Vishwa Deepak Dwivedi,
Pradeep Kumar Singh,
Pankaj Kumar Singh,
- Research Scholar Micro-nano Development Research Center, Department of Mechanical Engineering, GLA University Mathura Uttar Pradesh India
- Assistant Professor Micro-nano Development Research Centre, Department of Mechanical Engineering, GLA University Mathura Uttar Pradesh India
- Assistant Professor Micro-nano Development Research Centre, Department of Mechanical Engineering, GLA University Mathura Uttar Pradesh India
Abstract
With the enlargement of flexibility and suitability in material industries, high-performance thermal management materials are demanded with high thermal conductivity and electrical insulation are growing. In recent years, graphene has received a numerous focus from science community due to its high thermal conductivity and electrical insulation. Fabrication of light weight graphene and its derivatives as graphene Oxide (GO) and reduced graphene oxide (rGO) via facile processing method is yet a challenge for industries. The preparation of graphene through the wet exfoliation process of graphite leads to a several outstanding features of graphene. By thermal chemical reduction method, is simple and ecofriendly process used for the intercalate of graphene from graphite in a mass amount in the presence of aqueous solution H2SO4 and H2O2 through electrolysis process at high voltage (60 Volt) with electrolyte heating approach (60-70oC). This study investigates the structure and composition of graphene produced at different temperature as 650oC, 750oC and 850oC by thermal reduction of graphene oxide (GO) for short range of time (5 minutes). Thermal reduced graphene oxide (TrGO) diffraction peak, inter planar distance, crystallite size and structural disorder are all the significantly impacted by magnetic field and cyclic thermal loading, according to the FESEM and Raman spectra. TEM, UV analysis and TGA analyses demonstrated the significant influence of magnetic field and cyclic heating loading on the surface topography and micro structural characteristics. The thermal stability and functional groups contain oxygen seem to be unaffected by the magnetic field and cyclic thermal loading.
Keywords: Thermally reduced graphene oxide, Electro chemical exfoliation, electrolyte, thermal reduction, Green synthesis
[This article belongs to Journal of Polymer and Composites(jopc)]
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References
- K. Geim, K.S. Novoselov, The rise of graphene, Nano science and technology: a collection of reviews from nature journals, World Scientific, 2010, 11–19.
- S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva and A. A. Firsov,Science, 306, 2004, 666–669.
- Maleki A, Hajizadeh Z, Firouzi-Haji R. Eco-friendly functionalization of magnetic halloysite nano tube with SO3H for synthesis of di hydro pyrimidinones. Micropor Mesopor Mater, 2018, 259.
- I. Bolotin, K.J. Sikes, Z. Jiang, M. Klima, G. Fudenberg, J. Hone, P. Kim, H. Stormer, Ultrahigh electron mobility in suspended graphene, Solid State Commun. 146 (9–10), 2008, 351–355.
- Zhu Y, Murali S, Cai W, Li X, Suk JW, Potts JR, Ruoff RS;1; Graphene and graphene oxide: synthesis, properties, and applications. Adv Mater 22: 2010, 3906-3924.
- Balaprasad, Farah Water soluble graphene synthesis. Chemical Science Transactions 10: 2012, 500-507.
- Ban FY, Majid SR, Huang NM, Lim HN Graphene Oxide and Its Electrochemical Performance. Int J Electro chem Sci 7: 2012, 4345-4351.
- Hareema Saleem , Mobeen Haneef, Hina Y. Abbasi Synthesis route of reduced graphene oxide via thermal reduction of chemically exfoliated graphene oxide Materials Chemistry and Physics https://doi.org/10.1016/j.matchemphys.2017.10.020 2018, 0254-0584.
- Park JH, Dao TD, Lee H-i, Jeong HM, Kim BK;1; Properties of graphene/shape memory thermoplastic polyurethane composites actuating by various methods. Materials 7:2014, 1520- 1538.
- Dao TD, Oh KM, Choi JT, Lee H-i, Jeong HM, Kim YS, Park S-J, Kim BK;1; The effect of oxidation on properties of graphene and its polycaprolactone nanocomposites. J Nanosci Nanotechnol 12: 2012, 8420-8430.
- Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA;1; Electric field effect in atomically thin carbon films. Science 306: 2004, 666-669.
- Fu W, Kiggans J, Overbury SH, Schwartz V, Liang C;1; Low-temperature exfoliation of multilayer-graphene material from FeCl3 and CH3NO2 co-intercalated graphite compound. Chem Commun 47:2011, 5265-5267.
- Wu Z-S, Ren W, Gao L, Liu B, Jiang C, Cheng H-M;1; Synthesis of high-quality graphene with a pre-determined number of layers. Carbon 47: 2009, 493-499.
- Stankovich S, Dikin DA, Piner RD, Kohlhaas KA, Kleinhammes A, Jia Y, Wu Y, Nguyen ST, Ruoff RS;1; Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide. Carbon 45:2007, 1558-1565.
- Sutter PW, Flege J-I, Sutter EA;1; Epitaxial graphene on ruthenium. Nat Mater 7: 2008, 406-411.
- Gong Y, Ping Y, Li D, Luo C, Ruan X, Fu Q and Pan C Preparation of high-quality graphene via electrochemical exfoliation & spark plasma sintering and its applications Appl. Surf. Sci. 397 2017, 213–9.
- Akanda M R, Sohail M, Aziz M A and Kawde A N “Recent Advances in Nanomaterial- Modified Pencil Graphite Electrodes for Electroanalysis” Electroanalysis 28 2016, 408–24 .
- Chen K, Xue D and Komarneni S Nanoclay assisted electrochemical exfoliation of pencil core to high conductive graphene thin-film electrode J. Colloid Interface Sci. 487 2007, 156–61.
- Vishnu N and Kumar A S 2015 A preanodized 6B-pencil graphite as an efficient electrochemical sensor for mono-phenolic preservatives (phenol and meta-cresol) in insulin formulations Anal. Methods 7 2018, 1943–50.
- Vishnu N and Kumar A S 2017 Development of Prussian Blue and Fe(bpy)32 + hybrid modified pencil graphite electrodes utilizing its intrinsic iron for electroanalytical applications J. Electroanal. Chem. 786 2020, 145–53 .
- Hu, K. Xu, Physicochemical technologies for HRPs and risk control, in: High-risk Pollutants in Wastewater, Elsevier, 2020, pp. 2019, 169–207 .
- Zhang, et al., Ultrasensitive field-effect biosensors enabled by the unique electronic properties of graphene, Small 16 (15), 2020, 1902820.
- Bo, Y. Zou, J. Wang, Novel electrical properties and applications in kaleidoscopic graphene nanoribbons, RSC Adv. 11 (53) 2021, 33675–33691.
- Jiang, et al., Graphene-metal-metastructure monolith via laser shock-induced thermochemical stitching of MOF crystals, Matter 2 (6) 2020, 1535–1549.
- Chen, et al., Fatty amines/graphene sponge form-stable phase change material composites with exceptionally high loading rates and energy density for thermal energy storage, Chem. Eng. J. 382, 2020, 122831.
- Adrián Pinilla-Sánchez et al. Controlling the electrochemical hydrogen generation and storage in graphene oxide by in-situ Raman spectroscopy, Carbon, Volume 200, 5, Pages November 2022, 227-235.
- Marinova, et al., Graphene-based spatial light modulator operating at near infrared spectral range, Appl. Surf. Sci. 472 2019, 2–9.
- Sang, et al., Metal-organic framework (MOF) templated hierarchical Al-doped CoxP @ graphene composite: A promising solid-state asymmetric supercapacitor with PANI derived carbon nanorods, Journal of Alloys and Compounds Volume 965, 25, November 2023, 171183.
Journal of Polymer and Composites
Volume | 12 |
Issue | 05 |
Received | June 7, 2024 |
Accepted | June 24, 2024 |
Published | July 5, 2024 |