Composition and Structure of Oil finishing agent †

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Year : 2024 | Volume : | : | Page : –
By
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indra Neel Pulidindi,

  1. Scientific Consultant, Scientific Consultancy for Industrial and Academic Research (JSCIAR), Tharamani, Tamil Nadu, India

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Use of oil finishing agent is widely used in the process of production of carbon fibers to impart unusual and exceptional strength to the carbon fibers, the key load-bearing component, of the advanced materials, namely, carbon fiber reinforced composites (CFRPs). CFRPs are being widely used in the realm of aeronautics, astronautics, aeronautics, geonautics, sports equipment, and many more. However, quite often, much of the knowledge on the composition of oil finishing agents is concealed owing to the commercial relevance of the material. The subject of the chemical composition of oil finishing agents is seldom found in open literature as it is a proprietary material. Oil finishing agent imparts excellentstrengthh to carbon fibers. The oil finishing agent mainly comprises three components, namely, the epoxy/amino polyether-modified silicone, a non-volatile compound (diluent), and a surfactant. Characterization and analysis of the composition of oil agents are complicated and even experienced chemists are misleading owing to the ingenuity with which the oil finishing agent is formulated. NMR (1H, 13C, and 29Si) and FT-IR spectroscopy were judiciously used to find that the oil finishing agent is composed of lactic acid (3H, d; 0.81 and 1.21 ppm); formate type anions (1H, s; 8.3 ppm); organic silicone compounds [epoxy polyether-modified silicone; hexamethyldisilazane (HMDS)], a unique and unconventional methanol –dioxane complex used as a non-volatile solvent or diluent (dioxane also serves as surfactant). The presence of four characteristic signals at – 109.12, -22.42, – 19.6,2, and 7.17 ppm in the 29Si NMR spectrum of thoil-finishing agent indicated the presence of Si in four different chemical environments in the form of hexamethyl disiloxane (HMDS) and epoxy polyether-modified silicone. Such a result is further supported by the 1H NMR, 13C NMR, and FT-IR studies. Thus the mysterious chemical composition of the oil finishing agent is disclosed.

Keywords: Oil finishing agent; oil agent; methanol – dioxane complex; diluent; epoxy polyether modified poly organo siloxanes; lactic acid; NMR; FT-IR

How to cite this article:
indra Neel Pulidindi. Chemical composition of oil finishing agent used in the production of cartbon fibers for imprating unusual strength†. International Journal of Crystalline Materials. 2024; ():-.
How to cite this URL:
indra Neel Pulidindi. Chemical composition of oil finishing agent used in the production of cartbon fibers for imprating unusual strength†. International Journal of Crystalline Materials. 2024; ():-. Available from: https://journals.stmjournals.com/ijcm/article=2024/view=0

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References
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  1. Nakayama, T., Hashimoto, Y., Nakagawa, M., Oil agent for acrylic fibers for production of carbon fibers, acrylic fibers for production of carbon fibers, and method for producing carbon fibers. Matsumoto Yushi – Seiyaku Co Ltd., WO2010/140488 A1, 09/12/2010.
  2. Kobayashi, M., Ise, M., Yamazaki, K., Goto, H., Silicone straight oil finishing agent, precursor fiber for carbon fiber, carbon fiber and their production. Toray Industries Inc. JP2000136485 A, 16/05/2000.
  3. Xu, C.S., OuYang, L., Liu, H.Y., Chen, Q.W., Cai, Z.S., Xing, J.W., Synthesis of blocking polyether silicone oil and silicone blocking waterborne polyurethane and application to cashmere knitted fabric finishing. Textile Research Journal, 85 (19), 2015, 2040–50.
  4. Ma, Y.J., Wang, P., Wang, Q.M., Ding, F.M., Preparation of nano-SiO2 polyacrylate fluorine-free anti-fouling finishing agent and its application on cotton fabric. Industrial Crops & Products, 222 (2024) 119945.
  5. Li, Q., Fan, Z.L., Chen, C.X., Li, Z.B., Water and oil repellent properties affected by the crystallinity of fluorocarbon chain in fluorine-silicon containing finishing agent. The Journal of the Textile Institute, 111 (3), 2020, 360–369.
  6. Sui, Z.H., Guo, Z.A., Li, Y.P., Zhang, Q., Zu, B., Zhao, X., Study on preparation and performance of multifunctional linen fabric finishing agent. Textile Research Journal, 93 (7–8), 2023, 1686–1698.
  7. Li, Y.L., Luo, Y., Wang, Q.Q., Zou, W., Zheng, W.J., Ma, X.Y., Yang, H., Synthesis and performance analysis of green water and oil-repellent finishing agent with di-short fluorocarbon chain. Molecules, 28, 2023, 3369.
  8. Guo, H.K., Sun, Y.F., Chen, K., Meng, Q., Zhou, X.D., Synthesis and application of silane-modified castor oil-based waterborne polyurethane as a fluorine-free and durable water repellent. ACS Applied Polymer Materials, 6, 2024, 4138–4148.
  9. Rosales-Candelas, I., Soto-Bernal, J.J., Gonzalez-Mota, R., Frausto-Reyes, C., Effect of the finishing oil of acrylic fibers in the optical rotation of the Raman scattered light. Optics Express, 21 (21), 2013, 25546.
  10. Wang, R., Deng, S.A., Cao, L.D., Liu, Y.M., Yang, W.Y., Min, J., Fang, J., Effect of organosilicon resin containing disulfide bonds on elastic properties of cotton fabric. Cellulose, 29, 2022, 8443–8455.
  11. Seyidov, F.T., Mansoori, Y., Nezhad, J.T., Hydrophobicizing mould release agent for press moulding. Industrial Lubrication and Tribology, 59 (5), 2007, 236–241.
  12. Ibrahim, N.A., Amr, A., Eid, B.M., Multipurpose treatment of cellulose-containing fabrics to impart durable antibacterial and repellent properties. Fibers and Polymers, 21 (3), 2020, 513–521.
  13. Sui, Z.H., San, J.L., Wang, X., Zu, B., Cao, X.Y., Qiang, X.H., Organic fluorosilicone modified polyacrylate emulsion finishing agent. Journal of the Society of Leather Technologists and Chemists, 103 (4), 2019, 208–212.
  14. Yu, C.B., Shi, K.Q., Ning, J.Y., Zheng, Z., Yu, H.L., Yang, Z.X., Liu, J., Preparation and application of fluorine-free finishing agent with excellent water repellency for cotton fabric. Polymers, 2021, 13, 2980.
  15. Gao, A.Q., Hu, L., Zhang, H.J., Fu, D.N., Hou, A.Q., Xie, K.L., Silicone nanomicelle dyeing using the nanoemulsion containing highly dispersed dyes for polyester fabrics. Journal of Cleaner Production, 200, 2018, 48–53.
  16. Lloyd, S.G., Zeng, H.D., Wang, P.P., Chatham, J.C., Lactate isotopomer analysis by 1H NMR spectroscopy: consideration of long-range nuclear spin-spin interactions. Magnetic Resonance in Medicine, 51, 2004, 1279–1282.
  17. Pulidindi, I.N., New insight into the composition and structure of sizing agent from NMR spectroscopy. Journal of Photochemistry and Photochemical Research, 2 (2), 2024, 6–23.
  18. Pulidindi, I.N., Diglycidyl ether of bisphenol A (DGEBA) based epoxy sizing agent induces surface polarity in carbon fibers. International Journal of Crystalline Materials, 1 (2), 2024, 24–34.
  19. Sharma, D., Sahoo, S., Mishra, B.K., Molecular modeling in dioxane methanol interactions. Journal of Molecular Modeling, 20, 2014, 2408–2418.
  20. Sorensen, H., 1,4-dioxane and the application of phytoremediation at North Carolina hazardous waste groundwater contaminated sites. Master’s Thesis, Raleigh, North Carolina, 2013.
  21. Mojsiewicz-Piienkowska, K., Jamrogiewicz, Z., Lukasiak, J., Determination of polydimethyl siloxanes by 1H NMR in wine and edible oils. Food Additives and Contaminants, 20 (5), 2003, 438–444.
  22. Launer, P.J., Arkles, B., Infrared analysis of organosilicon compounds: Spectra-structure correlations. Reprinted from Silicon Compounds: Silanes and Silicons, 2013, Gelest, Inc., Morrisville, PA.
  23. Anderson, D.R., in Analysis of Silicones, A. Lee Smith, editor, Wiley-Interscience, New York, 1974, Chapter 10.
  24. Pulidindi, I.N., Raman spectroscopy for the determination of relative crystallinity of carbon fibers. International Journal of Crystalline Materials, 1 (1), 2024, 30–37.
  25. Pulidindi, I.N., Crystallinity of commercial carbon fibers from X-ray diffraction (XRD) studies. International Journal of Photochemistry and Photochemical Research, 1 (1), 2023, 17–27.
  26. Pulidindi, I.N., Gedanken, A., Surface modification of carbon fibers. Preprints, 2023, 2023082053. https://doi.org/10.20944/preprints202308.2053.v1, 2023.
Ahead of Print Subscription Original Research
Volume
Received 22/12/2024
Accepted 27/12/2024
Published 27/12/2024
248