Mamta Gour,
Deepti Pal,
Renu Hada,
Shalini Sharma,
Vishwajeet Yadav,
- Assistant Professor, Department of Chemistry, Medicaps University, Indore, Madhya Pradesh, India
- Assistant Professor, Department of Chemistry, Medicaps University, Indore, Madhya Pradesh, India
- Assistant Professor, Department of Chemistry, Medicaps University, Indore, Madhya Pradesh, India
- Assistant Professor, Department of Chemistry, Medicaps University, Indore, Madhya Pradesh, India
- Assistant Professor, Department of Chemistry, Sandipani Arts and Science College, Jeerapur, Madhya Pradesh, India
Abstract
The growing accumulation of synthetic polymeric waste, especially plastics, has become one of the most pressing environmental challenges due to their non-biodegradable nature and long-lasting presence in ecosystems. This issue is compounded by the widespread use of plastic materials in various industries, resulting in vast amounts of plastic waste that contribute to environmental pollution, clog waterways, and pose threats to wildlife. As global plastic production continues to rise, the need for effective waste management solutions has never been more urgent. In recent years, catalytic degradation has emerged as a promising and sustainable approach for managing polymer waste, offering an energy-efficient alternative to traditional recycling methods. This process involves using catalysts to break down plastics into smaller, valuable products, including fuels and chemicals, reducing their environmental impact. This study explores the use of steel oxide catalysts, specifically zinc oxide (ZnO) and copper oxide (CuO), for the catalytic degradation of common polymers such as polyethylene (PE), polypropylene (PP), and polystyrene (PS). These polymers are widely used in packaging, consumer goods, and industrial applications, but their resistance to natural degradation makes them persistent environmental pollutants. The research investigates the degradation performance of ZnO and CuO, examining their efficiency in breaking down these plastics, the underlying degradation mechanisms, and the environmental implications of their use in waste management. ZnO and CuO were chosen for their thermal stability, redox properties, and cost-effectiveness, making them viable candidates for large-scale applications.
Keywords: Polymer degradation, ZnO, CuO, metal oxides, catalysis.
[This article belongs to Special Issue under section in Journal of Polymer & Composites (jopc)]
Mamta Gour, Deepti Pal, Renu Hada, Shalini Sharma, Vishwajeet Yadav. Catalytic Degradation of Polymers Using Metal Oxides (Zno, Cuo): A Sustainable Approach. Journal of Polymer & Composites. 2025; 13(06):1052-1062.
Mamta Gour, Deepti Pal, Renu Hada, Shalini Sharma, Vishwajeet Yadav. Catalytic Degradation of Polymers Using Metal Oxides (Zno, Cuo): A Sustainable Approach. Journal of Polymer & Composites. 2025; 13(06):1052-1062. Available from: https://journals.stmjournals.com/jopc/article=2025/view=226982
References
- Ahmaruzzaman, M., 2023. Metal oxides (ZnO, CuO and NiO)-based nanostructured substances for photocatalytic remediation of natural contaminants. Nanotechnology for Environmental Engineering, 8(1), pp.219-235.
- Ahmed, M.A., Mahmoud, S.A. And Mohamed, A.A., 2025. Interfacially engineered metallic oxide nanocomposites for more desirable photocatalytic degradation of pollutants and strength packages. RSC advances, 15(20), pp.15561-15603.
- Ashar, A., Bhatti, I.A., Jilani, A., Mohsin, M., Rasul, S., Iqbal, J., Shakoor, M.B., Al-Sehemi, A.G., Wageh, S. And Al-Ghamdi, A.A., 2021. Enhanced sun photocatalytic reduction of Cr (VI) using a (ZnO/CuO) nanocomposite grafted onto a polyester membrane for wastewater treatment. Polymers, thirteen(22), p.4047.
- Ashar, A., Bhatti, I.A., Jilani, A., Mohsin, M., Rasul, S., Iqbal, J., Shakoor, M.B., Al-Sehemi, A.G., Wageh, S. And Al-Ghamdi, A.A., 2021. Enhanced solar photocatalytic discount of Cr (VI) the usage of a (ZnO/CuO) nanocomposite grafted onto a polyester membrane for wastewater remedy. Polymers, 13(22), p.4047.
- Bano, K., Kaushal, S., Lal, B., Joshi, S.K., Kumar, R. And Singh, P.P., 2023. Fabrication of CuO/ZnO heterojunction photocatalyst for green photocatalytic degradation of tetracycline and ciprofloxacin below direct solar light. Environmental Nanotechnology, Monitoring & Management, 20, p.100863.
- Bassie Gelaw, T., Kunhana Sarojini, B. And Krishna Kodoth, A., 2021. Review of the Advancements on Polymer/Metal Oxide Hybrid Nanocomposite‐Based Adsorption Assisted Photocatalytic Materials for Dye Removal. ChemistrySelect, 6(34), pp.9300-9310.
- Bassie Gelaw, T., Kunhana Sarojini, B. And Krishna Kodoth, A., 2021. Review of the Advancements on Polymer/Metal Oxide Hybrid Nanocomposite‐Based Adsorption Assisted Photocatalytic Materials for Dye Removal. ChemistrySelect, 6(34), pp.9300-9310.
- Borjigin, T., Schmitt, M., Morlet-Savary, F., Xiao, P. And Lalevée, J., 2022. Low-fee and recyclable photocatalysts: metal oxide/polymer composites carried out in the catalytic breakdown of dyes. Photochem, 2(three), pp.733-751.
- Danish, M.S.S., Estrella, L.L., Alemaida, I.M.A., Lisin, A., Moiseev, N., Ahmadi, M., Nazari, M., Wali, M., Zaheb, H. And Senjyu, T., 2021. Photocatalytic applications of metallic oxides for sustainable environmental remediation. Metals, eleven(1), p.80.
- Danish, M.S.S., Estrella, L.L., Alemaida, I.M.A., Lisin, A., Moiseev, N., Ahmadi, M., Nazari, M., Wali, M., Zaheb, H. and Senjyu, T., 2021. Photocatalytic applications of metal oxides for sustainable environmental remediation. Metals, 11(1), p.80.
- Das, T.K., Jesionek, M., Çelik, Y. And Poster, A., 2023. Catalytic polymer nanocomposites for environmental remediation of wastewater. Science of the Total Environment, 901, p.165772.
- Jeevarathinam, M. And Asharani, I.V., 2024. Synthesis of CuO, ZnO nanoparticles, and CuO-ZnO nanocomposite for enhanced photocatalytic degradation of Rhodamine B: a comparative examine. Scientific Reports, 14(1), p.9718.
- Kumar, R., 2023. Metal Oxides‐Based Nano/Microstructures for Photodegradation of Microplastics. Advanced Sustainable Systems, 7(6), p.2300033.
- Maurya, A.K., Gogoi, R. And Manik, G., 2022. Polymer-based totally nanocomposites for removal of pollutants from distinct environments and the use of catalytic degradation. In Advances in Nanocomposite Materials for Environmental and Energy Harvesting Applications (pp. 331-368). Cham: Springer International Publishing.
- Pandey, B., Singh, P. And Kumar, V., 2021. Photocatalytic-sorption techniques for the removal of pollution from wastewater using polymer metal oxide nanocomposites and related environmental dangers. Environmental Nanotechnology, Monitoring & Management, sixteen, p.100596.
- Serouti, A., Eddine, L.S., Meneceur, S., Hasan, G.G., Mohammed, H.A., Salmi, C., Iman, K., Ferhat, M.F., Ali, O.B. And Abdullah, J.A.A., 2024. Biogenic ZnO/CuO/Fe2O3 nanocomposite: a groundbreaking technique for stronger degradation talents and reusability in dye elimination applications. Arabian Journal for Science and Engineering, forty nine(1), pp.753-764.
- Danish, M.S.S., Estrella, L.L., Alemaida, I.M.A., Lisin, A., Moiseev, N., Ahmadi, M., Nazari, M., Wali, M., Zaheb, H. and Senjyu, T., 2021. Photocatalytic applications of metal oxides for sustainable environmental remediation. Metals, 11(1), p.80.
- Shinde, R.S., Khairnar, S.D., Patil, M.R., Adole, V.A., Koli, P.B., Deshmane, V.V., Halwar, D.K., Shinde, R.A., Pawar, T.B., Jagdale, B.S. And Patil, A.V., 2022. Synthesis and characterization of ZnO/CuO nanocomposites as a powerful photocatalyst and gasoline sensor for environmental remediation. Journal of Inorganic and Organometallic Polymers and Materials, pp.1-22.
- Tabet, A., Meneceur, S., Laouini, S.E., Salmi, C., Mohammed, H.A., Kir, I., Hasan, G.G., Alharthi, F. And Abdullah, J.A.A., 2024. One submit biosynthesis of novel ternary nanocomposite ZnO/CuO/Cu2MgO3 for reinforcing photocatalytic degradation of bromocresol inexperienced in wastewater. Journal of Cluster Science, 35(three), pp.765-777.
- Tran, V.V., Nu, T.T.V., Jung, H.R. And Chang, M., 2021. Advanced photocatalysts primarily based on conducting polymer/metal oxide composites for environmental applications. Polymers, thirteen(18), p.3031.
- Ullah, S., Bukhari, S.A.B., Nasir, H., Akhtar, T., Mahboob, S. And Zahid, M., 2024. Efficient photocatalytic degradation of profenofos by means of CuO-ZnO nanocomposite. Journal of Photochemistry and Photobiology A: Chemistry, 455, p.115787.

Journal of Polymer & Composites
| Volume | 13 |
| Special Issue | 06 |
| Received | 28/05/2025 |
| Accepted | 12/07/2025 |
| Published | 12/09/2025 |
| Publication Time | 107 Days |
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