This is an unedited manuscript accepted for publication and provided as an Article in Press for early access at the author’s request. The article will undergo copyediting, typesetting, and galley proof review before final publication. Please be aware that errors may be identified during production that could affect the content. All legal disclaimers of the journal apply.
Sunny Nanade,
Zarvan Movdawalla,
- Assistant Professor, Department of Mechatronics Engineering, Mukesh Patel School of Technology Management & Engineering, SVKM’s NMIMS, Mumbai, Maharashtra, India
- Student, Department of Mechanical Engineering, Mukesh Patel School of Technology Management & Engineering, SVKM’s NMIMS, Mumbai, Maharashtra, India
Abstract
Acrylonitrile styrene acrylate (ASA) is an amorphous terpolymer with superior UV resistance compared to acrylonitrile butadiene styrene (ABS), as its acrylate rubber phase lacks photodegradation-prone carbon–carbon double bonds. This study proposes acetone solvent welding as a polymer joining method to produce monolithic structures from FDM-processed ASA components, addressing three processing challenges: achieving structural continuity through polymer chain interdiffusion at solvent-wetted interfaces, correcting thermal warping via post-print geometric correction during welding, and optimizing infill density distribution for maximum strength-to-weight ratio.
Two iterative frame designs were fabricated and tested using quadcopter flight testing as a structural loading platform. Frame 1 (450 g) employed solid (100%) infill landing gears with conventional infill elsewhere, while Frame 2 (443 g) used a strategic variable infill strategy (60–20%) with key layer orientation to exploit FDM polymer anisotropy. A novel warping correction method was developed: acetone-softened ASA components were clamped against a flat granite surface plate during solvent evaporation, achieving geometric correction as polymer chains interdiffused across bond interfaces.
Frame 1 failed structurally within 10 flights, while Frame 2 completed 40+ flights with no structural degradation, no acetone joint separation, and motor mount coplanarity within 0.1 mm tolerance. Despite a 1.5% weight reduction, the optimized design achieved approximately four times greater operational life, demonstrating that polymer volume fraction distribution and layer orientation optimization are superior to uniform high-density infill. These findings provide reproducible guidelines for solvent-welded ASA polymer structures and an effective warping-reduction process without heated build chambers.
Keywords: ASA polymer, Solvent welding, Acetone bonding, Polymer chain interdiffusion, Variable infill, Fused deposition modeling, Thermoplastic processing, Anisotropic polymer properties, Warping mitigation
Sunny Nanade, Zarvan Movdawalla. Structural Optimization of FDM-Processed ASA Polymer Frames through Acetone Solvent Welding, Variable Infill Strategy, and Layer Orientation: Experimental Validation via Quadcopter Flight Testing. Journal of Polymer & Composites. 2026; 14(03):-.
Sunny Nanade, Zarvan Movdawalla. Structural Optimization of FDM-Processed ASA Polymer Frames through Acetone Solvent Welding, Variable Infill Strategy, and Layer Orientation: Experimental Validation via Quadcopter Flight Testing. Journal of Polymer & Composites. 2026; 14(03):-. Available from: https://journals.stmjournals.com/jopc/article=2026/view=243564
References
- Ngo TD, Kashani A, Imbalzano G, Nguyen KTQ, Hui D. Additive manufacturing (3D printing): A review of materials, methods, applications and challenges. Compos Part B Eng. 2018;143:172-196.
- Scheirs J, Priddy D. Modern Styrenic Polymers: Polystyrenes and Styrenic Copolymers. Wiley; 2003. p. 341-355.
- Hameed AZ, Aravind Raj S, Kandasamy J, Shahzad MA, Baghdadi MA. 3D Printing parameter optimization using Taguchi approach to examine acrylonitrile styrene acrylate (ASA) mechanical properties. Polymers. 2022;14(16):3256.
- Wool RP, O’Connor KM. A theory of crack healing in polymers. J Appl Phys. 1981;52(10):5953-5963.
- Turner BN, Strong R, Gold SA. A review of melt extrusion additive manufacturing processes: II. Materials, dimensional accuracy, and surface roughness. Rapid Prototyp J. 2015;21(3):250-261.
- Fernandez-Vicente M, Calle W, Ferrandiz S, Conejero A. Effect of infill parameters on tensile mechanical behavior in desktop 3D printing. 3D Print Addit Manuf. 2016;3(3):183-192.
- Wu W, Geng P, Li G, Zhao D, Zhang H, Zhao J. Influence of layer thickness and raster angle on the mechanical properties of 3D-printed PEEK and a comparative mechanical study between PEEK and ABS. Materials. 2015;8(9):5834-5846.
- Azarov AV, Antonov FK, Golubev MV, Khaziev AR, Ushanov SA. Composite 3D printing for the small size unmanned aerial vehicle structure. Compos Part B Eng. 2019;169:157-163.
- Popescu D, Zapciu A, Amza C, Baciu F, Marinescu R. FDM process parameters influence over the mechanical properties of polymer specimens: A review. Polym Test. 2018;69:157-166.
- Ziemian S, Okwara M, Ziemian CW. Tensile and fatigue behavior of layered acrylonitrile butadiene styrene. Rapid Prototyp J. 2015;21(1):80-90.
- Tanikella NG, Wittbrodt B, Pearce JM. Tensile strength of commercial polymer materials for fused filament fabrication 3D printing. Addit Manuf. 2017;15:40-47.
- Rajan K, Samykano M, Kadirgama K, Harun WSW, Rahman MM. Fused deposition modeling: process, materials, parameters, properties, and applications. Int J Adv Manuf Technol. 2022;120:1531-1570.
- Nanade S, Gharat E, Lakhe A, Shah R. Evaluating chassis designs for gesture-driven robots: A study of iron, acrylic, and 3D printed solutions. J Polym Compos. 2025;13(S5):S686-S692.
- Kirubakaran G, Kannan CS, Anbalagan RR, Palanisamy S, Alfarraj SA, Alharbi SA, Abbas M, Kalathil S, Belay M. Taguchi-based experimental optimization coupled with explainable machine learning for predictive modelling of FFF-printed CF-PA composites. Int J Adv Manuf Technol. 2026. https://doi.org/10.1007/s00170-026-17709-2.
- Fitriyana DF, Rudianzah TS, Palanisamy S, Firmansyah HN, Darsono FB, Ismail R, Siregar JP, Cionita T, Alfarraj SA, Alharbi SA, Abbas M, Kalathil S, Belay M. Investigation of the effect of nozzle temperature on the properties of 3D printed PET filament from plastic bottle waste. Int J Adv Manuf Technol. 2026;142:4073-4085.
- Fitriyana DF, Palanisamy S, Wicaksana YS, Anis S, Rasgianti, Ismail R, Siregar JP, Cionita T, Prawisudha P, Nugraha FW, Irawan AP, Hadi AE. Mechanical performance analysis of a 3D printing-based transtibial prosthetic socket against the gait cycle using the finite element method. RSC Adv. 2025;15:24150-24166.
- Palanisamy S, Karuppiah G, Kumar P, Dharmalingam S, Mubarak S, Santulli C, Ayrilmis N, Karumuri S. Effect of process parameters and material selection on the quality of 3D printed products by fused deposition modeling (FDM): A review. Adv Polym Technol. 2024;2024:3480281.
- Kechagias JD, Ninikas K, Vakouftsi F, Fountas NA, Palanisamy S, Vaxevanidis NM. Optimization of laser beam parameters during processing of ASA 3D-printed plates. Int J Adv Manuf Technol. 2024;130:527-539.

Journal of Polymer & Composites
| Volume | 14 |
| 03 | |
| Received | 20/03/2026 |
| Accepted | 31/03/2026 |
| Published | 12/05/2026 |
| Publication Time | 53 Days |
Login
PlumX Metrics