This is an unedited manuscript accepted for publication and provided as an Article in Press for early access at the author’s request. The article will undergo copyediting, typesetting, and galley proof review before final publication. Please be aware that errors may be identified during production that could affect the content. All legal disclaimers of the journal apply.
V Ravi Raj,
M Dharani,
S Karthick,
G Ashwin Prabhu,
R B Senthilrajan,
R. Karthikeyan,
Jeriel Samuel J,
Madhan Kumar D,
- Associate Professor, Department of Mechanical Engineering, Sri Sairam Engineering College, Chennai, Tamil Nadu, India
- Lecturer, Department of Physics, Central Institute of Petrochemicals Engineering and Technology(CIPET), Thiruvathavur, Madurai, Tamil Nadu, India
- Assistant Professor, Department of Physics, Global Institute of Engineering and Technology, Melvisharam, Ranipet, Tamil Nadu, India
- Assistant Professor, Department of Mechanical Engineering, St. Joseph’s College of Engineering, Old Mahabalipuram Road, Chennai, Tamil Nadu, India
- Assistant Professor, Department of Chemistry, Sethu Institute of Technology, Pulloor, Kariapatti, Tamil Nadu, India
- Assistant Professor, Department of Automobile Engineering, Rajalakshmi Engineering College (Autonomous), Thandalam, Chennai, Tamil Nadu, India
- UG Student, Department of Mechanical Engineering, St. Joseph’s College of Engineering, Old Mahabalipuram Road, Chennai, Tamil Nadu, India
- UG Student, Department of Mechanical Engineering, St. Joseph’s College of Engineering, Old Mahabalipuram Road, Chennai, Tamil Nadu, India
Abstract
This study examines the synergistic impact of green nanofillers on the mechanical and structural properties of basalt–kenaf fiber reinforced polyester composites, with the objective of developing sustainable, high-performance polymer materials. The composites were produced with different fiber ratios: B1 (70% basalt, 30% kenaf), B2 (60% basalt, 40% kenaf), and B3 (50% basalt, 50% kenaf), and were reinforced with 1 wt.% green-synthesized nano-TiO2, obtained using an eco-friendly sol–gel technique with plant extracts. The use of nanofillers markedly improved the interfacial adhesion between fibers and the polyester matrix. B2 demonstrated superior performance among the formulations, attaining a tensile strength of 165 MPa, a flexural strength of 228 MPa, and an impact energy of 17.3 kJ/m², representing a 20–25% enhancement compared to the non-nano composites. The density diminished by 10%, indicating enhanced lightweight properties, while SEM analysis verified consistent nano-TiO2 distribution and diminished microvoid occurrence. The synergistic impact of high-strength basalt fibers, natural kenaf reinforcement, and eco-friendly nanofillers yielded an exceptional equilibrium between mechanical performance and environmental sustainability. The research finds that green nano-enhanced basalt–kenaf composites present a feasible, environmentally sustainable option for structural, automotive, and marine applications, in accordance with green engineering and circular economy principles.
Keywords: Basalt-Kenaf Hybrid Composites, Green Nanofillers, Nano-TiO2, Sustainable Polymer Composites, Mechanical Properties, Eco-Friendly Materials.
V Ravi Raj, M Dharani, S Karthick, G Ashwin Prabhu, R B Senthilrajan, R. Karthikeyan, Jeriel Samuel J, Madhan Kumar D. Synergistic Effect of Green Nanofillers on Basalt–Kenaf Reinforced Sustainable Polymer Composites. Journal of Polymer & Composites. 2026; 14(02):-.
V Ravi Raj, M Dharani, S Karthick, G Ashwin Prabhu, R B Senthilrajan, R. Karthikeyan, Jeriel Samuel J, Madhan Kumar D. Synergistic Effect of Green Nanofillers on Basalt–Kenaf Reinforced Sustainable Polymer Composites. Journal of Polymer & Composites. 2026; 14(02):-. Available from: https://journals.stmjournals.com/jopc/article=2026/view=240366
References
- Saha, A., Kumar, S., & Kumar, A. (2021). Influence of pineapple leaf particulate on mechanical, thermal and biodegradation characteristics of pineapple leaf fiber reinforced polymer composite. Journal of Polymer Research, 28(2), 66.
- Anand, P. B., Lakshmikanthan, A., Gowdru Chandrashekarappa, M. P., Selvan, C. P., Pimenov, D. Y., & Giasin, K. (2022). Experimental investigation of effect of fiber length on mechanical, wear, and morphological behavior of silane-treated pineapple leaf fiber reinforced polymer composites. Fibers, 10(7), 56.
- Saha, A., Kumar, S., Zindani, D., & Bhowmik, S. (2021). Micro-mechanical analysis of the pineapple-reinforced polymeric composite by the inclusion of pineapple leaf particulates. Proceedings of the institution of mechanical engineers, Part L: Journal of materials: design and applications, 235(5), 1112-1127.
- BA, P., P Shetty, B., N, V., HV, S., & Singh Yadav, S. P. (2022). Mechanical properties and water absorption behaviour of pineapple leaf fibre reinforced polymer composites. Advances in Materials and Processing Technologies, 8(2), 1336-1351.
- Deeban, B., Maniraj, J., & Ramesh, M. (2023). Experimental investigation of properties and aging behavior of pineapple and sisal leaf hybrid fiber-reinforced polymer composites. e-Polymers, 23(1), 20228104.
- Wondimu, A., Kebede, M., & Palani, S. (2022). Trash pineapple leaf fiber reinforced polymer composite materials for light applications. In Bio-fiber reinforced composite materials: mechanical, thermal and tribological properties(pp. 13-30). Singapore: Springer Nature Singapore.
- Prabhu, G.A., Selvam, R. & Kumar, K.M. Enhancing the Mechanical Properties of Basalt Fiber and Stainless Steel Wire Mesh Composites Incorporating Fire Retardants Through Response Surface Methodology Optimization. Fibers Polym 25, 1443–1455 (2024).
- Brucely, Y., Sahoo, M. R., Halder, S., Thiyagu, M., Kumar, A. S., & Parida, L. (2022). Investigating mechanical strength of luffa and pineapple fibre reinforced polymer composite. Materials Today: Proceedings, 69, 1300-1303.
- Subramanian PM, Balamurugan L, Ashwin Prabhu G. Novel approaches in developing sustainable and cost-effective semi-active suspension systems for smart vehicles – A review. Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical Engineering. 2024;0(0).
- Krishnakumar, S., Mohanavel, V., Venkatesh, R., & Balasubramanian, K. (2024). Enhancement of tribology behaviour by the addition of different fiber length of pineapple fiber reinforced polyester composite. Journal of mechanical science and technology, 38(1), 201-206.
- Ponsuriyaprakash, S., Udhayakumar, P., & Pandiyarajan, R. (2022). Experimental investigation of ABS matrix and cellulose fiber reinforced polymer composite materials. Journal of Natural Fibers, 19(9), 3241-3252.
- Alsubari, S., Zuhri, M. Y. M., Sapuan, S. M., Ishak, M. R., Ilyas, R. A., & Asyraf, M. R. M. (2021). Potential of natural fiber reinforced polymer composites in sandwich structures: A review on its mechanical properties. Polymers, 13(3), 423.
- Chandgude, S., & Salunkhe, S. (2021). In state of art: Mechanical behavior of natural fiber‐based hybrid polymeric composites for application of automobile components. Polymer Composites, 42(6), 2678-2703.
- Jawaid, M., Awad, S. A., Asim, M., Fouad, H., Alothman, O. Y., & Santulli, C. (2021). A comparative evaluation of chemical, mechanical, and thermal properties of oil palm fiber/pineapple fiber reinforced phenolic hybrid composites. Polymer Composites, 42(12), 6383-6393.
- Murugapoopathi, S., Ashwin Prabhu, G., Chandrasekar, G. et al. Fabrication and Characterisation of Saw Dust Polymer Composite. J. Inst. Eng. India Ser. D (2023).
- Ng, L. F., Yahya, M. Y., & Muthukumar, C. (2022). Mechanical characterization and water absorption behaviors of pineapple leaf/glass fiber‐reinforced polypropylene hybrid composites. Polymer Composites, 43(1), 203-214.
- Sayeed, M. A., Sayem, A. S. M., Haider, J., Akter, S., Habib, M. M., Rahman, H., & Shahinur, S. (2023). Assessing mechanical properties of jute, kenaf, and pineapple leaf fiber-reinforced polypropylene composites: Experiment and modelling. Polymers, 15(4), 830.
- Prabhu, G. A., Pattanashetty, G., Arun, K., Sivashanmugam, N., Prasad, C. R., Hemanandh, J., … & Gopiraj, R. R. (2025). Evaluating the Mechanical Properties and Microstructure of Basalt-Kenaf Polyester Composites with Cellulose Fillers. Journal of The Institution of Engineers (India): Series D, 1-16.
- Dhinesh, S. K., Arun, P. S., Senthil, K. K., & Megalingam, A. (2021). Study on flexural and tensile behavior of PLA, ABS and PLA-ABS materials. Materials Today: Proceedings, 45, 1175-1180.
- Han, S. N. M. F., Taha, M. M., Mansor, M. R., & Rahman, M. A. A. (2022). Investigation of tensile and flexural properties of kenaf fiber-reinforced acrylonitrile butadiene styrene composites fabricated by fused deposition modeling. Journal of Engineering and Applied Science, 69(1), 52.
- Appusamy, A. M., Nanjappan, N., Eswaran, P., & Subramanian, M. (2022). The effect of natural Gongura roselle fiber on the mechanical properties of 3D printed ABS and PLA composites. Polimery, 67(3), 119-124.
- Prabhu, G.A., Tembhekar, T.D., Gopal, V. et al. Utilizing Machine Learning for Optimizing Composite Materials Derived from Leather Trimming and HDPE Waste. J. Inst. Eng. India Ser. D (2025).
- Dixit, N., & Jain, P. K. (2021). 3D printed carbon fiber reinforced thermoplastic composites: A review. Materials Today: Proceedings, 43, 678-681.
- Shirasu, K., Yamaguchi, Y., Hoshikawa, Y., Kikugawa, G., Tohmyoh, H., & Okabe, T. (2024). Micromechanics study of short carbon fiber-reinforced thermoplastics fabricated via 3D printing using design of experiments. Materials Science and Engineering: A, 891, 145971.
- Stalin, B., Arivukkarasan, S., & Prabhu, G. A. (2015). Microstructure and mechanical properties evaluation of aluminium matrix reinforced with tungsten carbide and silicon carbide. International Journal of Applied Engineering Research, 10(55), 3994-3999.
- Ahmad, M. N., Ishak, M. R., Taha, M. M., Mustapha, F., & Leman, Z. (2023). Mechanical, thermal and physical characteristics of oil palm (Elaeis Guineensis) fiber reinforced thermoplastic composites for FDM–Type 3D printer. Polymer Testing, 120, 107972.
- Huang, Y., Tian, X., Zheng, Z., Li, D., Malakhov, A. V., & Polilov, A. N. (2022). Multiscale concurrent design and 3D printing of continuous fiber reinforced thermoplastic composites with optimized fiber trajectory and topological structure. Composite Structures, 285, 115241.
- Yamamoto, K., Luces, J. V. S., Shirasu, K., Hoshikawa, Y., Okabe, T., & Hirata, Y. (2022). A novel single-stroke path planning algorithm for 3D printers using continuous carbon fiber reinforced thermoplastics. Additive Manufacturing, 55, 102816.
- Natarajan, Eswara Prasath, Rasu, Karthick, Murugesan, Vigneshkumar and Gnanasekaran, Ashwin Prabhu. “Effect of basalt and kenaf fiber hybridization on the physical, mechanical, and thermal properties of polymer composites” Materials Testing, vol. 67, no. 11, 2025, pp. 1860-1869.
- Masoudi, M. (2025). Biochar Based Composite Material: Study of Mechanical and Physicochemical Properties(Doctoral dissertation).
- Koriem, A. A., Abd El-Aziz, M. E., Salem, S. R., Hussain, A. I., & Turky, G. (2023). Management of agricultural waste to manufacture biochar: An alternative reinforcing filler for carbon black in nitrile butadiene rubber composites. Journal of Cleaner Production, 428, 139360.
- Minugu, O. P., Gujjala, R., Shakuntala, O., Manoj, P., & Chowdary, M. S. (2021). Effect of biomass derived biochar materials on mechanical properties of biochar epoxy composites. Proceedings of the Institution of Mechanical Engineers, Part C: Journal of Mechanical Engineering Science, 235(21), 5626-5638.
- Khilji, I. A., Chilakamarry, C. R., Surendran, A. N., Kate, K., & Satyavolu, J. (2023). Natural fiber composite filaments for additive manufacturing: a comprehensive review. Sustainability, 15(23), 16171.
- Adapa, S. K., & Jagadish. (2023). Prospects of natural fiber-reinforced polymer composites for additive manufacturing applications: a review. Jom, 75(3), 920-940.
- Rao, H. J., Nagabhooshanam, N., Kumar, D. S., Sahu, S. K., Verma, R., Jyothirmai, G., … & Mohanavel, V. (2023). Dynamic mechanical, ballistic and tribological behavior of luffa aegyptiaca fiber reinforced coco husk biochar epoxy composite. Polymer Composites, 44(3), 1911-1918.
- Ashwin Prabhu, G., Selvam, R., Tiwari, V. et al. Optimizing hybrid composites: Enhancing mechanical properties with SiC and Al2O3 nanoparticles using response surface methodology. J. Mater. Res. 40, 2723–2734 (2025).
- de Souza, P. H. C., Rocha, S. D. F., & de Rezende, D. B. (2023). Luffa cylindrica slow pyrolysis and solar pyrolysis: impact of temperature and heating rate on biochar properties and iodine adsorption performance. Waste and Biomass Valorization, 14(5), 1753-1768.
- Mazur, K. E., Borucka, A., Kaczor, P., Gądek, S., Bogucki, R., Mirzewiński, D., & Kuciel, S. (2022). Mechanical, thermal and microstructural characteristic of 3D printed polylactide composites with natural fibers: wood, bamboo and cork. Journal of Polymers and the Environment, 30(6), 2341-2354.
- Olcun, S., Ibrahim, Y., Isaacs, C., Karam, M., Elkholy, A., & Kempers, R. (2023). Thermal conductivity of 3D-printed continuous pitch carbon fiber composites. Additive Manufacturing Letters, 4, 100106.
- Carcassi, O. B., Maierdan, Y., Akemah, T., Kawashima, S., & Ben-Alon, L. (2024). Maximizing fiber content in 3D-printed earth materials: Printability, mechanical, thermal and environmental assessments. Construction and Building Materials, 425, 135891.
- Karuppiah, G., Kuttalam, K. C., Palaniappan, M., Santulli, C., & Palanisamy, S. (2020). Multiobjective optimization of fabrication parameters of jute fiber/polyester composites with egg shell powder and nanoclay filler. Molecules, 25(23), 5579.
- Santulli, C., Palanisamy, S., & Kalimuthu, M. (2022). Pineapple fibers, their composites and applications. In Plant Fibers, their Composites, and Applications(pp. 323-346). Woodhead Publishing.
- Goutham, E. R. S., Hussain, S. S., Muthukumar, C., Krishnasamy, S., Kumar, T. S. M., Santulli, C., … & Jesuarockiam, N. (2023). Drilling parameters and post-drilling residual tensile properties of natural-fiber-reinforced composites: A review. Journal of Composites Science, 7(4), 136.
- Ayrilmis, N., Kanat, G., Yildiz Avsar, E., Palanisamy, S., & Ashori, A. (2025). Utilizing waste manhole covers and fibreboard as reinforcing fillers for thermoplastic composites. Journal of Reinforced Plastics and Composites, 44(17-18), 1108-1118.
- Aruchamy, K., Karuppusamy, M., Krishnakumar, S., Palanisamy, S., Jayamani, M., Sureshkumar, K., … & Al-Farraj, S. A. (2025). Enhancement of Mechanical Properties of Hybrid Polymer Composites Using Palmyra Palm and Coconut Sheath Fibers: The Role of Tamarind Shell Powder. BioResources, 20(1).
- Palanisamy, S., Mayandi, K., Dharmalingam, S., Rajini, N., Santulli, C., Mohammad, F., & Al-Lohedan, H. A. (2022). Tensile properties and fracture morphology of Acacia caesia bark fibers treated with different alkali concentrations. Journal of Natural Fibers, 19(15), 11258-11269.

Journal of Polymer & Composites
| Volume | 14 |
| 02 | |
| Received | 08/01/2026 |
| Accepted | 28/01/2026 |
| Published | 20/04/2026 |
| Publication Time | 102 Days |
Login
PlumX Metrics