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Samjeet Singh Thakur,
Diwaker,
- Assistant Professor, Chemistry Department; NSCBM Govt. College Hamirpur, Himachal Pradesh, India
- Assistant Professor, Physics Department; SCVB Govt. College Palampur, Himachal Pradesh,
Abstract
Thin film coatings made from silicon dioxide (SiO₂), titanium dioxide (TiO₂) and zirconium dioxide (ZrO₂) have attracted great interest owing to their excellent optical, electrical, mechanical and chemical properties. These oxide thin films are widely used in microelectronics, solar cells, sensors, biomedical devices, photocatalysis, anti-reflective coatings and protective layers. The structural, morphological, compositional, optical and mechanical properties of these coatings are closely related to their performance and reliability. Therefore, thorough characterization methods are required to assess the film quality and adjust the deposition conditions. This article gives an overview of major characterization approaches for SiO2, TiO2 and ZrO2 thin film coatings. Structural analysis techniques like X-ray diffraction (XRD), morphological studies using scanning electron microscopy (SEM) and atomic force microscopy (AFM), compositional investigations using energy dispersive X-ray spectroscopy (EDX) and X-ray photoelectron spectroscopy (XPS), optical characterization using UV–Visible spectroscopy and ellipsometry, and mechanical characterization techniques including nanoindentation are detailed. The paper also points out the significance of these procedures in crystallinity, surface roughness, elemental composition, optical band gap, refractive index, hardness and adhesion qualities. Recent developments and applications of oxide thin film characterization are also very briefly discussed.
Keywords: Thin films, SiO₂ coatings, TiO₂ coatings, ZrO₂ coatings, characterization techniques, XRD, SEM, AFM, optical properties.
References
- Waseda Y, Matsubara E, Shinoda K. X-ray diffraction crystallography: introduction, examples and solved problems. Springer Science & Business Media; 2011 Mar 18.
- Wang, Z. L. (2001). Characterization of nanophase materials. Particle & Particle Systems Characterization: Measurement and Description of Particle Properties and Behavior in Powders and Other Disperse Systems, 18(3), 142-165.
- Henrich, V. E., & Cox, P. A. (1994). The surface science of metal oxides. Cambridge university press.
- Brinker, C. J., & Scherer, G. W. (1990). Sol-gel science: the physics and chemistry of sol-gel processing. Gulf Professional Publishing.
- Batzill, M., & Diebold, U. (2005). The surface and materials science of tin oxide. Progress in surface science, 79(2-4), 47-154.
- Fujishima, A., & Honda, K. (1972). Electrochemical photolysis of water at a semiconductor electrode. nature, 238(5358), 37-38.
- Macµk, J. M., Tsuchiya, H., & Schmuki, P. (2005). High-aspect-ratio TiO2 nanotubes by anodization of titanium. Chem. Int. Ed, 44, 2100-2102.
- Robertson, J. (2006). High dielectric constant gate oxides for metal oxide Si transistors. Reports on progress in Physics, 69(2), 327-396.
- Pecharromán, C., & Moya, J. S. (2000). Experimental evidence of a giant capacitance in insulator–conductor composites at the percolation threshold. Advanced Materials, 12(4), 294-297.
- Ohring, M. (2002). Materials science of thin films: depositon and structure. Academic press.
- Epifani, M., Giannini, C., Tapfer, L., & Vasanelli, L. (2000). Sol–gel synthesis and characterization of Ag and Au nanoparticles in SiO2, TiO2, and ZrO2 thin films. Journal of the American Ceramic Society, 83(10), 2385-2393.
- Adamczyk, A. (2018). The influence of ZrO2 precursor type on the structure of ZrO2-TiO2-SiO2 gels and selected thin films. Journal of Molecular Structure, 1171, 706-716.
- Bensouyad, H., Sedrati, H., Dehdouh, H., Brahimi, M., Abbas, F., Akkari, H., & Bensaha, R. (2010). Structural, thermal and optical characterization of TiO2: ZrO2 thin films prepared by sol–gel method. Thin Solid Films, 519(1), 96-100.
- Cueto, L. F., Sánchez, E., Torres-Martínez, L. M., & Hirata, G. A. (2005). On the optical, structural, and morphological properties of ZrO2 and TiO2 dip-coated thin films supported on glass substrates. Materials Characterization, 55(4-5), 263-271.
- Catauro, M., Barrino, F., Bononi, M., Colombini, E., Giovanardi, R., Veronesi, P., & Tranquillo, E. (2019). Coating of titanium substrates with ZrO2 and ZrO2-SiO2 composites by sol-gel synthesis for biomedical applications: Structural characterization, mechanical and corrosive behavior. Coatings, 9(3), 200.
- Dogra, V., Kishore, C., Mishra, A., Gaur, A., & Verma, A. (2026). Fabrication and characterisation of SiO2-ZrO2 double-layer nano-coating with potential usage as hydrophobic and antireflective coatings for solar applications. Materials Research Innovations, 30(2), 123-134.
- Bohdan, L., Hutsul, K., Yanushevska, O., Fedenko, Y., & Dontsova, T. (2025). Features of obtaining selective metal oxide layers for ceramic membranes via sol-gel method. Technology audit and production reserves, 6(3 (86)), 12-20.
- Gözlekçi, G., Er, U., Dönmez Kaya, M., Ataşer, T., Akın Sönmez, N., & Özçelik, S. (2025). UV-reflective functional coatings for bird-safe architectural glass. Journal of Materials Science: Materials in Electronics, 36(31), 2001.
- Lim, J., Kim, D., Lee, N. H., Kim, Y. G., Yu, H. K., Choi, J. Y., & Park, J. H. (2025). Optimizing electrostatic chuck performance through ZrO₂/Al₂O₃ ratio and doping components (SiO₂ and Y₂O₃). Ceramics International, 51(9), 11432-11436.
- Ali, S., Khan, M. F., Ullah, M. A., & Iqbal, M. W. (2025). Magnesium-doped ZnO thin film memristors for enhanced synaptic plasticity and resistive switching in neuromorphic computing. Journal of Alloys and Compounds, 1015, 178800.
- Srilatha, N., Prasad, S. S., Sahithi, V. V. D., Hari, S. S., & Balashowry, K. (2025). Developing Hybrid and Functional Materials with Sol-gel Chemistry–A Review. Journal of Environmental Nanotechnology, 14(3), 540-558.
- Wang, Y., Tian, X., Li, S., An, C., Liu, L., Liu, Y., … & Ma, Z. (2026). Room-temperature fabrication of TiO2 thin films with enhanced electrochromic performance. Surfaces and Interfaces, 108608.
- Lopamudra, P., Tripathy, H. P., Sabat, S., Sahoo, K. K., Gartia, A., Biswal, S. R., … & Pradhan, D. (2025, May). Modulation in the Performance of $text {Ni}-text {TiO} 2$ Thin Film Based Semiconductor Devices. In 2025 International Conference in Advances in Power, Signal, and Information Technology (APSIT)(pp. 1-5). IEEE.
- Benabid, F. Z., Kridi, S., Zouai, F., Khan, M. E., Ali, W., Ali, S. K., … & Zakri, W. (2025). Improved properties of PVDF/TiO2 nanocomposites through eco-friendly TiO2 treatment with stearic acid for optimal functional additive dispersion. Ceramics International, 51(7), 9429-9435.
- Davronbek, S., Bakhtiyor, G., & Gulyora, A. Z. (2026). Preparation of Metal–Dielectric–Semiconductor Structures Based on Metal Oxide Thin Films and Their Physical Propertie. Journal of Scientific Research of Uzbek Scholars, 1(5), 34-45.
- Tarek, A. H., Lai, C. W., Razak, B. A., & Wong, Y. H. (2022). Physical vapour deposition of Zr-based nano films on various substrates: A review. Current Nanoscience, 18(3), 347-366.

Journal of Materials & Metallurgical Engineering
| Volume | 16 | |
| 02 | ||
| Received | 02/06/2026 | |
| Accepted | 21/08/2026 | |
| Published | 26/08/2026 | |
| Publication Time | 85 Days |