Combustion Synthesis and Comprehensive Characterization of Pure and Ni-Doped CuFe₂O₄ Nanoparticles for Functional Composite Applications

Year : 2026 | Volume : 14 | Issue : 02 | Page : 1 11
    By

    A. Selvaraj,

  • M. Sundararajan,

  • S. Nandhini,

  • S. Yuvaraj,

  • Chandra Sekhar Dash,

  • Jagadeesh Kumar Alagarasan,

  • Arun Thirumurugan,

  • Gabriela Sandoval Hevia,

  • Tejaswi Ashok Hegde,

  • P Aji Udhaya,

  1. Assistant Professor, Department of Mathematics, Vel Tech Rangarajan Dr. Sagunthala R&D Institute of Science and Technology, Vel Nagar, Avadi, Chennai, Tamil Nadu, India
  2. Assistant Professor, Department of Physics, Paavendhar College of Arts & Science, M.V. South, Thalaivasal, Salem, Tamil Nadu, India
  3. Research Scholar, Department of Physics, Vel Tech Rangarajan Dr. Sagunthala R&D Institute of Science and Technology, Vel Nagar, Avadi, Chennai, Tamil Nadu, India
  4. Research Scholar, Department of Physics, Vel Tech Rangarajan Dr. Sagunthala R&D Institute of Science and Technology, Vel Nagar, Avadi, Chennai, Tamil Nadu, India
  5. Associate Professor, Department of Electronics and Communication Engineering, Centurion University of Technology and Management, Odisha, Bhubaneswar, Odisha, India
  6. Associate Professor, Department of Chemistry, Faculty of Science, Technology and Architecture (FoSTA), Manipal University Jaipur, Rajasthan, India
  7. Assistant Professor, Department of Chemistry, Vallenar Campus, University of Atacama, 105 Costanera, Avenue Vallenar 1612178, Chile
  8. Associate Professor, Department of Chemistry, Metropolitan Technological University, Santiago, 7800002, Chile
  9. Assistant Professor, Department of Physics, Hindustan Institute of Technology and Science, Chennai, Tamil Nadu, India
  10. Assistant Professor, Department of Physics, Holy Cross College, Nagercoil, Tamil Nadu, India

Abstract

The CuFe2-xNixO4 (x = 0, 0.1, 0.3, and 0.5) nanoparticles were synthesized using a combustion method and comprehensively characterized to understand their suitability for polymer-based composite applications. X-ray diffraction confirmed the formation of a single-phase spinel ferrite structure with crystallite sizes of 20–30 nm. Energy-dispersive X-ray spectroscopy verified the successful incorporation of Ni ions into the CuFe₂O₄ lattice, while FE-SEM analysis revealed uniformly dispersed nanoscale particles desirable for composite reinforcement. Optical characterization showed a gradual reduction in band gap energy from 1.81 to 1.75 eV with increasing Ni content, indicating enhanced electronic interactions that can contribute to improved functional performance in polymer matrices. FT-IR spectra further validated the structural stability of the Ni-substituted ferrites through characteristic metal–oxygen stretching vibrations. The tunable structural and optical properties of CuFe2-xNixO4 nanoparticles highlight their potential as promising fillers for multifunctional polymer and hybrid composite materials.

Keywords: CuFe2O4, combustion method, structural, band gap, composite applications

[This article belongs to Journal of Polymer & Composites ]

How to cite this article:
A. Selvaraj, M. Sundararajan, S. Nandhini, S. Yuvaraj, Chandra Sekhar Dash, Jagadeesh Kumar Alagarasan, Arun Thirumurugan, Gabriela Sandoval Hevia, Tejaswi Ashok Hegde, P Aji Udhaya. Combustion Synthesis and Comprehensive Characterization of Pure and Ni-Doped CuFe₂O₄ Nanoparticles for Functional Composite Applications. Journal of Polymer & Composites. 2026; 14(02):1-11.
How to cite this URL:
A. Selvaraj, M. Sundararajan, S. Nandhini, S. Yuvaraj, Chandra Sekhar Dash, Jagadeesh Kumar Alagarasan, Arun Thirumurugan, Gabriela Sandoval Hevia, Tejaswi Ashok Hegde, P Aji Udhaya. Combustion Synthesis and Comprehensive Characterization of Pure and Ni-Doped CuFe₂O₄ Nanoparticles for Functional Composite Applications. Journal of Polymer & Composites. 2026; 14(02):1-11. Available from: https://journals.stmjournals.com/jopc/article=2026/view=236830


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References

  1. Acharya P, Desai R, Aswal VK, et al. Structure of Co–Zn ferrite ferrofluid: a small angle neutron scattering analysis. J. Phys. 2008; 71: 1069–1074p.
  2. Emadi H., Mobarak H. Synthesis and characterization of copper ferrite nanoparticles and its application as MRI contrast agent. Lett. Appl. Nano Bio Sci. 2019; 8(1): 541–544p.
  3. Yue Z, Zhou J, Li L, et al. Effect of copper on the electromagnetic properties of Mg–Zn–Cu ferrites prepared by sol–gel auto-combustion method. Mater. Sci. Eng. B. 2001; 86(1): 64–69p.
  4. Srikanth K, Nutalapati V. Copper ferrite nanoparticles induced cytotoxicity and oxidative stress in Channel catfish ovary cells. Chemosphere. 2022; 287: 132166p.
  5. Gautam S, Charak R, Garg S, et al. Tailoring magnetism in chromium-doped zinc cobalt ferrite nanostructure for advanced spintronic memory devices. Mater. Today Chem. 2024; 41: 102291p.
  6. Alqassem B, Banat F, Palmisano G, et al. Emerging trends of ferrite-based nanomaterials as photocatalysts for environmental remediation: A review and synthetic perspective. Sustain. Mater. Technol. 2024; e00961p.
  7. Masunga N, Mamba BB, Getahu YW, et al. Synthesis of single-phase superparamagnetic copper ferrite nanoparticles using an optimized coprecipitation method. Mater. Sci. Eng. B 2021; 272: 115368p.
  8. Sundararajan M, Kennedy LJ, Vijaya JJ, et al. Microwave combustion synthesis of Co₁₋ₓZnₓFe₂O₄ (0 ≤ x ≤ 0.5): Structural, magnetic, optical and vibrational spectroscopic studies. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2015; 140: 421–430p.
  9. Mathew D.S., Juang R.S. An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions. Chem. Eng. J. 2007; 129(1–3): 51–65p.
  10. Noreen S, Hussain A. Structural, optical, morphological and magnetic properties of Cu₀.₂₅M₀.₇₅Fe₂O₄ (M = Mn, Mg, Ni and Co) ferrites for optoelectronic applications. Opt. Mater. 2023; 139: 113797p.
  11. Masunga N, Mamba BB, Kefeni KK. Improved magnetic, optical, electrochemical, and structural properties of copper ferrite through optimized addition of samarium dopant using the co-precipitation method. Mater. Sci. Eng. B 2023; 296: 116662p.
  12. Gingaşu D, Mîndru I, Patron L, Carp O, et al. Copper ferrite obtained by two “soft chemistry” routes. J. Alloys Compd. 2006; 425(1–2): 357–361p.
  13. Karakaş ZK. A comprehensive study on the production and photocatalytic activity of copper ferrite nanoparticles synthesized by microwave-assisted combustion method as an effective photocatalyst. J. Phys. Chem. Solids 2022; 170: 110927p.
  14. Meng X, Xu W, Ren X, et al. Progress and challenges of ferrite matrix microwave absorption materials. Materials 2024; 17(10): 2315p.
  15. Sukumar M, Rajabathar JR, Lohedan HAL, et al. Synthesize and characterization of copper doped nickel ferrite nanoparticles effect on magnetic properties and visible light catalysis for rhodamine dye degradation mechanism. J. Alloys Compd. 2023; 953: 169902p.
  16. Bashaa DB, Dahiyaa D, Veena E. Dielectric and magnetic properties of zinc copper ferrite nanoparticles. J. Ovonic Res. 2021; 17(6): 589–594p.
  17. Sundararajan M, Kennedy LJ, Aruldoss U, et al. Microwave combustion synthesis of zinc substituted nanocrystalline spinel cobalt ferrite: Structural and magnetic studies. Mater. Sci. Semicond. Process. 2015; 40(1): 1–10p.
  18. Revathi R, Sukumar M, Kumar A, et al. Facile synthesis of Ni²⁺-doped MgFe₂O₄ spinel nanoparticles: Structural, optical, magnetic, and dielectric behavior. J. Inorg. Organomet. Polym. 2024; 34: 374–386p.
  19. Patterson AL. The Scherrer formula for X-ray particle size determination. Phys. Rev. 1939; 56(10): 978–982p.
  20. Razik NA. Precise lattice constants determination of cubic crystals from x-ray powder diffractometric measurements. Appl. Phys. A 1985; 37: 187–189p.
  21. Dhiwahar AT, Sundararajan M, Sakthivel P, et al. Microwave-assisted combustion synthesis of pure and zinc-doped copper ferrite nanoparticles: Structural, morphological, optical, vibrational, and magnetic behavior. J. Phys. Chem. Solids 2019; 138: 109257p.
  22. Abbas YM, Mansour SA, Ibrahim MH, et al. Microstructure characterization and cation distribution of nanocrystalline cobalt ferrite. J. Magn. Magn. Mater. 2011; 323(22): 2748–2756p.
  23. Mahajan H, Godara SK, Srivastava AK. Synthesis and investigation of structural, morphological, and magnetic properties of manganese-doped cobalt–zinc spinel ferrite. J. Alloys Compd. 2022; 896: 162966p.
  24. Noreen S, Hussain A. Structural, optical, morphological and magnetic properties of Cu₀.₂₅M₀.₇₅Fe₂O₄ (M = Mn, Mg, Ni and Co) ferrites for optoelectronic applications. Opt. Mater. 2023; 139: 113797p.
  25. Baskar S, Yuvaraj S, Sundararajan M, et al. Influence of Ca²⁺ ion substitution on structural, morphological, optical, thermal and magnetic behaviour of Mg₁₋ₓCaₓFe₂O₄ (0 ≤ x ≤ 0.5) spinel. J. Supercond. Nov. Magn. 2020; 33: 3949–3956p.
  26. Sundararajan M, Kennedy LJ, Vijaya JJ, et al. Microwave combustion synthesis of Co₁−ₓZnₓFe₂O₄ (0 ≤ x ≤ 0.5): Structural, magnetic, optical and vibrational spectroscopic studies. Spectrochim. Acta A Mol. Biomol. Spectrosc. 2015; 140(1): 421–430p.
  27. Sundararajan M, Sukumar M, Dash CS, et al. A comparative study on NiFe₂O₄ and ZnFe₂O₄ spinel nanoparticles: Structural, surface chemistry, optical, morphology and magnetic studies. Physica B Condens. Matter 2022; 644: 414232p.
  28. Rosa JC, Segarra M. Optimization of the synthesis of copper ferrite nanoparticles by a polymer-assisted sol–gel method. ACS Omega 2019; 4(19): 18289–18298p.
  29. Subhashini N, Revathi S, Ubaidullah M, et al. Gd³⁺ substituted BiFeO₃ perovskite nanoparticles: facile synthesis, characterization and applications in heterogeneous catalysis. Dalton Trans. 2023; 52: 2735p.
  30. Sundararajan M, Kennedy LJ. Photocatalytic removal of rhodamine B under visible light using Co₁−ₓCuₓFe₂O₄ (0 ≤ x ≤ 0.5) nanoparticles. J. Environ. Chem. Eng. 2017; 5(4): 4075–4092p.
  31. Mathankumar K, Sukumar M, Dash CS, et al. Facile synthesis, characterization, catalytic and photocatalytic activity of multiferroic BiFeO₃ perovskite nanoparticles. J. Inorg. Organomet. Polym. 2022; 32: 3476–3487p.
  32. Chatterjee BK, Bhattacharjee K, Dey A, et al. Influence of spherical assembly of copper ferrite nanoparticles on magnetic properties: orientation of magnetic easy axis. Dalton Trans. 2024; 43: 7930–7944p.
  33. Tedjieukeng HMK, Tsobnang PK, Fomekong RL, et al. Structural characterization and magnetic properties of undoped and copper-doped cobalt ferrite nanoparticles prepared by the octanoate coprecipitation route at very low dopant concentrations. RSC Adv. 2018; 8: 38621–38630p.
  34. Kherrouba N, Bouamer A. Magnetic, optical, structural and thermal properties of copper ferrite nanostructured synthesized by mechanical alloying. Micro Nano Lett. 2021; 16(4): 251–256p.

Regular Issue Subscription Original Research
Volume 14
Issue 02
Received 22/12/2025
Accepted 09/01/2026
Published 11/02/2026
Publication Time 51 Days


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