Hydrothermal modification of carbon fiber fabrics by ZnO nanorods for mechanical strengthening of CFRP laminates

Open Access

Year : 2024 | Volume :11 | Special Issue : 12 | Page : 127-139
By

Ravi Shankar Rai

K. Payal Senapaty

Nandkishor Marotrao Sawai

Milind Motiram Patil

Vivek Bajpai

  1. Assistant Professor Department of Automation and Robotics, Sandip Institute of Technology and Research Centre Maharashtra India
  2. Assistant Professor Department of Mechanical Engineering, Sandip Institute of Engineering and Management Maharashtra India
  3. Associate Professor Department of Mechanical Engineering, Sandip Institute of Technology and Research Centre Maharashtra India
  4. Professor and Principal Department of Mechanical Engineering, Sandip Institute of Technology and Research Centre, Maharashtra India
  5. Associate Professor Department of Mechanical Engineering, Indian Institute of Technology (Indian School of Mines) Jharkhand India

Abstract

Hexagonal ZnO nanorods were produced on plain woven carbon fiber using a two-step seed-assisted hydrothermal procedure. By varying the process parameters such as molar concentrations, number of seeding cycles, and growth duration at a controlled growth temperature of 90 °C, it is feasible to produce ZnO nanostructures with a range of morphologies, including nanowires, hexagonal nanorods, and nanoflowers. The developed morphologies were examined using field emission scanning electron microscopy and the elemental compositions by energy-dispersive X-ray spectroscopy. The length of the seeding and growth treatments significantly impacts how nanostructures grow. Using the vacuum bagging technique, a laminated composite comprised of ZnO-orchestrated woven carbon fiber (WCF) with epoxy resin as the matrix. The most intriguing outcome of this work is how generated nanorods affect laminated composite impact strength due to better interfacial contact. The impact energy absorption capacity will alter because of fluctuations in ZnO’s convergence over time. ZnO grown on WCF, however, has led to the emergence of unique failure modes that characterize the fracture mechanism of hybrid composite materials, such as ZnO nanorod pullout and ZnO nanorod breakage. The most significant gains in impact strength, tensile strength, elastic modulus, and in-plane shear were obtained by the ZnO-modified composite at a concentration of 30 mM, with corresponding percentage increases of 39%, 38%, 32%, and 6%. A promising method of functionalization to achieve desired material characteristics for structural applications is the formation of ZnO nanostructures on WCF. Based on these outcomes, the hybrid composites that have been produced offer potential regarding utilization in the development of aviation and automotive industries. The developed composite materials are highly desirable for these industries because they have high impact strength, modulus, lightweight properties, and low void content.

Keywords: ZnO, Carbon fiber, Nanorods, Hydrothermal process, Impact energy absorption, Laminated composite

[This article belongs to Special Issue under section in Journal of Polymer and Composites(jopc)]

How to cite this article: Ravi Shankar Rai, K. Payal Senapaty, Nandkishor Marotrao Sawai, Milind Motiram Patil, Vivek Bajpai. Hydrothermal modification of carbon fiber fabrics by ZnO nanorods for mechanical strengthening of CFRP laminates. Journal of Polymer and Composites. 2024; 11(12):127-139.
How to cite this URL: Ravi Shankar Rai, K. Payal Senapaty, Nandkishor Marotrao Sawai, Milind Motiram Patil, Vivek Bajpai. Hydrothermal modification of carbon fiber fabrics by ZnO nanorods for mechanical strengthening of CFRP laminates. Journal of Polymer and Composites. 2024; 11(12):127-139. Available from: https://journals.stmjournals.com/jopc/article=2024/view=131715

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References

Cheon, M. Kim, Impact resistance and interlaminar shear strength enhancement of carbon fiber reinforced thermoplastic composites by introducing MWCNT-anchored carbon fiber, Compos. Part B Eng. (2021). https://doi.org/10.1016/j.compositesb.2021.108872.
X. Wang, L.Z. Wu, L. Ma, Low-velocity impact and residual tensile strength analysis to carbon fiber composite laminates, Mater. Des. (2010). https://doi.org/10.1016/j.matdes.2009.07.003.
Aizenberg, J.C. Weaver, M.S. Thanawala, V.C. Sundar, D.E. Morse, P. Fratzl, Materials science: Skeleton of euplectella sp.: Structural hierarchy from the nanoscale to the macroscale, Science (80-. ). 309 (2005) 275–278. https://doi.org/10.1126/science.1112255.
Tong, A.P. Mouritz, M.K. Bannister, L. Tong, A.P. Mouritz, M.K. Bannister, Chapter 9 – Z-Pinned Composites, in: 3D Fibre Reinf. Polym. Compos., 2002. https://doi.org/10.1016/B978-008043938-9/50021-1.
Kong, B.K. Deka, S.K. Kwak, A. Oh, H. Kim, Y. Bin Park, H.W. Park, Processing and mechanical characterization of ZnO/polyester woven carbon-fiber composites with different ZnO concentrations, Compos. Part A Appl. Sci. Manuf. 55 (2013) 152–160. https://doi.org/10.1016/j.compositesa.2013.08.013.
S. Rai, V. Bajpai, Synthesis of ZnO Nanostructures on Woven Kevlar Fabric and Impact of Hydrothermal Conditions on Growth of Nanorods, Lect. Notes Mech. Eng. (2023) 219–229. https://doi.org/10.1007/978-981-19-0561-2_20/COVER.
Goktas, A. Goktas, A comparative study on recent progress in efficient ZnO based nanocomposite and heterojunction photocatalysts: A review, J. Alloys Compd. (2021). https://doi.org/10.1016/j.jallcom.2021.158734.
S. Bhati, M. Hojamberdiev, M. Kumar, Enhanced sensing performance of ZnO nanostructures-based gas sensors: A review, Energy Reports. (2020). https://doi.org/10.1016/j.egyr.2019.08.070.
Kumar, R.S. Rai, V. Bajpai, N.K. Singh, Mass fabrication of 2D nanostructure (ZnO) in chemical growth solution using tip induced lithography, Mater. Manuf. Process. 00 (2021) 1–9. https://doi.org/10.1080/10426914.2021.1960993.
T. Noman, N. Amor, M. Petru, Synthesis and applications of ZnO nanostructures (ZONSs): a review, Crit. Rev. Solid State Mater. Sci. (2022). https://doi.org/10.1080/10408436.2021.1886041.
Lu, W. Cai, Y. Zhang, ZnO hierarchical micro/nanoarchitectures: Solvothermal synthesis and structurally enhanced photocatalytic performance, Adv. Funct. Mater. (2008). https://doi.org/10.1002/adfm.200700973.
S. Rai, V. Bajpai, Recent advances in ZnO nanostructures and their future perspective, Adv. Nano Res. (2021). https://doi.org/10.12989/anr.2021.11.1.037.
Kumar, R.S. Rai, N.K. Singh, An innovative approach to deposit ultrathin ZnO nanoflakes (2D) through hydrothermal assisted electrochemical discharge deposition and growth method, Ceram. Int. 46 (2020) 26216–26220. https://doi.org/10.1016/j.ceramint.2020.07.009.
S. Rai, V. Bajpai, Growth of CuO nanoparticles using one step chemical bath deposition under microwave heating and their characterizations, Int. J. Mater. Res. (2023). https://doi.org/10.1515/ijmr-2022-0043.
Baruah, J. Dutta, Hydrothermal growth of ZnO nanostructures, Sci. Technol. Adv. Mater. 10 (2009). https://doi.org/10.1088/1468-6996/10/1/013001.
S. Rai, V. Bajpai, Hydrothermally grown ZnO NSs on Bi-Directional woven carbon fiber and effect of synthesis parameters on morphology, Ceram. Int. 47 (2021) 8208–8217. https://doi.org/10.1016/j.ceramint.2020.11.180.
S. Rai, V. Bajpai, Rapid synthesis of ZnO nanostructures on woven carbon fiber using microwave treated chemical bath deposition and their characterization, Mater. Today Proc. (2022). https://doi.org/10.1016/j.matpr.2022.01.356.
Hosokawa, Synthesis of metal oxides with improved performance using a solvothermal method, J. Ceram. Soc. Japan. (2016). https://doi.org/10.2109/jcersj2.16109.
Ye, T. Yan, Z. Jiang, W. Wu, T. Fang, A review: Conventional and supercritical hydro/solvothermal synthesis of ultrafine particles as cathode in lithium battery, Ceram. Int. (2018). https://doi.org/10.1016/j.ceramint.2017.12.236.
Vayssieres, N. Beermann, S.E. Lindquist, A. Hagfeldt, Controlled aqueous chemical growth of oriented three-dimensional crystalline nanorod arrays: Application to iron(III) oxides, Chem. Mater. 13 (2001) 233–235. https://doi.org/10.1021/cm001202x.
Lin, G. Ehlert, H.A. Sodano, Increased interface strength in carbon fiber composites through a ZnO nanowire interphase, Adv. Funct. Mater. 19 (2009) 2654–2660. https://doi.org/10.1002/adfm.200900011.
K. Deka, K. Kong, J. Seo, D. Kim, Y. Bin Park, H.W. Park, Controlled growth of CuO nanowires on woven carbon fibers and effects on the mechanical properties of woven carbon fiber/polyester composites, Compos. Part A Appl. Sci. Manuf. 69 (2015) 56–63. https://doi.org/10.1016/j.compositesa.2014.11.001.
Ye, X. Fang, Y. Hao, X. Teng, L. Zhang, Zinc oxide nanostructures: Morphology derivation and evolution, J. Phys. Chem. B. 109 (2005) 19758–19765. https://doi.org/10.1021/jp0509358.
Kushwaha, M. Aslam, Zinc Oxide Nanowire Films : Solution Growth , Defect States and Electrical Conductivity, (n.d.) 453–491.
S. Rai, V. Bajpai, Improvement of interfacial adhesion of CuO nanostructured carbon fiber reinforced polymer composites, Polym. Compos. (2023). https://doi.org/10.1002/pc.27205.
K. Deka, A. Hazarika, Ob. Kwon, D.Y. Kim, Y. Bin Park, H.W. Park, Multifunctional enhancement of woven carbon fiber/ZnO nanotube-based structural supercapacitor and polyester resin-domain solid-polymer electrolytes, Chem. Eng. J. 325 (2017) 672–680. https://doi.org/10.1016/j.cej.2017.05.093.


Special Issue Open Access Original Research
Volume 11
Special Issue 12
Received October 30, 2023
Accepted December 20, 2023
Published January 24, 2024