This is an unedited manuscript accepted for publication and provided as an Article in Press for early access at the author’s request. The article will undergo copyediting, typesetting, and galley proof review before final publication. Please be aware that errors may be identified during production that could affect the content. All legal disclaimers of the journal apply.
S.Meena,
C. Mary Anbarasi,
S. S. Syed Abuthahir,
- , PG and Research centre of Chemistry, JayarajAnnapackiam College for Women, (Affiliated to Mother Teresa Women’s University, Kodaikanal), Periyakulam, Theni- 625601, Tamil Nadu, India
- , PG and Research centre of Chemistry, JayarajAnnapackiam College for Women, (Affiliated to Mother Teresa Women’s University, Kodaikanal), Periyakulam, Theni- 625601, Tamil Nadu, India
- , PG and Research Department of Chemistry, Jamal Mohamed College (Autonomous), Affiliated to Bharathidasan University, Tiruchirappalli 620 020, Tamil Nadu, India
Abstract
This study analyzed the efficacy of various inhibitors in safeguarding carbon steel against corrosion in hydrochloric acid. The compounds that were subjected to testing included Acalypha indica root extract (AIRE), Hibiscus cannabinus (HC), and Solanum trilobatum (ST) leaf extracts. The investigation focused on the inhibitory efficacy through the application of gravimetric and electrochemical impedance methods. GC-MS and FTIR were employed to investigate the features of the inhibitors and co-inhibitors. Tafel data indicated that extracts from both leaves display mixed-type behaviour in inhibiting corrosion. The examination of AC impedance spectra indicated the formation of a surface protective coating, a finding that was supported by investigations using SEM and AFM techniques. The results indicated a significant increase in AIRE’s inhibitory efficacy when it was used in conjunction with HC and ST co-inhibitors. On comparison, the maximum inhibition efficiency of 93% was obtained for the mixture of ST leaf extract with AIRE at a concentration of 20 ppm. A suitable inhibition mechanism has been proposed based on the active phytochemical constituents present in the extracts. Evidence from GC–MS and FTIR analyses indicates that the presence of a higher number of heteroatoms (N and O) along with aromatic π-electrons in the ST leaf extract is likely responsible for the enhanced protection of carbon steel in the acidic medium.
Keywords: Corrosion, Acalypha indica, Hibiscus cannabinus, Inhibitory efficiency, Solanum trilobatum
S.Meena, C. Mary Anbarasi, S. S. Syed Abuthahir. Comparative Evaluation of Hibiscus Cannabinus and Solanum Trilobatum Extracts as Inhibitors for C- Steel Corrosion protection in Acidic Medium. Journal of Polymer and Composites. 2025; 13(07):-.
S.Meena, C. Mary Anbarasi, S. S. Syed Abuthahir. Comparative Evaluation of Hibiscus Cannabinus and Solanum Trilobatum Extracts as Inhibitors for C- Steel Corrosion protection in Acidic Medium. Journal of Polymer and Composites. 2025; 13(07):-. Available from: https://journals.stmjournals.com/jopc/article=2025/view=233443
References
- Elabbasy HM, Fouda AS. Olive leaf as green corrosion inhibitor for C-steel in Sulfamic acid solution. Green Chem. Lett. Rev. 2019; 12(3): 332-42p.
doi: 10.1080/17518253.2019.1646812.
- NawalSetti, AsmaBarrahi, Mohamed Maatallah, et al. Experimental and computational approach on the corrosion inhibition properties of two newly pyrazole derivatives on carbon steel in acid medium. Sci. Rep. 2025; 15(1): 3631, doi: 10.1038/s41598-025-87564-w.
- Bi-lan Lin, Xin-xin Zhou, Tian-hu Duan, et al. Experimental and theoretical study on corrosion inhibition and adsorption performance of Ipomoea batatas L. leaf extract for mild steel. Arab. J. Chem. 2024; 17(1): 105410, doi:10.1016/j.arabjc.2023.105410.
- Kilo M, Rahal HT, Mohammed H. El – Dakdouki, et al. Study of the corrosion and inhibition mechanism for carbon steel and zinc alloys by an eco- friendly inhibitor in acidic solution. Chem. Eng. Comm. 2020; 208(12):1676-85p. doi:10.1080/00986445.2020.1811239.
- Namrata Chaubey, Dileep Kumar Yadav, Vinod Kumar Singh, et al. A comparative study of leaves extracts for corrosion inhibition effect on aluminium alloy in alkaline medium. Ain Shams Eng. J. 2017; 8(4): 673-82p. doi: 10.1016/j.asej.2015.08.020.
6. Denisa-Ioana (Gheorghe) Ruta, Ecaterina Matei, Sorin-Marius Avramescu. Recent Development of Corrosion Inhibitors: Types, Mechanisms, Electrochemical Behavior, Efficiency, and Environmental Impact. Technologies. 2025; 13(3): 103, doi: 10.3390/technologies /13030103.
- Ogunleye OO, Arinkoola AO, Alagbe SO, et al. Synthesis of green corrosion inhibitor for mild steel in acidic environment. Indian Chem. Eng. 2020; 62(1):52-66p. doi: 10.1080/00194506.2019.1625815.
- Toghan A, Gadow HS, Fawzy A, et al. Adsorption Mechanism, Kinetics, Thermodynamics, and Anticorrosion Performance of a New Thiophene Derivative for C-Steel in a 1.0 M HCl: Experimental and Computational Approaches. Metals. 2023; 13(9): 1565, doi: 10.3390/met13091565.
- Sivakumar PR, Srikanth A. Green Corrosion Inhibitor: A Comparative study. Sadhana. 2020; 45:56. doi: 10.1007/s12046-020-1283-x.
- Jeyaprabha C, Bhuvaneswari T. Thermodynamics,Adsorption and spectral studies of the corrosion inhibition of mild steel by different leaf extracts in 1.0N HCl : Comparative Analysis. J. Uni. Shanghai Sci.Tech. 2022; 24(10): 128-44p. doi: 10.51201/JUSST/22/1079.
- Adekunle AS, Adeleke AA,et al. Comparative analyses of the inhibitive influence of Cascabela thevetia and Jatropha curcas leave extracts on mild steel. Nat. Env. & Poll. Tech. 2020; 19(3):923-33p. doi: 10.46488/NEPT.2020.v19i03.003.
- Parajuli D, Sharma S, Oli HB, et al. Comparative Study of Corrosion Inhibition Efficacy of Alkaloid Extract of Artemesia vulgaris and Solanum tuberosum in Mild Steel Samples in 1 M Sulphuric Acid. Electrochem. 2022; 3(3): 416-43p. doi: 10.3390/electrochem3030029.
- Nartunai G, Susikumar S, Sunil kumar KN. Solanum trilobatum L., medicinal plants in India: Importance and Cultivation, Part-1V, New Delhi: Jaya publishing house; 2022. 388-97p.
- ArockiaSelvi J, Arthanareeswari M, Pusphamalini T, et al. Effectiveness of Vinca rosea leaf extract as corrosion inhibitor for mild steel in 1 N HCl medium investigated by adsorption and electrochemical studies. Int. J. Corros. Scale Inhib.2020; 9(4): 1429-43p. doi: 10.17675/2305-6894-2020-9-4-15.
- Bhuvaneswari TK, Jeyaprabha C. Corrosion inhibition of mild steel in hydrochloric acid by leaves extract of Tephrosia purpurea. J. Adhes. Sci. Technol. 2020; 34(22): 2424-47p. doi:10.1080/01694243.2020.1766395.
- Akinbulumo OA, Odejobi OJ, Odekanle EL. Thermodynamics and adsorption studies of the corrosion inhibition of mild steel by Euphorbia heterophylla L. extract in 1.5 M HCl. Results in Materials.2020; 5, https://doi.org/10.1016/j.rinma.2020.100074.
- Geicy Barboza KP, Marcia de Oliveria CC, MarceloNeves A, et al. Justicia brandegeeana as a green corrosion inhibitor for carbon steel in sulphuric acid. Green Chem. Lett. Rev. 2024; 17(1): 2320254.doi: 10.1080/17518253.2024.2320254.
- Hana Lahbib, Samia Ben Hassen, Husnu Gerengi, et al. Inhibition effect of Cynara carunculus leaf extract on corrosion of St 37 steel immersed in seawater with and without bleach solution. Chem. Eng. Comm. 2020; 208(9): 1260-78p. doi: 10.1080 /00986445.2020.1771320.
- Benedict Ushaka Ugi, Fredrick Bekong Ugi. 817M40T mild steel corrosion remediation in 0.5M HCl environment using alkaloid and flavonoid extracts of salvia officinalis. Phys.Chem.Res. 2024; 12(1): 121-133. doi: 10.22036/pcr.2023.361046.2188.
20. Karthick KA, Bhuvaneshwari DS, Umapathi D, et al. Benign approach of canthium parviflorum as a bioinhibitor for mild steel corrosion in 0.5 M H2SO4 medium. Sur. Rev.Lett. 2020; 27(9): 1950208, doi: 10.1142/S0218625X19502081.
- Shanmugapriya R,Monisha R, Sanmugapriya R, et al. Electrochemical and Morphological investigations of Elettaria cardamomum pod extract as a green corrosion inhibitor for Mild steel corrosion in 1 N HCl. Inorg. Chem. Commun. 2023; 154 ,110958, doi:10.1016/j.inoche.2023.110958.
- 22. Deepa T, Thangavelu C. Corrosion protection of carbon steel in RO water by sodium gluconate-Zn2+ Rasayan J. Chem. 2017; 10(2): 584-91p. doi: 10.7324/RJC.2017.1021550.
- Abdullatef OA. TritonX-100 and sodium lauryl sulphate surfactants as environmentally friendly corrosion inhibitors for steel in 0.5M H2SO4. Adv. Anal. Chem. 2017; 7(2): 23-30p, doi: 10.5923/j.aac.20170702.01.
- Aliyu M, Ibrahim MB. Adsorption and Thermodynamic studies of water melon seed ethanol extract on the corrosion of zinc in nitric acid. Chem Search Journal. 2021; 12(2): 101-12p. http://www.aoj.info/insex.php/csj.
- Manimegalai S, Prithiba A, Kanthimathi G, et al. A Comprehensive corrosion inhibition behaviour studies of Leucophyllum frutescens leaves extract for mild steel. Asian J.Chem.2024; 36(9):2070-78p. doi:10.14233/ajchem.2024.32109.
- Rathod MR, Rajappa SK, Praveen BM, et al. Investigation of Dolichandra unguis – cati leaves extract as a corrosion inhibitor for mild steel in acid medium. CRGSC. 2021; 4(2021): 100113, doi: 10.1016/j.crgsc.2021.100113.
- Begum AAS, Vahith RMA, Kotra V, et al. Spilanthes acmella leaves extract for corrosion inhibition in acid medium. Coatings. 2021; 11(1): 106p.
doi: 10.3390/coatings11010106.
- 28. Pinky Sisodia, RenuSingh, Khalid Hasan S. Inhibitory effects of cuscuta reflexa on the corrosion of iron in 1M HCl Acid: A Green Approach. Rasayan J. Chem. 2024; 17 (1): 236-43p. doi: 10.31788/RJC.2024.1718751.

Journal of Polymer & Composites
| Volume | 13 |
| 07 | |
| Received | 16/09/2025 |
| Accepted | 09/10/2025 |
| Published | 04/12/2025 |
| Publication Time | 79 Days |
Login
PlumX Metrics