Machine-Learning-Assisted Development of Polymer-Biochar Composite Adsorbents for the Removal of Heavy Metals from Gomti River Water

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Year : 2026 | Volume : 14 | 04 | Page :
    By

    Nidhi Singh,

  • Smita Tung,

  1. Research Scholar, Department of Civil Engineering, GLA University, Mathura, Uttar Pradesh,
  2. Assistant Professor, Department of Civil Engineering, GLA University, Mathura, Uttar Pradesh, India

Abstract

Rapid urbanization, industrial discharge, and agricultural runoff pose a significant threat to freshwater sustainability and public health. Within these ecosystems, polymer pollutants—such as microplastics, nanoplastics, synthetic fibres, and additive residues—have emerged as persistent vectors capable of adsorbing and transporting toxic heavy metals. Because these polymeric contaminants dynamically interact with conventional aquatic parameters to alter pollutant mobility and ecological risk profiles, there is an urgent need to transition from passive environmental monitoring to active, materials-driven remediation. To address this challenge, this study presents the development and machine-learning-assisted performance evaluation of a novel polymer-biochar composite adsorbent designed for the removal of heavy metals from complex aquatic matrices. The Gomti River Basin was utilized as a real-world environmental testbed. A dataset comprising 100 water samples collected from five representative locations, characterized by 18 physicochemical and heavy-metal parameters, served as the competing ionic background matrix. To predict the composite’s adsorption efficiency under varying, non-linear riverine conditions, a comparative assessment of machine learning (ML) models—Multiple Linear Regression (MLR) and Artificial Neural Network (ANN)—was conducted. A standardized 70:30 train–test split combined with nested 10-fold cross-validation was employed to ensure robust model development. Among the investigated models, the ANN demonstrated superior predictive capability for evaluating the composite’s performance against matrix interferences, achieving a testing R² of 0.99, RMSE of 0.05, and 92.5% of predictions falling within ±20% of observed values. From a physical chemistry perspective, the ML framework identified that elevated Electrical Conductivity (EC), Total Dissolved Solids (TDS), and sulfate concentrations act as the dominant variables influencing the electrical double layer, surface complexation, and biosorption capacity of the polymeric material. Ultimately, these findings demonstrate that integrating green polymer-composite design with data-driven ML modelling provides a highly effective pathway for optimizing nanoparticle-enabled water-treatment technologies, thereby advancing the goals of circular polymer science and sustainable aquatic management.

Keywords: Polymeric contaminants, Micro plastics, Nano plastics, Water Quality Index, Machine Learning; Gomti River Basin, Biopolymers; Nanoparticles; Biosorption; Green composites; River water quality.

How to cite this article:
Nidhi Singh, Smita Tung. Machine-Learning-Assisted Development of Polymer-Biochar Composite Adsorbents for the Removal of Heavy Metals from Gomti River Water. Journal of Polymer & Composites. 2026; 14(04):-.
How to cite this URL:
Nidhi Singh, Smita Tung. Machine-Learning-Assisted Development of Polymer-Biochar Composite Adsorbents for the Removal of Heavy Metals from Gomti River Water. Journal of Polymer & Composites. 2026; 14(04):-. Available from: https://journals.stmjournals.com/jopc/article=2026/view=248262


References

  1. Ahmed, Mehreen, Rafia Mumtaz, and Syed Mohammad Hassan Zaidi. 2021. “Analysis of Water Quality Indices and Machine Learning Techniques for Rating Water Pollution: A Case Study of Rawal Dam, Pakistan.” Water Supply 21(6):3225–50. doi:10.2166/ws.2021.082.
  2. Ajoy Kanti Das, Nandini Gupta, Tahir Mahmood, Binod Chandra Tripathy, Rakhal Das, Suman Das. 2025. An Efficient Water Quality Evaluation Model Using Weighted Hesitant Fuzzy Soft Sets for Water Pollution Rating. 1st ed. CRC Press, Taylor & Francis.
  3. Ayvaz, M. Tamer. 2010. “A Linked Simulation-Optimization Model for Solving the Unknown Groundwater Pollution Source Identification Problems.” Journal of Contaminant Hydrology 117(1–4):46–59. doi:10.1016/j.jconhyd.2010.06.004.
  4. Baudron, Paul, Francisco Alonso-Sarría, José Luís García-Aróstegui, Fulgencio Cánovas-García, David Martínez-Vicente, and Jesús Moreno-Brotóns. 2013. “Identifying the Origin of Groundwater Samples in a Multi-Layer Aquifer System with Random Forest Classification.” Journal of Hydrology 499:303–15. doi:10.1016/j.jhydrol.2013.07.009.
  5. Bose, Shirsha, Elisa Mele, and Vadim V. Silberschmidt. 2024. “Computational Modelling of Collagen-Based Flexible Electronics: Assessing the Effect of Hydration.” Multiscale and Multidisciplinary Modeling, Experiments and Design 7(3):1643–55. doi:10.1007/s41939-023-00230-4.
  6. Cao, Minghua, Konstantinos P. Baxevanakis, and Vadim V. Silberschmidt. 2024. “High-Temperature Behaviour and Interfacial Damage of CGI: 3D Numerical Modelling.” Multiscale and Multidisciplinary Modeling, Experiments and Design 7(3):1515–25. doi:10.1007/s41939-023-00188-3.
  7. Chabuk, Ali, Udai A. Jahad, Ali Majdi, Hasan Sh Majdi, Aya Alaa Hadi, Hassan Hadi, Nadhir Al-Ansari, and Mubeen Isam. 2023. “Integrating WQI and GIS to Assess Water Quality in Shatt Al-Hillah River, Iraq Using Physicochemical and Heavy Metal Elements.” Applied Water Science 13(7):1–15. doi:10.1007/s13201-023-01933-2.
  8. Chen, Longhu, Qinqin Wang, Guofeng Zhu, Xinrui Lin, Dongdong Qiu, Yinying Jiao, Siyu Lu, Rui Li, Gaojia Meng, and Yuhao Wang. 2024. “Dataset of Stable Isotopes of Precipitation in the Eurasian Continent.” Earth System Science Data 16(3):1543–57. doi:10.5194/essd-16-1543-2024.
  9. Chen, Longhu, Guofeng Zhu, Xinrui Lin, Rui Li, Siyu Lu, Yinying Jiao, Dongdong Qiu, Gaojia Meng, and Qinqin Wang. 2024. “The Complexity of Moisture Sources Affects the Altitude Effect of Stable Isotopes of Precipitation in Inland Mountainous Regions.” Water Resources Research 60(6). doi:10.1029/2023WR036084.
  10. Das, Ajoy Kanti, and Carlos Granados. 2024. “Neutrosophic Systems with Applications Neutrosophic Approach to Water Quality Assessment : A Case Study of Gomati River , the Largest River in Tripura , India Neutrosophic Approach to Water Quality Assessment : A Case Study of Gomati River , the Largest R.” 22(1).
  11. Das, Ajoy Kanti, Nandini Gupta, Tahir Mahmood, Binod Chandra Tripathy, Rakhal Das, and Suman Das. 2024. “An Innovative Fuzzy Multi-Criteria Decision Making Model for Analyzing Anthropogenic Influences on Urban River Water Quality.” Iran Journal of Computer Science 8(1):103–24. doi:10.1007/s42044-024-00211-x.
  12. Das, Biswajit, Sanjay Jain, Surjeet Singh, and Praveen Thakur. 2019. “Evaluation of Multisite Performance of SWAT Model in the Gomti River Basin, India.” Applied Water Science 9(5):1–10. doi:10.1007/s13201-019-1013-x.
  13. Dheeraj, Vijayendra Pratap, C. S. Singh, Nawal Kishore, and Ashwani Kumar Sonkar. 2023. “Groundwater Quality Assessment in Korba Coalfield Region, India: An Integrated Approach of GIS and Heavy Metal Pollution Index (HPI) Model.” Nature Environment and Pollution Technology 22(1):369–82. doi:10.46488/NEPT.2023.V22I01.036.
  14. Dong, Y., M. Gao, Z. Song, and W. Qiu. 2020. “As(III) Adsorption onto Different-Sized Polystyrene Microplastic Particles and Its Mechanism.” Chemosphere 239:124792. doi:10.1016/j.chemosphere.2019.124792.
  15. Godoy, V., G. Blázquez, M. Calero, L. Quesada, and M. A. Martín-Lara. 2019. “The Potential of Microplastics as Carriers of Metals.” Environmental Pollution 255:113363. doi:10.1016/j.envpol.2019.113363.
  16. Haq, Mohd Anul, Abdul Khadar Jilani, and P. Prabu. 2022. “Deep Learning Based Modeling of Groundwater Storage Change.” Computers, Materials and Continua 70(3):4599–4617. doi:10.32604/cmc.2022.020495.
  17. Hahladakis, J. N., C. A. Velis, R. Weber, E. Iacovidou, and P. Purnell. 2018. “An Overview of Chemical Additives Present in Plastics: Migration, Release, Fate and Environmental Impact During Their Use, Disposal and Recycling.” Journal of Hazardous Materials 344:179–199. doi:10.1016/j.jhazmat.2017.10.014.
  18. Hermabessiere, L., A. Dehaut, I. Paul-Pont, C. Lacroix, R. Jezequel, P. Soudant, and G. Duflos. 2017. “Occurrence and Effects of Plastic Additives on Marine Environments and Organisms: A Review.” Chemosphere 182:781–793. doi:10.1016/j.chemosphere.2017.05.096.
  19. Holmes, L. A., A. Turner, and R. C. Thompson. 2012. “Adsorption of Trace Metals to Plastic Resin Pellets in the Marine Environment.” Environmental Pollution 160:42–48. doi:10.1016/j.envpol.2011.08.052.
  20. Iqbal, Kashifa, Shamshad Ahmad, and Venkatesh Dutta. 2019. “Pollution Mapping in the Urban Segment of a Tropical River: Is Water Quality Index (WQI) Enough for a Nutrient-Polluted River?” Applied Water Science 9(8):1–16. doi:10.1007/s13201-019-1083-9.
  21. Jiang, Simin, Jinhong Fan, Xuemin Xia, Xianwen Li, and Ruicheng Zhang. 2018. “An Effective Kalman Filter-Based Method for Groundwater Pollution Source Identification and Plume Morphology Characterization.” Water (Switzerland) 10(8). doi:10.3390/w10081063.
  22. Kanti, Ajoy, Das Nandini, Gupta Tahir, Mahmood Binod, Chandra Tripathy, Rakhal Das, and Suman Das. 2024. “Assessing Anthropogenic Influences on the Water Quality of Gomati River Using an Innovative Weighted Fuzzy Soft Set Based Water Pollution Rating System.” Discover Water. doi:10.1007/s43832-024-00136-3.
  23. Khalaf, Amr Mostafa, and Rabee Rustum. 2024. “Assessment of Projected Extreme Climate Change Impact on the Operational Performance of Surface Water Reservoirs.” Water Conservation and Management 8(1):11–19. doi:10.26480/wcm.01.2024.11.19.
  24. Khan, Ramsha, and Abhishek Saxena. 2023. “Potentially Toxic Elements (PTEs) in Gomti-Ganga Alluvial Plain, Associated Human Health Risks Assessment and Potential Remediation Using Novel-Nanomaterials.” Environmental Monitoring and Assessment 195(1). doi:10.1007/s10661-022-10562-2.
  25. Khan, Ramsha, Abhishek Saxena, Saurabh Shukla, Pooja Goel, Prosun Bhattacharya, Peiyue Li, Esmat F. Ali, and Sabry M. Shaheen. 2022. “Appraisal of Water Quality and Ecological Sensitivity with Reference to Riverfront Development along the River Gomti, India.” Applied Water Science 12(1):1–12. doi:10.1007/s13201-021-01560-9.
  26. Khullar, Sakshi, and Nanhey Singh. 2021. “Machine Learning Techniques in River Water Quality Modelling: A Research Travelogue.” Water Science and Technology: Water Supply 21(1). doi:10.2166/ws.2020.277.
  27. Krishnamoorthy, Loganathan, and Vignesh Rajkumar Lakshmanan. 2024. “Groundwater Quality Assessment Using Machine Learning Models: A Comprehensive Study on the Industrial Corridor of a Semi-Arid Region.” Environmental Science and Pollution Research (July). doi:10.1007/s11356-024-34119-7.
  28. Li, Rui, Guofeng Zhu, Longhu Chen, Xiaoyu Qi, Siyu Lu, Gaojia Meng, Yuhao Wang, Wenmin Li, Zhijie Zheng, Jiangwei Yang, and Yani Gun. 2025. “Global Stable Isotope Dataset for Surface Water.” Earth System Science Data 17(5):2135–45. doi:10.5194/essd-17-2135-2025.
  29. Lu, Yen-Ju, Ching-Wen Wang, and Chen-Hua Wang. 2025. “A Hybrid Diagnostic System for Corrosion Mechanism Identification in Petrochemical Equipment: Integrating Bayesian Probabilities and Association Rule.” Process Safety and Environmental Protection 201:107577. doi:https://doi.org/10.1016/j.psep.2025.107577.
  30. Mohinuddin, Sk, Soumita Sengupta, Biplab Sarkar, Ujwal Deep Saha, Aznarul Islam, Abu Reza Md Towfiqul Islam, Zakir Md Hossain, Sadik Mahammad, Taushik Ahamed, Raju Mondal, Wanchang Zhang, and Aimun Basra. 2023. “Assessing Lake Water Quality during COVID-19 Era Using Geospatial Techniques and Artificial Neural Network Model.” Environmental Science and Pollution Research 30(24):65848–64. doi:10.1007/s11356-023-26878-6.
  31. Nandi, B. P., G. Singh, A. Jain, and D. K. Tayal. 2024. “Evolution of Neural Network to Deep Learning in Prediction of Air, Water Pollution and Its Indian Context.” International Journal of Environmental Science and Technology 21(1):1021–36. doi:10.1007/s13762-023-04911-y.
  32. Nayak, Anjali, Gagan Matta, and D. P. Uniyal. 2023. Hydrochemical Characterization of Groundwater Quality Using Chemometric Analysis and Water Quality Indices in the Foothills of Himalayas. Vol. 25. Springer Netherlands.
  33. Pimparkar, A. M., S. N. Patil, B. D. Patil, and A. K. Kadam. 2023. “Comparative Assessment of Wetland Water Quality from Rural and Urban Area of Aurangabad District, Maharashtra, India Using Water Quality Index.” HydroResearch 6:269–78. doi:10.1016/j.hydres.2023.10.001.
  34. Poursaeid, Mojtaba. 2025. “Comprehensive Water Quality Indicators Modeling by Environmental Protection View Using Multi Optimized Weighted Ensemble Machine Learnings.” Process Safety and Environmental Protection 193(October 2024):696–709. doi:10.1016/j.psep.2024.11.042.
  35. Saalidong, Benjamin M., Simon Appah Aram, Samuel Otu, and Patrick Osei Lartey. 2022. “Examining the Dynamics of the Relationship between Water PH and Other Water Quality Parameters in Ground and Surface Water Systems.” PLoS ONE 17(1 1):1–17. doi:10.1371/journal.pone.0262117.
  36. Santy, Sneha, Pradeep Mujumdar, and Govindasamy Bala. 2020. “Potential Impacts of Climate and Land Use Change on the Water Quality of Ganga River around the Industrialized Kanpur Region.” Scientific Reports 10(1):1–13. doi:10.1038/s41598-020-66171-x.
  37. Saqib, Nazmu, Praveen Kumar Rai, Shruti Kanga, Deepak Kumar, Bojan Đurin, and Suraj Kumar Singh. 2023. “Assessment of Ground Water Quality of Lucknow City under GIS Framework Using Water Quality Index (WQI).” Water (Switzerland) 15(17). doi:10.3390/w15173048.
  38. Sidek, L. M., H. A. Mohiyaden, M. Marufuzzaman, N. S. M. Noh, Salim Heddam, Mohammad Ehteram, Ozgur Kisi, and Saad Sh Sammen. 2024. “Developing an Ensembled Machine Learning Model for Predicting Water Quality Index in Johor River Basin.” Environmental Sciences Europe 36(1). doi:10.1186/s12302-024-00897-7.
  39. Singh, Kunwar P., Ankita Basant, Amrita Malik, and Gunja Jain. 2009. “Artificial Neural Network Modeling of the River Water Quality-A Case Study.” Ecological Modelling 220(6):888–95. doi:10.1016/j.ecolmodel.2009.01.004.
  40. Singh, Nidhi, and Smita Tung. 2025. “Assessment of Water Quality of Gomti River at Lucknow.” Air, Soil and Water Research doi:10.1177/11786221251328589.
  41. Singh, Raj Mohan, and Bithin Datta. 2007. “Artificial Neural Network Modeling for Identification of Unknown Pollution Sources in Groundwater with Partially Missing Concentration Observation Data.” Water Resources Management 21(3):557–72. doi:10.1007/s11269-006-9029-z.
  42. Sohn, Insoo. 2021. “Deep Belief Network Based Intrusion Detection Techniques: A Survey.” Expert Systems with Applications 167:114170. doi:10.1016/j.eswa.2020.114170.
  43. Surya Prakash, Mishra. 2014. “Analysis of Water Quality of Gomti River At District Sultanpur (U.P.).” International Journal of Engineering Science Invention Research & Development I(Iii):113.
  44. Turner, A., and L. A. Holmes. 2015. “Adsorption of Trace Metals by Microplastic Pellets in Fresh Water.” Environmental Chemistry 12(5):600–610. doi:10.1071/EN14143.
  45. Tourinho, P. S., V. Kočí, S. Loureiro, and C. A. van Gestel. 2019. “Partitioning of Chemical Contaminants to Microplastics: Kinetic and Thermodynamic Aspects.” Environmental Toxicology and Chemistry 38(10):2093–2110. doi:10.1002/etc.4540.
  46. Wang, Borui, Zhifang Tan, Wanbao Sheng, Zihao Liu, Xiaoqi Wu, Lu Ma, and Zhijun Li. 2024. “Identification of Groundwater Contamination Sources Based on a Deep Belief Neural Network.” Water (Switzerland) 16(17). doi:10.3390/w16172449.
  47. Wang, F., K. M. Shih, and X. Y. Li. 2017. “The Partition Behavior of Perfluorooctanesulfonate (PFOS) and Perfluorooctanesulfonamide (FOSA) on Microplastics.” Chemosphere 181:60–67. doi:10.1016/j.chemosphere.2017.04.039.
  48. Wang, J., X. Liu, Y. Li, T. Powell, X. Wang, G. Wang, and P. Zhang. 2020. “Microplastics as a Vector for Heavy Metals in a Simulated Riverine Environment.” Science of the Total Environment 704:135437. doi:10.1016/j.scitotenv.2019.135437.
  49. Wei, Chengbiao, Taoyan Zhao, Jiangtao Cao, and Ping Li. 2025. “Water Quality Prediction Model Based on Interval Type-2 Fuzzy Neural Network with Adaptive Membership Function.” International Journal of Fuzzy Systems. doi:10.1007/s40815-025-01999-x.
  50. Wei, Wangru, Weilin Xu, Jun Deng, and Yakun Guo. 2022. “Self-Aeration Development and Fully Cross-Sectional Air Diffusion in High-Speed Open Channel Flows.” Journal of Hydraulic Research 60(3):445–59. doi:10.1080/00221686.2021.2004250.
  51. 2008. “WHO 2008.” WHO Library Cataloguing-in-Publication Data.
  52. Zheng, Hongmei, Shiwei Hou, Jing Liu, Yanna Xiong, and Yuxin Wang. 2024. “Advanced Machine Learning and Water Quality Index (WQI) Assessment: Evaluating Groundwater Quality at the Yopurga Landfill.” Water (Switzerland) 16(12). doi:10.3390/w16121666.
  53. Ayrilmis, N., Kanat, G., Yildiz Avsar, E., Palanisamy, S. and Ashori, A., 2025. Utilizing waste manhole covers and fibreboard as reinforcing fillers for thermoplastic composites. Journal of Reinforced Plastics and Composites, 44(17-18), pp.1108-1118.
  54. Almeshaal, M., Palanisamy, S., Murugesan, T.M., Palaniappan, M. and Santulli, C., 2022 Physico-chemical characterization of Grewia Monticola Sond (GMS) fibers for prospective application in biocomposites. Journal of Natural Fibers, 19(17), pp.15276-15290.
  55. Palanisamy, S., Mayandi, K., Palaniappan, M., Alavudeen, A., Rajini, N., Vannucchi de Camargo, F. and Santulli, C., 2021. Mechanical properties of Phormium tenax reinforced natural rubber composites. Fibers, 9(2), p.11.
  56. Ramasubbu, R., Kayambu, A., Palanisamy, S. and Ayrilmis, N., 2024. Mechanical Properties of Epoxy Composites Reinforced with Areca catechu Fibers Containing Silicon Carbide. BioResources, 19(2).
  57. Palanisamy, S., Mayandi, K., Dharmalingam, S., Rajini, N., Santulli, C., Mohammad, F. and Al- Lohedan, H.A., 2022. Tensile properties and fracture morphology of Acacia caesia bark fibers treated with different alkali concentrations. Journal of Natural Fibers, 19(15), pp.11258-11269.

 

 


Ahead of Print Subscription Original Research
Volume 14
04
Received 26/06/2026
Accepted 30/06/2026
Published 30/06/2026
Publication Time 4 Days


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