced durability for demanding automotive and aerospace applications.

 

Keywords: degradation, magneto-responsive fluid, oscillatory, rheological response, shear stress

How to cite this article:
Dewi Utami, Saiful Amri Mazlan, Nur Azmah Nordin, Mohd Aidy Faizal Johari, Ubaidilla. Material-Level Degradation of Magnetorheological Fluids Under Long-Term Cyclic Shear. Journal of Polymer & Composites. 2026; 14(01):-.
How to cite this URL:
Dewi Utami, Saiful Amri Mazlan, Nur Azmah Nordin, Mohd Aidy Faizal Johari, Ubaidilla. Material-Level Degradation of Magnetorheological Fluids Under Long-Term Cyclic Shear. Journal of Polymer & Composites. 2026; 14(01):-. Available from: https://journals.stmjournals.com/jopc/article=2026/view=238428


References

  1. Wereley NM, Cho JU, Choi YT, Choi SB. Magnetorheological dampers in shear mode. Smart Mater Struct. 2008 Feb 1;17(1).
  2. Dutra RMA, de Andrade RM, Soares AB, Thakor NV, Vimieiro CBS. Magnetorheological fluid in prostheses: A state-of-the-art review. Vol. 35, Journal of Intelligent Material Systems and Structures. SAGE Publications Ltd; 2024. p. 485–516.
  3. Saini RST, Kumar H, Chandramohan S. Optimal design of ow mode semi-active prosthetic knee dampers. Scientia Iranica. 2022 Nov 1;29(6 B):3049–62.
  4. Laun HM, Gabriel C, Kieburg C. Magnetorheological fluid in oscillatory shear and parameterization with regard to MR device properties. In: Journal of Intelligent Material Systems and Structures. 2010. p. 1479–89.
  5. Carlson JD. What makes a good MR fluid? J Intell Mater Syst Struct [Internet]. 2002 Jul 18;13(7–8):431–5. Available from: http://jim.sagepub.com/cgi/doi/10.1106/104538902028221
  6. Deng L, Sun S, Christie M, Ning D, Jin S, Du H, et al. Investigation of a seat suspension installed with compact variable stiffness and damping rotary magnetorheological dampers. Mech Syst Signal Process. 2022 May 15;171.
  7. Kumar JS, Paul PS, Raghunathan G, Alex DG. A review of challenges and solutions in the preparation and use of magnetorheological fluids. Vol. 14, International Journal of Mechanical and Materials Engineering. Springer; 2019.
  8. Liang W, Qian Z, Chen W, Song H, Cao Y, Wei G, et al. Mechanisms and component design of prosthetic knees: A review from a biomechanical function perspective. Vol. 10, Frontiers in Bioengineering and Biotechnology. Frontiers Media S.A.; 2022.
  9. Chen X, Andrews MP, Landry-Blais A, Lucking Bigué JP, Plante JS. Investigation of shear-induced physical and chemical transformations of Fe microparticles in hydrocarbon- And fluorocarbon-based magnetorheological fluids. Smart Mater Struct. 2019 Aug 27;28(10).
  10. Johari MAF, Mazlan SA, Ubaidillah U, Nordin NA, Ahmad Khairi MH, Abdul Aziz SA, et al. Natural Weathering Effects on the Mechanical, Rheological, and Morphological Properties of Magnetorheological Elastomer (MRE) in Tropical Climate. Int J Mol Sci. 2022 Sep 1;23(17).
  11. Kikuchi T, Abe I, Ueshima Y, Akaiwa S, Tsuji H. Development of Durability Test Device for Magnetorheological Fluids with Two Types of Rotors and Their Long-Term Torque Characteristics. Actuators. 2022 Jun 1;11(6).
  12. Utami D, Ubaidillah, Mazlan SA, Imaduddin F, Nordin NA, Bahiuddin I, et al. Material characterization of a magnetorheological fluid subjected to long-term operation in damper. Materials. 2018 Nov 6;11(11).
  13. 2025 Integrative Machine Learning approaches for predicting the rheological behaviour of soft mr elastomer.
  14. Choi SB. Sedimentation Stability of Magnetorheological Fluids: The State of the Art and Challenging Issues. Vol. 13, Micromachines. MDPI; 2022.
  15. Osial M, Pregowska A, Warczak M, Giersig M. Magnetorheological fluids: A concise review of composition, physicochemical properties, and models. Vol. 34, Journal of Intelligent Material Systems and Structures. SAGE Publications Ltd; 2023. p. 1864–84.
  16. Hreinsson E. Durability of a Magnetorheological Fluid in a Prosthetic Knee Joint. PhD Thesis, University of Iceland, Reykjavik, Iceland; 2011.
  17. Ciocanel C, Elahinia MH, Molyet KE, Naganathan NG. Design analysis and control of a magnetorheological fluid based torque transfer device. International Journal of Fluid Power. 2008;9(3):19–24.
  18. Shan L, Chen K, Zhou M, Zhang X, Meng Y, Tian Y. Shear history effect of magnetorheological fluids. Smart Mater Struct. 2015 Sep 18;24(10).
  19. Tian Y, Chen KK, Shan L, Zhang X, Meng Y. Unexpected shear strength change in magnetorheological fluids. APL Mater. 2014 Sep 1;2(9).
  20. Nagiredla S, Joladarashi S, Kumar H. Characterization of an in-house prepared magnetorheological fluid and vibrational behavior of composite sandwich beam with magnetorheological fluid core. Scientia Iranica. 2023 May 1;30(3 B):983–96.
  21. Maurya CS, Sarkar C. Magnetorheological fluids: a comprehensive review of operational modes and performance under varied circumstances. Rheologica Acta. Springer Nature; 2024.
  22. Ulicny JC, Balogh MP, Potter NM, Waldo RA. Magnetorheological fluid durability test-Iron analysis. Materials Science and Engineering: A. 2007 Jan 15;443(1–2):16–24.
  23. Spaggiari A. Properties and applications of magnetorheological fluids. Frattura ed Integrita Strutturale. 2012;23:57–61.
  24. Cheng H, Wang M, Liu C, Wereley NM. Improving sedimentation stability of magnetorheological fluids using an organic molecular particle coating. Smart Mater Struct. 2018 Jun 11;27(7).

Ahead of Print Subscription Original Research
Volume 14
01
Received 28/01/2026
Accepted 11/02/2026
Published 12/03/2026
Publication Time 43 Days


Login


My IP

PlumX Metrics