A comprehensive review on Sustainable Pathways to Synthesize 2, 5-Furandicarboxylic Acid (FDCA) from 5-Hydroxymethylfurfural (HMF) via Oxidative Processes

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Year : August 1, 2024 at 10:21 am | [if 1553 equals=””] Volume :11 [else] Volume :11[/if 1553] | [if 424 equals=”Regular Issue”]Issue[/if 424][if 424 equals=”Special Issue”]Special Issue[/if 424] [if 424 equals=”Conference”][/if 424] : 02 | Page : –

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Anand Metre,

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  1. Professor Chemical Engineering Department, M S University, Vadodara Gujarat India

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Abstract

nThe increasing global concern over the environmental impact of traditional plastics derived from petroleum and natural gas has spurred a search for more sustainable alternatives. Bioplastics, which are derived from renewable sources and may be biodegradable, have garnered significant interest as eco-friendly materials. Among the promising building blocks for bioplastics, 2,5-Furandicarboxylic Acid (FDCA) has emerged due to its potential to enhance polymer properties. One key precursor for bioplastics, 5-Hydroxymethylfurfural (5-HMF), has been identified, and its oxidation to FDCA represents a significant pathway for bioplastic synthesis. Various oxidation processes, employing homogeneous, heterogeneous catalysis, or even without catalysts, have been explored for the synthesis of FDCA from 5-HMF.This review paper focuses on elucidating the recent advancements in the homogeneous and heterogeneous catalytic synthesis of FDCA from 5-HMF. Homogeneous catalysts, such as metal complexes, and heterogeneous catalysts, including metal oxides and supported metal nanoparticles, have been extensively studied and continue to evolve in terms of design and performance for the conversion of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Homogeneous catalysts offer high selectivity, controlled reaction conditions, and mechanistic insights, with examples including Ru-based complexes and Co and Mn salts. Heterogeneous catalysts provide ease of separation, reusability, and stability, with examples including metal oxides like TiO2 and CeO2, and supported metal nanoparticles like Pt, Pd, and Au. Recent advances focus on bimetallic and multimetallic systems, nano-structuring, surface fictionalization, and green chemistry approaches to enhance catalytic activity, selectivity, and environmental sustainability. Both types of catalysts are crucial for the efficient and sustainable conversion of HMF to FDCA, with ongoing research aimed at meeting industrial and environmental demands. It provides a comprehensive overview of the methodologies, catalysts, reaction conditions, and outcomes associated with these oxidation processes. By summarizing the state-of-the-art in FDCA synthesis, the review aims to contribute to the understanding and development of sustainable pathways for bioplastic production.

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Keywords: HMF, FDCA, Bioplastic, Homogeneous and Heterogeneous catalyst, Oxidation.

n[if 424 equals=”Regular Issue”][This article belongs to Emerging Trends in Chemical Engineering(etce)]

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How to cite this article: Anand Metre. A comprehensive review on Sustainable Pathways to Synthesize 2, 5-Furandicarboxylic Acid (FDCA) from 5-Hydroxymethylfurfural (HMF) via Oxidative Processes. Emerging Trends in Chemical Engineering. August 1, 2024; 11(02):-.

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How to cite this URL: Anand Metre. A comprehensive review on Sustainable Pathways to Synthesize 2, 5-Furandicarboxylic Acid (FDCA) from 5-Hydroxymethylfurfural (HMF) via Oxidative Processes. Emerging Trends in Chemical Engineering. August 1, 2024; 11(02):-. Available from: https://journals.stmjournals.com/etce/article=August 1, 2024/view=0

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Volume 11
[if 424 equals=”Regular Issue”]Issue[/if 424][if 424 equals=”Special Issue”]Special Issue[/if 424] [if 424 equals=”Conference”][/if 424] 02
Received June 26, 2024
Accepted July 17, 2024
Published August 1, 2024

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